• Title/Summary/Keyword: $CO_2$ Addition

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Carbon Dioxide Adsorption Study of Biochar Produced from Shiitake Mushroom Farm by-product Waste Medium (표고버섯 농가 부산물 폐배지 기반 바이오차의 이산화탄소 흡착 연구)

  • Gyuseob Song;Jinseung Kim;Juhyoung Park;Younghoon Noh;Youngchan Choi;Youngjoo Lee;Kyubock Lee
    • New & Renewable Energy
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    • v.20 no.1
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    • pp.135-144
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    • 2024
  • The present study investigated waste medium from a domestic shiitake mushroom farm, which was pyrolyzed to produce biochar. The yield rate of the biochar was compared after exposure to various pyrolysis temperature conditions, and the characteristics of the produced biochar were analyzed. The present study focused on the carbon dioxide (CO2) adsorption capacity of the resulting biochar. The CO2 adsorption capacity exhibited a correlation with the pyrolysis temperature of the biochar, with increasing temperatures resulting in higher CO2 adsorption capacities. Brunauer-Emmett-Teller (BET) analysis showed that the CO2 adsorption capacity was related to the surface area and pore volume of the biochar. Calcium is added to the process of producing mushroom medium. Experiments were performed to investigate the CO2 adsorption capacity of the biochar from the waste medium with the addition of calcium. In addition, CO2 adsorption experiments were conducted after the pyrolysis of kenaf biochar with the addition of calcium. The results of these experiments show that calcium affected the CO2 adsorption capacity.

Magnetic Properties of Hot Press and Die-Upset Nd-Fe-B-Co Magnets (Hot Press 및 Die-Upset 법에 의해 제조된 Nd-Fe-B-Co 자석의 자기적 특성)

  • Lee, K.S.;Kim, Y.S.;Suh, S.J.;Park, H.S.;Park, C.
    • Journal of the Korean Magnetics Society
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    • v.7 no.1
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    • pp.49-54
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    • 1997
  • The effect of Co and annealing temperature on the magnetic properties, phase change and microstructure of melt-spun $(Nd_{14.73}Fe_{78.67}B_{6.60})_{100-x}Co_x$ (X=0, 1, 2, 3) ribbons has been studied. The Co containing ribbons were found to have higher coercivity ($_iH_c$) than the ribbons without Co. Intrinsic coercivity of 20.3 kOe has been obtained by addition of 2 at%Co. This effect by Co addition is also represented in the case of hot pressed and die-upseted magnets. The maximum intrinsic coercivities of hot press and die-upset $(Nd_{14.73}Fe_{78.67}B_{6.60})_{100- x}Co_x$ (X=0, 1, 2, 3) magnets are 16.9 kOe and 15.2 kOe when X=2.

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Piezoelectric and Dielectric Properties of PZW-PMN-PZT Piezoelectric Ceramic according to Sintering Aid Li2CO3 Addition (소결조제 Li2CO3 첨가에 따른 PZW-PMN-PZT 압전 세라믹의 압전 및 유전 특성)

  • Lee, Kab-Soo;Lee, Il-Ha;Yoo, Ju-Hyun;Ryu, Sung-Lim
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.12
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    • pp.1034-1038
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    • 2007
  • In order to develop the composition ceramics capable of being sintered at low temperature with high piezoelectric properties for multilayer piezoelectric actuator application, PZW-PMN-PZT system ceramics were manufactured according to sintering aid $Li_2CO_3$ addition and their microstructural, dielectric and piezoelectric properties were investigated. The crystal structure of the specimens showed a perovskite phase and no pyrochlore or other second phase was detected. At the sintering temperature of $900\;^{\circ}C,\;0.2\;wt%Li_2CO_3$ added specimen showed a optimum values of kp = 0.562, $d_{33}\;=\;360\;pC/N$ and Qm = 1184, respectively.

Effect of Additives on Catalytic Activity in Thermal Catalytic De-NOx Process (Thermal catalytic de-NOX 공정에서 첨가제가 촉매의 활성에 미치는 영향에 관한 연구)

  • 이진구;김태원;최재순;김정호;이재수;장경욱;박해경
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.3
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    • pp.249-255
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    • 1999
  • We sdudied effect of additives on catalytic activity in thermal catalytic de-NOx process which was composed of thermal reduction, catalytic reduction and catalytic oxidation stage. Pd-Pt/${\gamma}$-$Al_2O_3$ catalysts with the addition of transition metals(Co, Cu, Fe, Ni, W, Zn, Zr) and rare earth metals(Ce, Sr) were prepared by the conventional washcoating method. Those catalysts were characterized by CO pulse chemisorption, ICP, $N_2$ adsorption, SEM and XRD. The effect of catalyst additives on NOx removal for diesel emission was studied in thermal catalytic de-NOx process at reduction temperature(350~50$0^{\circ}C$), space velocity(5,000~20,000 $hr^{-1}$) and the engine load(0~120kW). The concentraton of CO, $CO_2$, NO and $NO_2$ in the exhaust gas increased with the engine load. On the other hand the concentration of $O_2$ decreased. The de-NOx activityof all prepared catalysts increased with respect to high CO and low $O_2$ level in the thermal reduction stage of the process. Insertion of Ce to Pt-Pd/${\gamma}$-$Al_2O_3$ catalyst showed the best activity of all the catalysts under these experimental conditions. De-NOx catalysts are effective to remove CO in addition to NOx in the catalytic reduction stage.

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Potential Use of Microalgae Scenedesmus acuminatus for Tertiary Treatment of Animal Wastewater (축산폐수 고도처리를 위한 미세조류 Scenedesmus acuminatus의 이용 가능성)

  • Park, Ki-Young;Lim, Byung-Ran;Lee, Ki-Say;Lee, Soo-Koo
    • Journal of The Korean Society of Agricultural Engineers
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    • v.53 no.1
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    • pp.63-69
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    • 2011
  • The green algae Scenedesmus acuminatus was cultured in different media: animal wastewater and an artificial culture medium in order to evaluate potential use for tertiary treatment. The experiments were conducted with air flowrate 1~2 L/min at $28{\sim}30^{\circ}C$. The nitrogen and phosphorus showed very similar removal efficiencies (68~77 % and 69~80 % for nitrogen and phosphorus respectively). The optimal fed period was estimated as three days in the semi-continuous experiment. The effects of $CO_2$ (4.5 %) injection on nutrient uptake from animal wastewater (biological treatment effluent) were compared to an air injection under the same conditions of light and photoperiod. The uptake rates of nutrient with air injection were observed 0.009 gN/gChl-a/day, 0.028 gN/gChl-a/day and T-P 0.003 gP/gChl-a/day for nitrate, total nitrogen and phosphorus respectively. The rates were enhanced by addition of $CO_2$ to 0.026 gN/gChl-a/day, 0.076 gN/gChl-a/day and T-P 0.018 gP/gChl-a/day. This study establishes that $CO_2$ addition during nutrient deprivation of microalgal cells may accelerate tertiary wastewater treatment.

The Analysis of CO2 Emission Assessment in Concrete with Smart Blast Furnace Slag (스마트 고로슬래그미분말 혼입 콘크리트의 CO2 배출량 평가에 관한 연구)

  • Kim, Tae-Hyoung;Tae, Sung-Ho;Ha, Sung-Kyun;Park, Jung-Hoon;Roh, Seung-Jun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.05a
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    • pp.43-45
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    • 2012
  • As a part of recent CO2 emission reduction studies in the concrete industry with active use of concrete admixtures with low basic unit of CO2 emission such as blast furnace slag (BFS), basic unit of CO2 emission by SBFS was computed in order to assess CO2 emission by reinforced concrete building with smart blast furnace slag (SBFS). In addition, SBFS concrete was applied to the subject building for assessment of CO2 emission during material production step among construction steps. Life cycle CO2 emission assessment on the subject building was classified into 7cases according to mix ratio of BFS and SBFS.

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Effects of Global Warming on the Estuarine Wetland Biogeochemistry (기후변화가 하구 습지 토양의 생지화학적 반응에 미치는 영향에 관한 연구)

  • Ki, Bo-Min;Choi, Jung-Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.8
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    • pp.553-563
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    • 2011
  • This study investigated the effects of elevated $CO_2$ and nitrogen addition on the anaerobic decomposition mediated by microorganisms to determine the microbial metabolic pathways in the degradation of organic matters of the sediments. There were statistically significant differences(P < 0.05) in the rates between denitrification and methanogenesis upon increased $CO_2$ concentration, nitrogen addition, in the presence of plants. Based on the assumption that anaerobic degradation of organic matter mainly occurs through denitrification, iron reduction, and methanogenesis, methanogenesis is the dominant pathways in the decomposition of organic matter under the condition of elevated $CO_2$ and nitrogen addition. In addition, the altered environment increased anaerobic carbon decomposition. Therefore, it can be concluded that freshwater wetland sediments have positive effects on the global warming by the increased methanogenesiss as well as increased anaerobic carbon decomposition.

Development of prediction methodology from CO2 emissions of construction equipment based multiple linear regression (다중선형회귀분석 기반 건설장비 이산화탄소 배출량 예측모델 개발)

  • Gwon, Jae-Min;Lee, Jae-Hak;Jo, Min-Do;Choi, Young-Jun;Han, Seung-Woo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.38-39
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    • 2019
  • Environmental problems caused by GHG emitted by various industries are emerging around the world, and accordingly, relevant regulations are being applied by countries around the world. Korea is operating a carbon credit system that trades GHG in industry for money, which is expected to be applied to the construction industry. In addition, construction equipment using fossil fuels accounts for the largest portion of $CO_2$ emissions in the construction industry, and the importance of $CO_2$ reduction and prediction is increasing. However, there is a lack of data on the directly measured $CO_2$ emissions of construction equipment and there is no accurate methodology for measuring methods. Therefore, in this study, independent variables were derived based on the $CO_2$ emission data. In addition, multiple linear regression is performed for each independent variable to derive a predictive model of carbon dioxide emission by work type of construction equipment. It is expected that the construction process plan based on environmental factors in the construction industry can be established in the future.

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Various Filler Added CaO-Al2O3-SiO2 Glass Composites for LTCC Substrate Applications (LTCC 기판재료 응용을 위한 다양한 충전제 함유 CaO-Al2O3-SiO2 유리복합체 연구)

  • Kim, Kwan-Soo;Jang, Ho-Soon;Shin, Hyun-Ho;Kim, In-Tae;Kim, Shin;Han, Yong-Hyun;Yoon, Sang-Ok
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.323-329
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    • 2009
  • Influences of ceramic filler types and dose on the sintering, phase evolution, and dielectric properties of ceramic/CaO-$Al_2O_3-SiO_2$ glass composites were investigated. All of the specimens were sintered at $900^{\circ}C$ for 2 h, which conditions are required by the lowtemperature co-firing ceramic (LTCC) technology. Ceramic fillers of $Al_2O_3,\;SiO_2$, kaolin, and wollastonite were used. The addition of $Al_2O_3$ filler yielded the crystalline phases of alumina and wollastonite, and the densification over 95% of the relative density was achieved up to 50 wt% addition of the filler. For the cases of the fillers of $SiO_2$, kaolin, and wollastonite, crystalline phases of quartz, mullite, and wollastonite formed, while the densification decreased monotonically with the filler addition. In overall, all the investigated fillers with 10 wt% addition resulted in a reasonable sintering (over 95 %) and low dielectric constants (less than 6), demonstrating the feasibility of the investigated composites for application to a LTCC substrate material with a low dielectric constant.

A Study on the Absorption of $CO_2$Using Alkanolamine Solution (Alkanolamine계 수용액을 이용한 이산화탄소 흡수에 관한 연구)

  • 이성남;송호철;현재휴;박진원
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.5
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    • pp.407-414
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    • 2001
  • In this study, the absorption kinetics of $CO_2$onto a mixture of AMP (2-amino-2-methyl-1-propanol) MEA (monoethanolamine) water were investigated at 30 and 4$0^{\circ}C$ using a packed absorption tower. Solubility and absorption rate of $CO_2$into alkanolamine solutions and optimal condition of $CO_2$absorption process were investigated. The experimental conditions are as follows; temperature of 30 and 4$0^{\circ}C$, gas flow rate of 3ι/min for the absorption tower, and liquid flow rate of 0.1ι/min. Feed gas was a mixture of 85% $N_2$and 15% $CO_2$. The experimental results showed that AMP had greater solubilities and faster absorption rates than MEA and DEA. In addition, MEA had the fastest initial reaction rate. To improve the properties of AMP which have low initial reaction rate and high cost, AMP was used with MEA. The mixing ratio was also changed in constant total molarity of 1,2,3 and 4. The experimental results can be summarized as follows: (1) in solubility experiment, the addition of MEA in constant total polarity decreased the solubility of $CO_2$in AMP/MEA mixture. (2) from 0 to about 0.3 in mixing ratio, the solubility of $CO_2$in AMP/MEA mixture had little differences compared with the sum of solubility of AMP only and solubility of MEA only . (3) mixing ratio of 0.3 was found to be an optimal point with the fastest $CO_2$absorption rate.

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