• Title/Summary/Keyword: $CO_2$ 주입

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Effects of Die Temperature and CO2 Injection on Physical Properties and Antioxidant Activity of Extruded Rice with Tomato Flour (사출구 온도와 CO2 주입이 쌀·토마토 압출성형물의 물리적 특성 및 항산화 활성에 미치는 영향)

  • An, Sang-Hee;Ryu, Gi-Hyung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.44 no.6
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    • pp.912-920
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    • 2015
  • The study was designed to investigate the effects of die temperature and $CO_2$ injection on the physical and antioxidant properties of extruded rice with tomato flour. Moisture content and screw speed were fixed at 25% and 150 rpm, respectively. Die temperatures and $CO_2$ injection were adjusted to 80, 110, and $140^{\circ}C$ and 0, and 300 mL/min, respectively. Specific mechanical energy input decreased as die temperature increased from 80 to $140^{\circ}C$. The expansion index increased, while bulk density decreased with $CO_2$ injection. All extrudates showed increased water soluble index (WSI) and water absorption index through the extrusion process. WSI increased as die temperature increased. 1,1-Diphenyl-2-picrylhydrazyl (DPPH) radical-scavenging activity and total phenolic compounds increased as die temperature increased from 80 to $140^{\circ}C$. Total carotenoid and lycopene contents decreased through the extrusion process. Total carotenoid and lycopene contents upon 0 mL/min $CO_2$ injection and $140^{\circ}C$ die temperature were highest at $6.65{\mu}g/g$ and 2.69 mg/kg, respectively. In conclusion, $CO_2$ injection affects expansion properties while an increased die temperature leads to increased DPPH radical scavenging activity and total phenols.

Laboratory study of $CO_2$ migration in water-saturated anisotropic sandstone, based on P-wave velocity imaging (P-파 속도 영상화에 근거한 물로 포화된 이방성 사암에서의 $CO_2$ 이동에 관한 실험 연구)

  • Xue, Ziqiu;Lei, Xinglin
    • Geophysics and Geophysical Exploration
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    • v.9 no.1
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    • pp.10-18
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    • 2006
  • We measured the changes in P-wave velocity that occur when injecting $CO_2$ in gaseous, liquid, and supercritical phases into water-saturated anisotropic sandstones. P-wave velocities were measured in two cylindrical samples of Tako Sandstone, drilled along directions normal and parallel to the bedding plane, using a piezo-electric transducer array system. The velocity changes caused by $CO_2$ injection are typically -6% on average, with maximum values about -16% for the case of supercritical $CO_2$ injection. P-wave velocity tomograms obtained by the differential arrival-time method clearly show that $CO_2$ migration behaviour is more complex when $CO_2$ flows normal to the bedding plane than when it flows parallel to bedding. We also found that the differences in P-wave velocity images were associated both with the $CO_2$ phases and with heterogeneity of pore distribution in the rocks. Seismic images showed that the highest velocity reduction occurred for supercritical $CO_2$ injection, compared with gaseous or liquid $CO_$ injection. This result may justify the use of the seismic method for $CO_2$ monitoring in geological sequestration.

Scenario Analysis of Injection Temperature and Injection Rate for Assessing the Geomechanical Stability of CCS (Carbon Capture and Sequestration) System (이산화탄소 격리저장시스템의 역학적 안정성 평가를 위한 주입온도 및 주입량 시나리오 해석)

  • Kim, A-Ram;Kim, Hyung-Mok
    • Tunnel and Underground Space
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    • v.26 no.1
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    • pp.12-23
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    • 2016
  • For a successful accomplishment of Carbon Capture Sequestration (CCS) projects, appropriate injection conditions should be designed and optimized for site specific geological conditions. In this study, we evaluated the effect of injection conditions such as injection temperature and injection rate on the geomechanical stability of CCS system in terms of TOUGH-FLAC simulator, which is one of the well-known T-H-M coupled analysis methods. The stability of the storage system was assessed by a shear slip potential of the pre-existing fractures both in a reservoir and caprock, expressed by mobilized friction angle and Mohr stress circle. We demonstrated that no tensile fracturing was induced even in the cold CO2 injection, where the injected CO2 temperature is much lower than that of the reservoir and tensile thermal stress is generated, but shear slip of the fractures in the reservoir may occur. We also conducted a scenario analysis by varying injected CO2 volume per unit time, and found out that it was when the injection rate was decreasing in a step-wise that showed the least potential of a shear slip.

Evaluating the Effectiveness of In-Situ Carbonation in Floor Dry Cement Mortar Applications (바닥용 건조시멘트 모르타르 배합 내 In-situ 탄산화 적용을 위한 CO2 주입 특성 및 물리적 특성 검토)

  • Kim, Jin-Sung;Cho, Sung-Hyun;Kim, Chun-Sik
    • Journal of the Korea Institute of Building Construction
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    • v.24 no.1
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    • pp.1-10
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    • 2024
  • In-situ carbonation technology represents a form of mineral carbonation that integrates CO2 into the fabrication process of cementitious construction materials, capturing CO2 as calcium carbonate(CaCO3) through a reaction between calcium ions(Ca2+) and CO2 released during cement hydration. This investigation examines the application of in-situ carbonation technology to a variety of floor dry cement mortar formulations commonly used in local construction projects. It assesses the effects of varying the CO2 injection flow rate and total volume of CO2 injected. Additionally, the study evaluates the impact of reducing the quantity of cement used as a binder on the final product's quality.

Time-lapse crosswell seismic tomography for monitoring injected $CO_2$ in an onshore aquifer, Nagaoka, Japan (일본 Nagaoka의 육상 대수층에 주입된 $CO_2$의 관찰을 위한 시간차 시추공간 탄성파 토모그래피)

  • Saito, Hideki;Nobuoka, Dai;Azuma, Hiroyuki;Xue, Ziqiu;Tanase, Daiji
    • Geophysics and Geophysical Exploration
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    • v.9 no.1
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    • pp.30-36
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    • 2006
  • Japan's first pilot-scale $CO_2$ sequestration experiment has been conducted in Nagaoka, where 10400 t of $CO_2$ have been injected in an onshore aquifer at a depth of about 1100 m. Among various measurements conducted at the site for monitoring the injected $CO_2$, we conducted time-lapse crosswell seismic tomography between two observation wells to determine the distribution of $CO_2$ in the aquifer by the change of P-wave velocities. This paper reports the results of the crosswell seismic tomography conducted at the site. The crosswell seismic tomography measurements were carried out three times; once before the injection as a baseline survey, and twice during the injection as monitoring surveys. The velocity tomograms resulting from the monitoring surveys were compared to the baseline survey tomogram, and velocity difference tomograms were generated. The velocity difference tomograms showed that velocity had decreased in a part of the aquifer around the injection well, where the injected $CO_2$ was supposed to be distributed. We also found that the area in which velocity had decreased was expanding in the formation up-dip direction, as increasing amounts of $CO_2$ were injected. The maximum velocity reductions observed were 3.0% after 3200 t of $CO_2$ had been injected, and 3.5% after injection of 6200 t of $CO_2$. Although seismic tomography could map the area of velocity decrease due to $CO_2$ injection, we observed some contradictions with the results of time-lapse sonic logging, and with the geological condition of the cap rock. To investigate these contradictions, we conducted numerical experiments simulating the test site. As a result, we found that part of the velocity distribution displayed in the tomograms was affected by artefacts or ghosts caused by the source-receiver geometry for the crosswell tomography in this particular site. The maximum velocity decrease obtained by tomography (3.5%) was much smaller than that observed by sonic logging (more than 20%). The numerical experiment results showed that only 5.5% velocity reduction might be observed, although the model was given a 20% velocity reduction zone. Judging from this result, the actual velocity reduction can be more than 3.5%, the value we obtained from the field data reconstruction. Further studies are needed to obtain more accurate velocity values that are comparable to those obtained by sonic logging.

Effect of Cyclic Injection on Migration and Trapping of Immiscible Fluids in Porous Media (공극 구조 내 교차 주입이 비혼성 유체의 포획 및 거동에 미치는 영향)

  • Ahn, Hyejin;Kim, Seon-ok;Lee, Minhee;Wang, Sookyun
    • Economic and Environmental Geology
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    • v.52 no.1
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    • pp.37-48
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    • 2019
  • In geological $CO_2$ sequestration, the behavior of $CO_2$ within a reservoir can be characterized as two-phase flow in a porous media. For two phase flow, these processes include drainage, when a wetting fluid is displaced by a non-wetting fluid and imbibition, when a non-wetting fluid is displaced by a wetting fluid. In $CO_2$ sequestration, an understanding of drainage and imbibition processes and the resulting NW phase residual trapping are of critical importance to evaluate the impacts and efficiencies of these displacement process. This study aimed to observe migration and residual trapping of immiscible fluids in porous media via cyclic injection of drainage-imbibition. For this purpose, cyclic injection experiments by applying n-hexane and deionized water used as proxy fluid of $scCO_2$ and pore water were conducted in the two dimensional micromodel. The images from experiment were used to estimate the saturation and observed distribution of n-hexane and deionized water over the course drainage-imbibition cycles. Experimental results showed that n-hexane and deionized water are trapped by wettability, capillarity, dead end zone, entrapment and bypassing during $1^{st}$ drainage-imbibition cycle. Also, as cyclic injection proceeds, the flow path is simplified around the main flow path in the micromodel, and the saturation of injection fluid converges to remain constant. Experimental observation results can be used to predict the migration and distribution of $CO_2$ and pore water by reservoir environmental conditions and drainage-imbibition cycles.

Analysis of CO2 Capture Efficiency in Relation to the Inlet Moisture Content of the Regenerator in the Continuous Process by using Sorbent Analysis (연속공정에서 고체흡수제의 입자분석을 통한 재생반응기 주입 수분량에 따른 CO2 회수효율 영향 분석)

  • Lee, Do-Young;Kim, Ki-Chan;Park, Young Cheol;Han, Moon-Hee;Yi, Chang-Keun
    • Korean Chemical Engineering Research
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    • v.50 no.4
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    • pp.654-658
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    • 2012
  • In this study, $CO_2$ capture efficiency in relation to the inlet moisture content of the regenerator was investigated using potassium-based sorbents in the continuous process composed of two bubbling fluidized-bed reactors, where solid outlet configuration in the regenerator was converted from underflow to overflow. XRD (X-ray Diffraction), SEM (Scanning Electron Microscope) and TGA were performed to find out the effect of water pre-treatment according to inlet moisture content in the regenerator. The $K_2CO_3{\cdot}1.5H_2O$ structure of solid sorbents has been increased as inlet moisture content of the regenerator increased. As a result, the $CO_2$ capture efficiency increased as the $K_2CO_3{\cdot}1.5H_2O$ structure of solid sorbents increased since the reactivity of the sorbents has been improved by that structure generated by the water pre-treatment. And $CO_2$ capture efficiency increased about 3~8% after sorbent outlet configuration of the regenerator was changed underflow to overflow.

Strength and Effectiveness of Grouting of Sand Treated with Bacteria (Bacteria로 처리된 모래지반의 강도 및 주입효과)

  • Park, Kyung-Ho;Kim, Dae-Hyeon
    • Journal of the Korean Geotechnical Society
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    • v.29 no.2
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    • pp.65-73
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    • 2013
  • The purpose of this study is to confirm strength and effectiveness of grouting of the sand treated with bacteria. In order to analyze the cementation of sand treated with bacteria, five types of specimens(Not treated, Cement 2% treatment, Cement 4% treatment, Cement 2% + $CaCO_3$ 2% treatment and $CaCO_3$ 4% treatment) were made. Unconfined compressive strength tests were done on $D\;5cm{\times}H\;10cm$ specimens and biogrouting tests were performed on $D\;6cm{\times}H\;12cm$ specimens to observe the effectiveness of grouting with bacteria. As a result, Cement 2% + $CaCO_3$ 2% treatment was found to be the most effective in terms of the unconfined compressive strength.

Lab-Scale Air/Bio-Sparging Study to Remediate Diesel-Contaminated Soil and Groundwater : The Effect of Air Injection Rate and Pattern (디젤오염 토양 및 지하수 복원을 위한 공기주입정화법 실험실 연구 : 공기주입량과 공기주입방식의 영향)

  • Chang, Soon-Woong;Lee, Si-Jin;Cho, Su-Hyung;Yoon, Jun-Ki
    • Journal of Soil and Groundwater Environment
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    • v.11 no.4
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    • pp.10-17
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    • 2006
  • Laboratory-scale two-dimensional aquifer physical model studies were conducted to assess the effect of air injection rate and air injection pattern on the removal of disel contaminated soil and groundwater by air/bio-sparging. The experimental results were represented that the optimal conditions in this experiment were as air injection rate of 1,000 ml/min and pulsed air injection pattern(15 min on/off). The results of the TPH reduction, DO consumption and $CO_2$ production indicate the effective biodegradation evidence of diesel. Based on our results, The minimal $O_2$ supply and pulsed air injection pattern could effectively enhance the diesel removal and the pulsing air injection had effect on oxygenation in this system. Thus, the cost of operating air/bio-sparging system will be reduced if optimal air injection rate and pulsed air injection pattern are applied to remediate contaminants.

Preliminary Evaluation of the Optimal Injection Rate and Injection Efficiency of Groundwater Artificial Recharge Site Using Numerical Model (수치모델을 활용한 지하수 인공함양 대상지의 적정 주입량 및 주입효율 예비 평가)

  • Cha, Jang-Hwan;Kim, Gyoo-Bum;Lee, Jae Young
    • The Journal of Engineering Geology
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    • v.31 no.1
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    • pp.19-30
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    • 2021
  • This study evaluated the injection rate and the injection efficiency of the artificial recharge in the upper drought-prone watershed region, where the remaining water was used for injection, by using a numerical model to secure water during a drought. As a result of a numerical model under the condition of diverse injection rates per a well and hydraulic characteristics of the aquifer, the optimal injection rate per a well was estimated as 50.0 ㎥/day, and the injection efficiency was simulated as 33.2% to 81.2% of the total injection volume. As the injection time was shorter, the injection efficiency tented to increase non-linearly. As the injection rate increased, the residual storage in aquifer increased and available groundwater amount also increased, which could be advantageous for drought relief. For a more accurate assessment of injection efficiency, the model will be validated using the field injection data and optimum scenarios will enable the efficient operation of the artificial recharge system in the study area.