• Title/Summary/Keyword: $CO_2$ 분리

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Computational Study on the Energy Separation of the Vortex Tube for CO2 Reduction (CO2 흡수용 20Nm3/hr급 Vortex tube의 에너지 분리 현상에 관한 해석적 연구)

  • Kim, Chang-Su;Jung, Young-Chul;Han, Keun-Hee;Park, Sung-Young
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.4
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    • pp.695-701
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    • 2009
  • Vortex tube is the device that can separate small particles from the compressed gas, as well as compressed gas into hot and cold flow. In this study, computational approach has been performed to analyze the characteristics of the vortex tube. Energy separation characteristics of the vortex tube has been tested for various geometric design parameters. For the given conditions, it is found that as the tube is lengthened, hot end temperature is reduced but cold end temperature does not influenced much. As the orifice diameter decreases, cold end temperature decreases. Also, as hot gas fraction increases, hot end temperature decreases. The results from this study can be used for the basic design parameter of the $CO_2$ reduction device.

A Study on the Separation of $CO_2$from Flue Gas by Chemical Absorption (화학흡수법에 의한 연소폐가스 중 지구온난화 가스 $CO_2$분리에 관한 연구)

  • 안성우;김영국;송호철;박진원
    • Journal of Energy Engineering
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    • v.6 no.2
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    • pp.203-211
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    • 1997
  • This study is on the separation of Global warming effect gas, CO$_2$by chemical absorption from mixture of CO$_2$-N$_2$which was modeled after flue gas of fire power plant. Investigation of optimum condition for absorbent was carried out by using sparged vessel apparatus. Through packed tower experiments, applicabilities of two absorption models were tested by comparing experimental results with theoretical values. Absorbent used in the experiments was Monoethanolamine (MEA) and gas mixture was made in the mole composition of 15% CO$_2$and 85% N$_2$. Through estimations of CO$_2$loading and CO$_2$removal efficiency, optimum concentration of absorbent was found in the range of 4-5 M. To find a rate of absorption, an enhancement factor was introduced. Values of rate of absorption were calculated by Film model and Higbie model, respectively. Higbie model showed good agreement with experimental results. Therefore, this models is considered to be applicable to the CO$_2$separation process for flue gas from fire power plant.

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A study on the corrosion behavior of Ni-Al electoplated 316L SS separator of molten carbonate fuel cells (Ni-Al이 전기도금된 용융탄산염 연료전지 분리판용 316L SS의 부식거동에 관한 연구)

  • 문영준;임희천;이덕열
    • 한국전기화학회:학술대회논문집
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    • 2001.06a
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    • pp.237-242
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    • 2001
  • 용융탄산염 연료전지에서 분리판으로 사용되는 316L 스테인리스 스틸의 내식성을 향상시키기 위해 Ni과 Al을 전기도금법에 의해 코팅하였으며 열처리를 통해 스테인리스 스틸표면에 $Ni_2Al_3$, NiAl 등의 금속간화합물을 형성시켰다. $62mol\%Li_2CO_3-38mol\%K_2CO_3$ 전해질 내에서 100시간 동안 침지실험을 수행한 결과 Al의 도금두께가 $10{\mu}m$ 이상인 경우에는 내식성이 상당히 향상되었음을 확인하였다.

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Oxygen Permeation Properties of Tubular $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ (BSCF) Membranes under Different Condition of Feed Side and Permeate Side (공급 측과 투과 측 조건에 따른 $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ (BSCF) 관형 분리막의 산소투과 특성)

  • Kim, Jong-Pyo;Park, Jung-Hoon;Lee, Yong-Taek;Choi, Young-Jong
    • Membrane Journal
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    • v.21 no.2
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    • pp.155-162
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    • 2011
  • Dense tubular $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ (BSCF) membranes were prepared by extrusion technique. The phase structure of the $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ membranes was characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). Relative density of $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ tubular membrane was 94.10%. Oxygen permeation was measured at difference operating condition of feed side and permeate side in the temperature range from 700 to $950^{\circ}C$. The oxygen permeation flux of dense tubular $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ membrane reached maximum 1.37 mL/$min{\cdot}cm^2$ at $900^{\circ}C$ exposed to ambient air (feed side) and vacuum pump (permeate side).

New Analytical Method for Separation and Identification of Heavy Metals (I) (중금속의 분리 및 검출을 위한 분석화학적 연구 (제 1 보). 새로운 분리방법의 개발)

  • Kim, Youn-Doo;Bae, Jun-Heon;Shin, Young-Kook
    • Journal of the Korean Chemical Society
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    • v.31 no.3
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    • pp.231-235
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    • 1987
  • In 10M chloride (4M HCl + 6M LiCl) solution, cobalt, but not nickel, formed complex anion (${CoCl_3}^-$), and this anion was extracted by a liquid anion exchanger with Amberlite LA-2. The ion exchange capacity was 2.175meq of cobalt complex per unit ml of Amberlite LA-2. Upon eluting the resin with 0.4M nitric acid, the cobalt complex was stripped and transfered into eluate quantitatively. By using this separation method in the chloride solution dissolved with 50mg of cobalt (II) and 500mg of nikel(II), recovery of cobalt were 99.6 percent.

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Fabrication of Organic Solvent Resistant Polyketone Hollow Fiber Membranes (유기용매 저항성 Polyketone 중공사 분리막의 제조)

  • Park, Yeji;Jang, Wongi;Choi, Jinwon;Woo, Yunha;Hou, Jian;Jeon, Sungil;Byun, Hongsik
    • Membrane Journal
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    • v.31 no.5
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    • pp.363-370
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    • 2021
  • Organic solvent resistant hollow fiber membranes were fabricated via a thermally induced phase separation (TIPS) method using Polyketone polymer, a material with excellent resistance to organic solvents. The PEG300, DMSO2 and Glycerine called the "green solvents" were used as diluents for TIPS method. The spherulite structure was formed with DMSO2 by S-L phase separation behavior whereas the bicontinuous structures were formed with PEG300 and Glycerine, respectively. The morphology of the PK hollow fiber membranes was investigated using SEM. The pure water permeability and the durability test were conducted to understand the permeation properties of PK hollow fiber membranes. The tensile strength test was conducted for the property of mechanical strength. In this study, the fabrication of PK hollow fiber membranes with various diluents was discussed to understand the correlation between diluent and polymer in detail.

Fabrication and Property of Ba0.5Sr0.5Co0.8Fe0.2O3-δ Hollow Fiber Membranes (Ba0.5Sr0.5Co0.8Fe0.2O3-δ 중공사 분리막의 제조 및 물성)

  • Jeon, Sung Il;Park, Jung Hoon;Kim, Jong Pyo;Sim, Woo Jong;Lee, Yong Taek
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.1-5
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    • 2012
  • $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ hollow fiber with o.d. 1.02 mm and i.d. 0.437 mm were fabricated by a phase-inversion spinning technique.The starting $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ precursor was synthesized by the polymerized complex method and then calcined at $900^{\circ}C$. As-prepared powder was dispersed in a polymer solution, and extruded as form of hollow fiber through a spinneret. Finallydense $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ hollow fiber membrane was obtained by sintering for 2 h at $1,080^{\circ}C$ for the application of oxygen separation. In addition, despite a very thin membrane with 0.58 mm, the BSCF hollow fiber membrane possessed a proper mechanical strength of 602.5 MPa.

Bioethanol Production from Seaweed Undaria pinnatifida Using Various Yeasts by Separate Hydrolysis and Fermentation (SHF) (갈조류 미역(Undaria pinnatifida)의 분리당화발효와 다양한 효모를 이용한 바이오에탄올의 생산)

  • Nguyen, Trung Hau;Ra, Chae Hun;Park, Mi-Ra;Jeong, Gwi-Taek;Kim, Sung-Koo
    • Microbiology and Biotechnology Letters
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    • v.44 no.4
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    • pp.529-534
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    • 2016
  • Bioethanol was produced using the separate hydrolysis and fermentation (SHF) method with macroalgal polysaccharides from the seaweed, Undaria pinnatifida as biomass. This study focused on the pretreatment, enzymatic saccharification, and fermentation of yeasts in co-culture. Ethanol fermentation with 14.5% (w/v) seaweed hydrolysate was performed using the yeasts, Saccharomyces cerevisiae KCTC 1126 alone, Pichia angophorae KCTC 17574 alone, and their co-cultures with the yeasts either adapted to mannitol or not. Among the combinations, the co-culture of non-adapted S. cerevisiae and P. angophorae adapted to mannitol showed high bioethanol production of 12.2 g/l and an ethanol yield ($Y_{EtOH}$) of 0.41. Co-culture in the SSF process was employed in this study, to increase the ethanol yields of 35.2% and reduction of 33.3% in fermentation time. These results provide suitable information on ethanol fermentation with marine seaweeds for bioenergy production.