• 제목/요약/키워드: $CO_2$ Evolution

검색결과 423건 처리시간 0.033초

제지(製紙)슬러지의 시용(施用)이 논 토양(土壤)의 화학성(化學性)과 수도생육(水稻生育)에 미치는 영향(影響);IV. 슬러지시용(施用)이 토양중(土壤中) 휘발성저급지방산변화(揮發性低級脂肪酸變化)에 미치는 영향(影響) (Effects of Paper Sludge Application on the Chemical Properties of Paddy Soil and Growth of Paddy Rice;IV. Effects of Paper Sludge Application on the Seasonal Variations of Volatie Lower Fatty Acids in Paddy Soil)

  • 허종수;김광식;하호성
    • 한국환경농학회지
    • /
    • 제7권1호
    • /
    • pp.34-42
    • /
    • 1988
  • 제지(製紙)슬러지의 시용량(施用量)을 300, 600, 900 및 1,200kg/10a으로 달리하고 각(各) 시용수준별(施用水準別) C/N율(率)을 30 : 1로 조절(調節)하여 Pot시험(試驗)을 실시(實施)함으로써 토양중(土壤中) 휘발성저급지방산조성(揮發性低級脂肪酸組成)을 시기별(時期別)로 조사(調査)하였다. 그리고 제지(製紙)슬러지의 분해양상(分解樣相) 및 토양중(土壤中) $CO_2$발생량(發生量)을 경시적(經時的)으로 조사(調査)하였으며, 토양중(土壤中) 휘발성지방산함량(揮發性脂肪酸含量)과 수도(水稻)의 무기성분흡수(無機成分吸收)와의 관계(關係)등을 검토(檢討)한 결과(結果)는 다음과 같다. 1. 제지(製紙)슬러지 시용후(施用後) 120일간(日間)의 분해율(分解率)은 $35{\sim}44%$, C/N율(率)은 $55{\sim}82$였다. 2. 토양중(土壤中) $CO_2$발생량(發生量)은 슬러지의 시용량(施用量)이 많을수록 증가(增加)하였으며 $CO_2$발생량(發生量)과 슬러지의 분해율(分解率) 및 토양중(土壤中) 휘발성방린산함량(揮發性肪燐酸含量)과 고도(高度)의 유의적(有意的)인 정(正)의 상관(相關)이 있었다. 3. 토양중(土壤中) 휘발성지방산(揮發性脂肪酸) acetic, propionic, i-butyric, butyric, i-valeric 및 valeric acid의 6종(種)이 동정(同定)되었으며, 그 함량(含量)은 슬러지의 시용량(施用量)이 많을수록 증가(增加)하였고, 슬러지시용후(施用後) 25일경(日頃)이 가장 높았으며 그후 시일(時日)이 경과할수록 감소(減少)하는 경향(傾向)이었다. 4. 토양중(土壤中) 휘발성지방산(揮發性脂肪酸)은 수도(水稻)의 초기생육(初期生育)을 억제(抑制)하였으며 벼이앙후(移秧後) 25일(日)의 토양중(土壤中) acetic, propionic, i-valeric acid 함량(含量)과 수도(水稻)의 질소(窒素), 린산(燐酸), 칼리, 석탄고토(石炭苦土) 및 규산흡수량간(珪酸吸收量間)에는 유의적(有意的)인 역상관(逆相關)이 있었고, butyric acid 함량(含量)과 린산(燐酸) 및 석탄흡수량간(石炭吸收量間)에도 같은 경향(傾向)이었다. 5. 이앙후(移秧後) 25일(日)의 토양중(土壤中) 총휘발성지방산함량(總揮發性脂肪酸含量)은 토양중(土壤中) $Fe^{++}$$Mn^{++}$ 함량(含量)과 유의적(有意的)인 정의(正) 상관(相關)이 있었으며 $Fe^{++}$ 함량(含量)은 특히 acetic acid 함량(含量)과 고도(高度)의 유의적(有意的)인 정(正)의 상관(相關)이 있었다.

  • PDF

pH가 낮은 탄산수의 CO2 탈기에 따른 용존탄소동위원소 변화 (Changes of carbon-13 Isotope of Dissolved Inorganic Carbon Within Low-pH CO2-rich Water during CO2 Degassing)

  • 채기탁;유순영;김찬영;박진영;방하은;이인혜;고동찬;신영재;오진만
    • 한국지하수토양환경학회지:지하수토양환경
    • /
    • 제24권3호
    • /
    • pp.24-35
    • /
    • 2019
  • It is known that ${\delta}^{13}C_{DIC}$ (carbon-13 isotope of dissolved inorganic carbonate (DIC) ions) of water increases when dissolved $CO_2$ degases. However, ${\delta}^{13}C_{DIC}$ could decrease when the pH of water is lower than 5.5 at the early stage of degassing. Laboratory experiments were performed to observe the changes of ${\delta}^{13}C_{DIC}$ as $CO_2$ degassed from three different artificial $CO_2$-rich waters (ACWs) in which the initial pH was 4.9, 5.4, and 6.4, respectively. The pH, alkalinity and ${\delta}^{13}C_{DIC}$ were measured until 240 hours after degassing began and those data were compared with kinetic isotope fractionation calculations. Furthermore, same experiment was conducted with the natural $CO_2$-rich water (pH 4.9) from Daepyeong, Sejong City. As a result of experiments, we could observe the decrease of DIC and increase of pH as the degassing progressed. ACW with an initial pH of 6.4, ${\delta}^{13}C_{DIC}$ kept increasing but, in cases where the initial pH was lower than 5.5, ${\delta}^{13}C_{DIC}$ decreased until 6 hours. After 6 hours ${\delta}^{13}C_{DIC}$ increased within all cases because the $CO_2$ degassing caused pH increase and subsequently the ratio of $HCO_3{^-}$ in solution. In the early stage of $CO_2$ degassing, the laboratory measurements were well matched with the calculations, but after about 48 hours, the experiment results were deviated from the calculations, probably due to the equilibrium interaction with the atmosphere and precipitation of carbonates. The result of this study may be not applicable to all natural environments because the pressure and $CO_2$ concentration in headspace of reaction vessels was not maintained constant as well as the temperature. Nevertheless, this study provides fundamental knowledge on the ${\delta}^{13}C_{DIC}$ evolution during $CO_2$ degassing, and therefore it can be utilized in the studies about carbonated water with low pH and the monitoring of geologic carbon sequestration.

First Record of Platorchestia monodi (Crustacea: Amphipoda: Talitridae) from the Pacific Region

  • Kim, Min-Seop;Min, Gi-Sik
    • Animal Systematics, Evolution and Diversity
    • /
    • 제27권3호
    • /
    • pp.205-212
    • /
    • 2011
  • Platorchestia monodi (Mateus et al., 1986), the beach hopper, commonly lives in sea shores and was previously reported only from the Atlantic regions, such as Mid-Atlantic islands, Brazilian coast, and Israel. We present the first record of this species in the Pacific region. The present species can be clearly distinguished from related species by the shapes of gnathopods 1-2 and development of sexual dimorphism in antenna 2 and pereopod 7. Descriptions of the diagnostic characteristics of the species are provided on the text. In addition, this paper also provided the partial sequence of the mitochondrial cytochrome c oxidase subunit 1 (CO1) gene of the species for its molecular characteristics.

CPD 모델을 활용한 석탄 가스화 과정 중 탄종에 따른 휘발분 배출에 관한 이론해석연구 (A Theoretical Analysis on Volatile Matter Release from Different Coals Using CPD Model During a Coal Gasification)

  • 김량균;이병화;전충환;장영준;송주헌
    • 대한기계학회논문집B
    • /
    • 제33권12호
    • /
    • pp.1000-1006
    • /
    • 2009
  • Integrated Coal Gasification Combined Cycle (IGCC) power plants have been developed to reduce carbon dioxide emissions and to increase the efficiency of electricity generation. A devolatilization process of entrained coal gasification is predicted by CPD model which could describe the devolatilization behavior of rapidly heated coal based on the chemical structure of the coal. This paper is intended to compare the mass release behavior of char, tar and gas(CO, $CO_2,\;H_2O,\;CH_4$) for three different coals. The influence of coal structure on gas evolution is examined over the pressure range of 10${\sim}$30atm.

SPHEREx Galactic Science: Ice Evolution from Molecular Clouds to Protoplanetary Disks

  • Lee, Jeong-Eun
    • 천문학회보
    • /
    • 제43권1호
    • /
    • pp.48.1-48.1
    • /
    • 2018
  • SPHEREx의 중요 임무 중 하나는 $0.75{\mu}m$$5{\mu}m$ 사이에서 $H_2O$, CO, $CO_2$, XCN, OCS, 그리고 $CH_3OH$와 같은 얼음 분자의 전천 탐사 스펙트럼을 제공하는 것이다. 이러한 얼음 분자는 성간분자운의 먼지 티끌 표면에서 생성되어 별 탄생의 필연적 산물이며, 행성이 형성되는 원시행성계원반에서 다양한 변화를 겪게 되고, 복잡한 유기분자를 합성하게 된다. 하지만 충분하지 않은 관측 자료로 인해, 얼음 분자의 진화에 대한 이해가 미약한 상태이다. 현재까지는 근적외선에서 충분히 밝은 100 여개의 배경별이나 원시성에 대해서만 얼음 스펙트럼을 관측할 수 있었다. SPHEREx를 이용한 고감도 전천 탐사 미션은 약 20,000 여개의 배경별과 원시성에 대해 얼음 분자 스펙트럼을 제공할 것이다. 이렇게 100 배 이상 늘어난 샘플 스펙트럼 수로 인해, 얼음 분자의 진화에 대해서 통계적으로 의미있는 연구가 가능해 질 것이다. 본 발표에서는 SPHEREx의 Ice Program을 소개하고, 기대되어지는 결과에 대해서 논의하고자 한다.

  • PDF

Superconducting transition in the Presence of Magnetic order in BaFe1.89Co0.11As2

  • Kim, K.W.;Wolf, T.;Bernhard, C.
    • 한국초전도ㆍ저온공학회논문지
    • /
    • 제17권4호
    • /
    • pp.21-24
    • /
    • 2015
  • We report optical spectra of underdoped $BaFe_{1.89}Co_{0.11}As_2$ that hosts both of magnetic and superconducting orders. The temperature dependent evolution of optical conductivity shows finger prints of the magnetic order and the s-wave nature of the superconducting gaps. Careful inspection on the superconducting state reveals that the two orders compete but coexist in the ground state.

Aero Engine in the New Century -Challenge in Technology and Business-

  • Sekido, Toshinori
    • 한국추진공학회:학술대회논문집
    • /
    • 한국추진공학회 2004년도 제22회 춘계학술대회논문집
    • /
    • pp.440-448
    • /
    • 2004
  • Toasting the 100 year anniversary of controlled, powered flight, the propulsion system used on today's aircraft represents the evolution of jet propulsion based on the gas turbine, first conceived by Whittle and Von Ohain about 70 years ago. In that period, propulsion system concepts have evolved through turbo-props, turbo-jets, low by-pass ratio(BPR) turbofans to today's high BPR 2-shaft and 3-shaft turbofans. Also, this period has seen remarkable progress in the performance, reliability environmental compatibility of these propulsion systems.(omitted)

  • PDF

중원 지역 탄산수의 지구화학적 진화 (Geochemical Evolution of CO2-rich Groundwater in the Jungwon Area)

  • 고용권
    • 자원환경지질
    • /
    • 제32권5호
    • /
    • pp.469-483
    • /
    • 1999
  • Two different types of deep groundwaters occur together in the Jungwon area: $CO_2$-rich water and alkali water. Each water shows distrinct hydrogeochemical and environmental isotopic characteristics. The $CO_2$-rich waters are characterized by lower pH(6.0~6.4), higher Eh (25~85mV) and higher TDS content (up to 3,300 mg/l), whereas the alkali type waters have higher pH (9.1~9.5), lower Eh (-136~-128mV) and lower TDS content (168~254 mg/l). The CO2-rich waters ($Pco_2$=up to 1atm) were probably evolved by the local supply of deep $CO_2$ during the deep circulation, resulting in enhanced dissolution of surrounding rocks to yield high concentrations of $Ca^{2+}, Na^+, Mg^{2+}, K^+\; and \;HCO_3\;^-$ under low pH conditions. On the other hand, the alkali type waters ($Pco_2$=about 10-4.6 atm) were evolved through lesser degrees of simple wate/rock (granite) interaction under the limited suppy of $CO_2$. The alkali waters are relatively enriched in F- (up to 14mg/l), whereas the F- concentration of$CO_2$-rich water is lower (2.2~4.8 mg/l) due to the buffering by precipitation of fluorite. The oxygen-hydrogen isotopes and tritium data indicate that compared to shaltion ($\delta$18O=-9.5~-7.8$\textperthousand$),two different types fo deep groudwaters (<1.0TU)were both derived from pre-thermonuclear (more than 40 years old) meteoric waters with lighter O-H isotopic composition ($\delta$18O=-9.5~-7.8$\textperthousand$) and have evolved through prolonged water/rock interaction. The $CO_2$-rich waters also show some degrees of isotopic re-equilibration with $CO_2$ gas. The $\delta^{34}S$ values of dissolved sulfates (+24.2~+27.6$\textperthousand$) in the $CO_2$-rich waters suggest the reduction of sulfate by organic activity at depths. The carbon isotope data show that dissolved carbon in the $CO_2$-rich waters were possibly derived either from dissolution of calcite or from deep $CO_2$ gas. However, strontium isotope data indicate Ca in the $CO_2$-rich waters were derived mainly from plagioclase in granite, not from hydrothermal calcites.

  • PDF

(Bi,Nd)(Fe,Ti)O3 세라믹스와 박막의 상형성 거동 (Phase Evolution Behavior of (Bi,Nd)(Fe,Ti)O3 Ceramics and Thin Films)

  • 김경만;이희영
    • 한국전기전자재료학회논문지
    • /
    • 제23권12호
    • /
    • pp.949-955
    • /
    • 2010
  • Nd and Ti co-doped bismuth ferrite $(Bi_{1-x}Nd_x)(Fe_{1-y}Ti_y)O_3$ (x, y = 0, 0.05, 0.1, 0.2) ceramics and thin films were synthesized through the conventional mixed-oxide process and pulsed laser deposition (PLD), respectively. Nd and Ti co-doping effect was examined with emphasis on how these impurities affect phase formation behavior as there could be the improvement in leakage current problems often associated with multiferroic $BiFeO_3$ (BFO) thin films. The lattice constants of BFO ceramics decreased with Nd doping concentration up to 10mol%, while they further decreased with Nd and Ti co-doping to about 20%. BFO thin films obtained by the PLD process revealed random polycrystalline structure. Similar to bulk BFO ceramic, Nd and Ti co-doping effectively suppressed the formation of unwanted secondary phase and thus stabilized the perovskite phase in BFO thin films.

A case study of extraplanar molecular gas in a Virgo spiral using the ALMA

  • Lee, Bumhyun;Chung, Aeree
    • 천문학회보
    • /
    • 제41권2호
    • /
    • pp.61.3-62
    • /
    • 2016
  • NGC 4522 is a spiral galaxy located in the Virgo cluster which appears to be undergoing active ram pressure stripping due to the intracluster medium (ICM). What makes this galaxy special is the extraplanar CO gas, some of which coincides with the extraplanar $H{\alpha}$ patches. As one of the few cases where the interstellar molecular gas is thought to have been pushed out from the stellar disk by the ICM, this galaxy provides an opportunity to study the impact of ICM pressure on the dense/star forming gas and its fate in the extraplanar space after stripping. In order to probe detailed molecular gas properties inside and outside the stellar disk and the associated star formation activities, we have observed NGC 4522 in 12CO (1-0) and 13CO (1-0) using the ALMA. We have targeted two regions, one around the center of the galaxy and one centered on the peak of the extraplanar CO, detecting both lines in both regions. Particularly, this is the first case where 13CO gas has been detected outside the stellar disk in a galaxy undergoing ram pressure stripping. In this work, we present preliminary results from the ALMA observations and discuss the evolution of molecular gas properties and star formation activities inside and outside the stellar disk.

  • PDF