• Title/Summary/Keyword: $CO_2$ 가스화

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TiN and TiC Gas Alloying of Ti-6Al-4V Alloy by CO2 Laser (CO2 레이저를 이용한 Ti-6Al-4V합금의 TiN 및 TiC 가스 합금화)

  • Song, K.H.;Lee, O.Y.
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.3
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    • pp.177-186
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    • 1996
  • Surface alloying of Ti alloy by $CO_2$ laser is able to produce few hundred micrometers thick TiN or TiC surface-alloyed layer with high hardness on the substrate by injecting reaction gas($N_2$ or $CH_4$). Laser surface alloying by means of process control is in many applications essential in order to obtain predictable hardening layer. This research has been investigated the effect of such parameters on TiN and TiC gas alloying of Ti-6Al-4V alloy by $CO_2$ laser. The maximum surface hardness of TiN layer was obtained 1750Hv on the conditions of 0.8kW laser power, 0.8m/min scanning speed and 100% $N_2$ atmosphere. However, the maximum hardness of TiC formation layer after laser treatment was about 630Hv. As scanning speed was increased, the hardness and depth of these layers were decreased at constant laser power.

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Preparation of Silicon Tetrachloride by Chlorination of Silicon (실리콘의 염소화반응에 의한 사염화규소 제조)

  • Park, Kyun Young;Lee, Mi Sun;Kim, Min Cheol;Lee, Chan Hee;Park, Hoey Kyung;Kang, Tae Won;Jeong, Hae Seong;Han, Kyoung Ah;Huh, Weon Hoe;You, Ji Cheol
    • Korean Chemical Engineering Research
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    • v.51 no.3
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    • pp.407-410
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    • 2013
  • The chlorination of a metallurgical-grade silicon was carried out in a fluidized bed reactor, 25 mm in diameter. The flow rate of the chlorine admitted into the reactor was 0.2 L/min and that of the carrier nitrogen was 0.8~1.0 L/min. The reactor temperature was maintained at $450^{\circ}C$ and the temperature of the coolant at the $SiCl_4$ condenser was at $-5^{\circ}C$. The $SiCl_4$ yield increased with increasing the mole fraction of chlorine in the feed gas, exhibiting 28% at the mole fraction of 0.2. Further increase of the chlorine mole fraction was not attempted in a worry that the reactor might be failed due to the high exothermicity of the reaction. The production of $SiCl_4$ from silicon by fluidized bed chlorination was demonstrated on a laboratory scale, which is a stepping stone for future studies under more severe conditions toward industrial application.

Effect of C-Content for Ti Surface-Alloying Treatment on Steel by $CO_2$ Laser Beam (레이저 빔에 의한 철강재의 Ti 표면합금화에 미치는 C함량의 영향)

  • Choe, Jun-Yeong;Kim, Do-Hun
    • Korean Journal of Materials Research
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    • v.2 no.6
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    • pp.436-442
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    • 1992
  • When $N_2$was used as shielding gas during the formation of Ti surface-alloyed layer by irradiation of $CO_2$laser beam on steel, TiN and F$e_2$Ti were formed regardness of carbon-content in steel. When Ti content was increased in low carbon-content steel, formation of martensitic structure was suppressed due to increase of critical cooling rate for martensitic transformation. In case of high-carbon steel, even though Ti content was about 1.5% in alloyed layer, hardness was increased by formation of martensitic structure instead of ferrite. In addition to that structure, hardness was incrreased further by precipitation of TiC in Ti alloyed-layer of high carbon-steel.

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Carbon Capture and CO2/CH4 Separation Technique Using Porous Carbon Materials (다공성 탄소재료를 이용한 CO2 포집 및 CO2/CH4 분리 기술)

  • Cho, Se Ho;Bai, Byong Chol;Yu, Hye-Ryeon;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.22 no.4
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    • pp.343-347
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    • 2011
  • Due to the strong dependence on fossil fuels within the history of human progress, it leads to disaster of the whole world like flood, shortage of water and extinction of the species. In order to curb carbon dioxide emissions, many technologies are being developed. Among them, porous carbon materials have important advantages over other absorbent, such as high surface area, thermal and chemical resistance, low cost, various pore distribution and low energy requirement for their regeneration. Carbon capture and storage (CCS) has attracted the significant research efforts for reducing green house gas emission using several absorbent and process. Moreover, the absorbent are used for the separation of bio mass gas that contains methane which is considered a promising fuel as new green energy resource. In this review, we summarized the recent studies and trend about the porous carbon materials for CCS as well as separation from the biogas.

초정밀기술과 옵토메카트로닉스부품의 현황과 과제

  • Korea Optical Industry Association
    • The Optical Journal
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    • s.97
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    • pp.62-66
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    • 2005
  • 본 고는「특집: 여러 가지 초정밀기술을 응용한 옵토메카트로닉스부품화기술」이라는 주제로 일본 광기술콘택트지 (Vol. 42, No. 12(2004년), 637~641쪽)에 게재됐던 카사이 도시오(河西敏雄)씨가 기고한 내용을 번역, 정리한 것으로 초정밀기술과 옵토메카트로닉스부품의 현황과 과제에 관해 간단히 논하였다. 산업계에서 신문보도등에 의하면 교또의정서의 발효는, 러시아의 기준에 의해 2005년 2월경이라고 한다. 지금까지 앞서간다고 여겨져 왔던 엄한 CO가스의 삭감규제가 드디어 아주 가깝게 대두되었다. 환경문제로 지구온난화를 조금이라도 억제하려는 기업 노력이 추진되어 왔지만, 금후의 초정밀기술 및 옵토메카트로닉스부품·시스템에 대해서도 이를 염두에 둔 새로운 기술전개가 시작될 것으로 예상된다.

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Characteristics Evaluation of Combustion by Analysis of Fuel Gas Using Refuse-derived Fuel by Mixing Different Ratios with Organic and Combustible Wastes (배연가스 분석에 의한 가연성과 유기성폐기물을 혼합한 고형화연료 연소 특성평가)

  • Ha, Sang-An
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.3
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    • pp.27-39
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    • 2009
  • The main objective of this study is to investigate the characteristics of combustion by analyzing fuel gases from a combustion equipment with various combustion conditions for refuse-derived fuels (RDFs). CO gas is a parameter for indicating of incomplete combustion during a combustion process. The lowest CO gas was produced when the experiment conditions were m=2 under air-fuel condition and $800^{\circ}C$. $CO_2$ gas is a final product after complete combustions. The highest amount of $CO_2$ gas was produced when the experiment conditions were m=2 under air-fuel condition and $800^{\circ}C$. The highest level of $SO_2$ gas was produced in S.1 sample containing the highest sulfur. The highest level of NOx gas was produced in S.1 sample with the highest nitrogen content and air-fuel condition of m=2 under temperature of $800^{\circ}C$. HCl gas that is generated by reacting with metals catalyst through oxygen catalyst reaction during combustion process is a precursor of dioxin formation. The higher level of HCl gas was produced in the sample with higher chlorine content. The lowest level of HCl gas was produced when the experiment conditions were air-fuel condition of m=2 and $800^{\circ}C$. The lowest level of $NH_3$ gas was generated when the experiment condition was m=2 under air-fuel condition and after 3 minutes. Air-fuel condition is more important to create $NH_3$ gas than operating temperatures. Higher level of $H_2S$ gas was generated in S.1 sample with the higher sulfur content and was created in RDFs that contain higher mixture ratios of sewage sludge and food wastes. A result of combustion, gases and gases levels from the combustion of S.1 and S.2 were very similar to the combustion of a stone coal. As results of this research, when evaluating the feasibility of the RDFs, the RDFs could be used as auxiliary and main fuels.

Research on manufacturing secondary construction products using in-situ carbonation technology (In-situ 탄산화 기술이 적용된 콘크리트 2차제품 제조 연구)

  • Hye-Jin Yu;Sung-Kwan Seo;Woo-Sung Yum
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.6
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    • pp.226-233
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    • 2023
  • In this study, the basic physical properties and microstructure of concrete interlocking blocks with amount of different CO2 gas injection were analyzed according to determine the applicability of In-situ carbonation technology to construction secondary products. The amount of carbon dioxide gas injection was selected as 0, 0.1, 0.3, 0.5, 0.7 wt.% compared to cement amount. A lab-scale press equipment was designed to apply developed carbonation technology to real construction site. And mixer for stable CO2 gas injection was designed. Using the designed devices, CO2 gas injected samples were created and physical property of samples were performed. As a result of the physical property test, as the CO2 injection amount increased to 0.3 %, it showed higher strength behavior compared to the original mix. And more than 0.5 % samples showed lower strength behavior than original sample, but they satisfied the standard of concrete interlocking block. This results were determined that CO2 injection contributed to the creation of hydrates such as C-S-H. Therefore, the possibility of applying carbonation technology, which injects CO2 during mixing, to various secondary construction products was confirmed.

Preparation of Fe/$Al_2O_3$ Granules for Conversion of Syngas to Light Olefins by Fischer-Tropsch Reaction (합성가스에서 경질올레핀 제조를 위한 피셔-트롭시 반응용 구형 철-알루미나 촉매 합성)

  • Lee, Dong-Joon;Jung, Kwang-Deog;Yoo, Kye-Sang
    • Applied Chemistry for Engineering
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    • v.21 no.3
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    • pp.333-336
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    • 2010
  • Fe/$Al_2O_3$ granules with various compositions were prepared by combining sol-gel with oil drop method for Fishcer-Tropsh reaction to produce light olefin from synthesis gas. The granules was characterized and employed as a catalyst in the reaction. The surface area of granules was decreased with increasing Fe concentration. Especially, granule with 1.5 of Al/Fe ratios showed the highest CO conversion. However, the olefin selectivity was hardly affected by Al/Fe ratio. K concentration of granule gave a significant effect on catalytic performance. Initial CO conversion and olefin selectivity were increased with K concentration. However, the catalyst with higher K concentration was deactivated rapidly.

Design of Digital Controller for Thyristor Controlled Arc Welding Machine (제어 정류형 아크 용접기의 디지털 제어기 설계)

  • 우동학;채영민;한석우;최규하;한광수;안기은
    • The Transactions of the Korean Institute of Power Electronics
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    • v.3 no.2
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    • pp.92-98
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    • 1998
  • With the development of semiconductor devices, adoption of microcontroller prevails in industrial area. But in are welding industry, there has not been much progress in adoption of microcontroller technology. Therefore, this paper shows the application of digital control technology to welding machine. This paper presents the design of microcontroller that is appropriate for three phase $CO_2$ gas metal are welding machine. By using microcontroller in $CO_2$ gas metal are welding machine, the overall cost can be reduced compared to analog comtroller. Also TMS370C850 microprocessor is used as overall microcontroller for the are welding machine.

Combustion Characteristics of Synthetic Gas from Flame Pyrolysis Gasification of Polymetric Wastes and their Applicability to Gas Engine System (합성고분자류 폐기물의 화염열분해 가스화에 의한 발생가스의 연소특성 및 가스엔진시스템에의 적용연구)

  • Kim, Tae Kwon;Jang, Jun Young;Shim, Sung Hoon;Kim, Jeung Bea;Kim, Byung Ha
    • Journal of Hydrogen and New Energy
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    • v.10 no.4
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    • pp.233-243
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    • 1999
  • Combustion characteristics of synthetic gas from flame pyrolysis gasification of polymetric wastes are reported and the applicability of synthetic gas from flame pyrolysis gasification to a gas engine system is presented. Engine power is easily predicted by the volume percentage of the synthetic gas. Measurements have been made to obtain the range of flame existence in the function of volume percentage of CO and $H_2$ gases in the synthetic gas. In order to clarify the emission of the flames, NOx measurements by chemiluminescent analyser are taken in flames with different equivalent ratios. From the results of the engine performance data we also have demonstrated that the output of the gas engine modified from a LPG engine is about 5 ps at normal rating. We conclude that synthetic gas from flame pyrolysis gasification of polymetric wastes is applicable to a gas engine system.

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