• Title/Summary/Keyword: $CO_2$ Storage

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Characteristics and Economic Evaluation of a CO2-Capturing Repowering System with Oxy-Fuel Combustion for Utilizing Exhaust Gas of MCFC (MCFC 배기가스를 이용하는 순산소연소 $CO_2$ 회수형 발전시스템의 특성과 경제성 평가)

  • Pak, Pyong-Sik;Lee, Young-Duk;Ahn, Kook-Young;Jeong, Hyun-Il
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2940-2945
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    • 2008
  • The scale of 2.4 MW MCFC was taken to construct a high-efficiency and economical power generation system without CO2 emission into the atmosphere for utilizing its exhaust gas. The conventional steam turbine power generation system (STGS) was evaluated and the net generated power (NGP) was estimated to be only 133 kW and the STGS is not economically feasible. A CO2-caputuring repowering system was proposed, where low temperature steam (LTS) produced at HRSG by using exhaust gas from MCFC is utilized as a main working fluid of a gas turbine, and the temperature of LTS was raised by combusting fuel in a combustor by using pure oxygen, not the air. It has been shown that NGP of the proposed system is 264 kW, and CO2 reduction amount is 608 t-CO2/y, compared to 306 t-CO2/y of STGS. The CO2 reduction cost was estimated to be negligible small, even when the costs of oxygen production and CO2 liquefaction facilities etc. were taken into account.

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Numerical Analysis of Fault Stability in Janggi Basin for Geological CO2 Storage (CO2 지중저장에 따른 장기분지 내 단층안정성 기초해석)

  • Jung-Wook Park;Hanna Kim;Hangbok Lee;Chan-Hee Park;Young Jae Shinn
    • Tunnel and Underground Space
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    • v.33 no.5
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    • pp.399-413
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    • 2023
  • The present study conducted a numerical modeling of CO2 injection at the Janggi Basin using the TOUGH-FLAC simulator, and examined the hydro-mechanical stability of the aquifer and the fault. Based on the site investigations and a 3D geological model of the target area, we simulated the injection of 32,850 tons of CO2 over a 3-year period. The analysis of CO2 plume with different values of the aquifer permeability revealed that assuming a permeability of 10-14 m2 the CO2 plume exhibited a radial flow and reached the fault after 2 years and 9 months. Conversely, a higher permeability of 10-13 m2 resulted in predominant westward flow along the reservoir, with negligible impact on the fault. The pressure changes around the injection well remained below 0.6 MPa over the period, and the influence on the hydro-mechanical stability of the reservoir and fault was found to be insignificant.

Effect of UV-B irradiation time on storage characteristics of the fruiting body of Heuktari (UV-B조사 시간에 따른 흑타리 자실체의 저장 특성)

  • Park, Tae-Min;Park, Youn-Jin;Oh, Tae-Seok;Cho, Young-Koo;Jang, Myoung-Jun
    • Journal of Mushroom
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    • v.19 no.4
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    • pp.329-335
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    • 2021
  • This experiment was conducted to investigate the changes in freshness parameters and determine the optimal UV-B irradiation conditions for each storage period for Heuktari, an oyster mushroom cultivar, grown under LED lightNo significant changes were observed in the CO2 and O2 content until day 12 of storage; however, after day 15, the CO2/O2 ratios were higher in the UV-treated groups than in the untreated groups. No color difference was observed between the UV-treated and untreated groups. In all UV-treated groups, hardness decreased over time; however, the group irradiated for 15 minutes showed higher hardness values than those of the untreated group. The UV-irradiated group showed higher ergosterol content than did the untreated group, and scanning electron microscopy revealed that mushroom cell wall destruction increased with increased UV treatment time. Overall, these findings confirmed that UV-B irradiation increased the ergosterol content of Heuktari but decreased its freshness and negatively impacted other storage characteristics.

Container System Actively Maintaining High CO2 Concentration for Improved Sensory Quality of Kimchi

  • Lee, Hye Lim;An, Duck Soon;Jung, Yong Bae;Lee, Dong Sun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.22 no.3
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    • pp.79-84
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    • 2016
  • A kimchi container actively controlling $CO_2$ concentration by timely flushing of $CO_2$ gas was structured and tested in its capability and effectiveness because high $CO_2$ concentration enhances the sensory flavor of the product. The inlet and outlet valves of $CO_2$ gas were programmed to open and close allowing synchronous vent/$CO_2$ flush according to the requirements of its dissolution in the contained kimchi. During the chilled storage, the headspace of container could be maintained at desired high $CO_2$ concentration providing the preferred kimchi in sensory quality compared to control of the conventional container. However, there was no significant difference between the high $CO_2$ container and control (container simply closed with air) in kimchi quality attributes of pH, titratable acidity, total viable bacterial count, Lactobacillus sp. count and Leuconostoc sp. count. The flow rate and time interval of $CO_2$ flushing need to be adjusted considering the kimchi amount, headspace volume and ripening time. The designed system has potential to be applied in refrigerator appliances in homes and food service industry.

Characterization of Potassium Based Dry CO2 Sorbents Developed for the Reduction of Side Reactions (부반응 저감 조성 K계 건식 CO2 흡수제 특성평가)

  • Jang, Young-shin;Kim, Ui-sik;Yoon, Yang-no;Baek, Jeom-In
    • KEPCO Journal on Electric Power and Energy
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    • v.5 no.4
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    • pp.337-341
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    • 2019
  • In this study, the effects of two materials, active alumina and CaO based inorganic binder, which cause the side reaction on the K2CO3-based solid CO2 sorbents was investigated. K2CO3-based solid sorbents called KAM series was prepared by spray drying method and then measured its physical properties and CO2 sorption capacity. Among the KAM series sorbents, KAM(0.5) maintained high CO2 sorption capacity of 7.6 wt% after 3 cycle of sorption/regeneration reaction and showed very low attrition loss as low as 3.1 % which was measured by ASTM D5757-95.

Relationship between Hydrochemical Variation of Groundwater and Gas Tigtness in the Underground Oil Storage Caverns (지하원유비축기지 공동주변 지하수의 수질화학적 변화와 기밀성과의 관계)

  • Jeong Chan Ho
    • The Journal of Engineering Geology
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    • v.14 no.3 s.40
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    • pp.259-272
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    • 2004
  • The purpose of this study is to investigate the effect of hydrochemical variation of groundwater on the gas tigtness in an unlined oil storage cavern. The groundwater chemistry is greatly influenced by the seawater mixing, the water curtain and the dissolution of grounting cements. The chemical composition of groundwater greatly varies ac-cording to both the location of monitoring wells and the sampling period. Most of groundwater shows alkaline pH and high electrical conductivity. The chemical types of groundwater show the dominant order as follows : Na-Cl type > Ca-Cl type > $Ca-HCO_3(CO_3)$ type. Thermodynamic equilibrium state between chemical composition of groundwater and major minerals indicates that carbonate minerals except clay minerals can be precipitated as a secondary mineral. It means that the secondary precipitates can not greatly exerts the clogging effect into fracture aperture in rock mass around oil storage cavern. The content of total organic carbon (TOC) shows a slightly increasing trend from initial stage to late stage. The $EpCO_2$ was computed so as to assess the gas contribution on the $CO_2$ in groundwater. The $EpCO_2$ of 0$\~$41.3 indicates that the contribution of oil gas on $CO_2$ pressure in groundwater system can be neglected.

Design of Pore and Matter Architectures in Cobalt Oxide Electrode for Supercapacitor (수퍼커패시터용 산화코발트전극의 세공과 재료구조의 설계)

  • Kim, Han-Joo;Shin, Dal-Woo;Kim, Yong-Chul;Kim, Seong-Ho;Park, Soo-Gil
    • Proceedings of the KIEE Conference
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    • 2000.11c
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    • pp.425-427
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    • 2000
  • We describe the preparation of a cobalt oxide in which the solid-pore architecture of the material is controllably varied. All $CoO_2$ gels derived from $CoCl_2$-based sol-gel synthesis, but exhibit markedly different final pore structures based on how the pore fluid is removed from forces that result from extraction are either low or nonexistent. These nanoscale mesoporous materials have higher $CoO_2$ crystallites. Controlling both the pore and solid architecture on the nanoscale offers a strategy for the design of new supercapacitor and charge-storage materials.

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The growth and characterization of Rb-doped $KNbO_3$ nonlinear optical crystals

  • Beh, C.Y.;Chong, T.C.;Kumagai, H.;Hirano, M.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.06a
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    • pp.149-155
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    • 1997
  • We have successfully grown colorless and transparent Rb-doped potassium niobate (KRN) single crystals using the top seeded solution growth(TSSG) technique. In our crystal growth experiments, the Rb doping concentrations within the melt range from 2-15 mol% relative to that of Nb$_2$O5. Atomic absorption measurements indicate that the Rb content in the KRN solid solution is rather low; the Rb segregation coefficient is found to be on the order of 0.05. It is believed that this is due to the relatively much larger Rb+ ionic radius compared to that of K+, rendering it more difficult for Rb to replace K in the KNbO$_3$(KN) host lattice. Preliminary single-pass second harmonic generation (SHG) experimental results indicate that there exists marginal improvement in the phase-matching temperature tolerance of KRN compared to that of pure Kn single crystals.

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Physicochemical Study of Thermal Treated Serpentine for Carbon Dioxide Sequestration (이산화탄소 포획을 위한 serpentine의 열처리와 물리화학적 특성 변화 연구)

  • Choi, Weon-Kyung;Cho, Tae-Hwan
    • Transactions of the Korean hydrogen and new energy society
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    • v.18 no.3
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    • pp.301-308
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    • 2007
  • Silicate mineral serpentine with magnesium and calcium was selected as a mineral carbonation mediators for carbon dioxide storage. Serpentine has various metallic elements as an oxides form of magnesium, iron, calcium, aluminium etc. Magnesium and calcium could be carbonation salt preferentially than other metal component within serpentine. Systemic thermochemical treatment for serpentine could change physicochemical properties like a surface area and pore dimensions. Due to the rapid chemical reaction rate depended on dimensional values, carbonation formation could determined by surface property change of thermochemical treated serpentine.

Indentification of Cholesterol Oxides Formed in Butter under Varied Storage Conditions (상이한 조건에서 저장한 버터로부터 생성된 콜레스테롤 산화물의 확인)

  • Chang, Young-Sang;Yang, Joo-Hong;Shin, Hyo-Sun
    • Korean Journal of Food Science and Technology
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    • v.22 no.7
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    • pp.762-766
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    • 1990
  • The effect of storage conditions on the oxidative stability of cholesterol in butter was studied by identifing cholesterol oxides by TLC. Experimental variables for storage conditions were packaging(packaged and unpackaged), storage temperature(ambient and refrigerated), light source(dark, fluorescent and ultraviolet), and storage period(2, 4, 6, and 8 weeks). No cholesterol oxides were detected from packaged butter under all storage conditions. When unpackaged butter was stored under darkness at ambient and refrigerated temperatures, cholesterol oxides were not detected even after 6 weeks of storage, but small amounts of $7{\alpha}-and\;7{\beta}-hydroxycholesterols$ were detected after 8 weeks of storage. When unpackaged butter was stored under ultraviolet light at ambient temperature, $7{\alpha}-hydroxycholesterol,\;7{\beta}-hydroxycholesterol$ cholestane-triol, and cholesterol epoxide were detected after 2 weeks of storage, and when fluorescent light was used instead of ultraviolet light, the same species of cholesterol oxides were detected after 6 weeks of storage.

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