Membrane Journal (멤브레인)

The Membrane Society of Korea (한국막학회)
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Oxygen Permeation Properties of Tubular $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ (BSCF) Membranes under Different Condition of Feed Side and Permeate Side

공급 측과 투과 측 조건에 따른 $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ (BSCF) 관형 분리막의 산소투과 특성

  • Kim, Jong-Pyo (Department of Chemical Engineering, Chungnam National University) ;
  • Park, Jung-Hoon (Greenhouse Gas Research Center, Climate Change Technology Research Division, Korea Institute of Energy Research) ;
  • Lee, Yong-Taek (Department of Chemical Engineering, Chungnam National University) ;
  • Choi, Young-Jong (INNO WILL Corp.)
  • Received : 2011.04.23
  • Accepted : 2011.06.21
  • Published : 2011.06.30
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Abstract

Dense tubular $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ (BSCF) membranes were prepared by extrusion technique. The phase structure of the $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ membranes was characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). Relative density of $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ tubular membrane was 94.10%. Oxygen permeation was measured at difference operating condition of feed side and permeate side in the temperature range from 700 to $950^{\circ}C$. The oxygen permeation flux of dense tubular $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ membrane reached maximum 1.37 mL/$min{\cdot}cm^2$ at $900^{\circ}C$ exposed to ambient air (feed side) and vacuum pump (permeate side).

$Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ (BSCF) 조성을 갖는 치밀한 관형 분리막은 압출 성형 방법으로 제조하였다. $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ 관형 분리막의 구조적 특성은 x-선 회절분석기 (XRD)와 전자 주사 현미경 (SEM)을 이용하여 분석하였으며, 상대밀도는 94.10%를 보였다. 산소투과량 분석은 700~$950^{\circ}C$ 범위에서 공급 측과 투과 측의 운전조건에 따라 측정되었다. 공급 측과 투과 측에서 대기 중 공기와 진공펌프를 사용할 경우, $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ 관형 분리막의 산소투과량은 $900^{\circ}C$에서 1.37 mL/$min{\cdot}cm^2$로 높게 나타났다.

Keywords

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