• Title/Summary/Keyword: $CH_4/H_2$ flame

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Flamelet Modeling of Structures and $NO_{x}$ Formation Charateristics in Bluff-Body stabilized Methanol Flames (메탄올 Bluff-Body 난류 화염내의 화염구조 및 $NO_{x}$ 생성 특성에 대한 수치적 연구)

  • Lee, Joon-Kyu;Kim, Seoung-Ku;Kim, Yong-Mo;Kim, Sae-Won
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.37-42
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    • 2001
  • This paper computes the bluff-body stabilized jet and flame. This study numerically investigates the nonpremixed $C_{2}H_{4}-air$ jet for the nonreacting case and the nonpremixed $CH_{3}OH-air$ turbulent flames for the reacting case using the laminar flamelet model on modified KIVA2 code. And this study predicts $NO_{x}$ formation characteristics using Eulerian Particle Flamelet Model. In the present study, the turbulent combustion model is applied to analyze both nonreacting and reacting case. And both standard $k-{\varepsilon}$ model and modified $k-{\varepsilon}$ model are used in nonreacting case. Calculations are compared with experimental data in terms of velocity, mixture fraction, mixture fraction Root Mean Square and Temperature. The present model correctly predicts the essential features of flame structures and $NO_{x}$ formation characteristics in the bluff-body stabilized flames.

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The Effect of Mixture Component in a Gasoline Engine on Combustion (The Effect of Combustion Velocity) (가솔린 기관(機關)의 혼합기(混合氣) 성분(成分)이 연소특성(燃燒特性)에 미치는 영향(影響) (연소(燃燒) 속도(速度)에 미치는 영향(影響)))

  • Song, J.I.
    • Journal of ILASS-Korea
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    • v.2 no.4
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    • pp.47-53
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    • 1997
  • By using a premixed laminar burner, the effect of mixture component on laminar burning velocity($S_L$) was investigated. The following was made clear ; (1)As the humidity$(H_2O)$, $CO_2$ and Ar in mixture is increased, $S_L$ decreased in proportion to quantity of those dilution gases. (2) The heat reaction theory says that mean thermal conductivity $(\lambda_m)$, specific heat $(C_{pm})$ of mixture and adiabatic flame temperatures $(T_b)$ affect $S_L$. As a result of theoretical analysis, the effect of $\lambda_m\;and\;C_{pm}$ on $S_L$ is less than 1/25 of the effect of $T_b$, so the effect of $\lambda_m\;and\;C_{pm}$ can be ignored. (3) From experimental results, it was confirmed that $\ln(S_L)$ is proportional to $(1/T_b)$, that is, the effect of $H_2O$ on $S_L$ is mainly caused by changes of $T_b$. This conclusion was verified by the fact increases of $H_2O,\;CO_2$ and Ar decrease the intensity of radiation typical $C_2$, CH, and OH in the same manner.

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Effects of various densities and velocities on gaseous hydrocarbon fuel on near nozzle flow field under different laminar coflow diffusion flames

  • Ngorn, Thou;Jang, Sehyun;Yun, Seok Hun;Park, Seol Hyeon;Lee, Joo Hee;Chung, Suk Ho;Choi, Jae Hyuk
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.2
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    • pp.102-106
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    • 2016
  • An experimental study on the flow characteristics under various laminar coflow diffusion flames was conducted with a particular focus on the buoyancy force exerted from gaseous hydrocarbon fuels. Methane ($CH_4$), ethylene ($C_2H_4$), and n-butane ($C_4H_{10}$) were used as the fuels. A coflow burner and the Schlieren imaging technique were used to observe the flow field of each fuel near the nozzle exit as well as the flow characteristics in the flames. The results show that a vortex with a density heavier than air appeared in n-butane near the nozzle exit with a strong negative buoyancy on the fuel steam. As the Reynolds number increased through the control of the fuel velocity of the n-butane flame, the vortices were greater and the vortex tips were moved up from the nozzle exit. In addition, the heated nozzle affected the flow fields of the fuel steam near the nozzle exit.

Numerical Investigation of Low-pollution Combustion with applying Flue Gas Recirculation in Counterflow Flames: Part I. Combustion Characteristics of Low NOx (대향류 화염에서 FGR이 적용된 저공해 연소의 수치적 해석: Part I. 저 NOx 연소특성)

  • Cho, Seo-Hee;Lee, Kee-Man
    • Journal of the Korean Institute of Gas
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    • v.23 no.6
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    • pp.8-16
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    • 2019
  • One of the methods for low-pollution combustion, flue gas recirculation(FGR) is effective to reduce nitrogen oxides and it was applied in CH4/air premixed counterflow flames to identify the change of flame characteristics and NOx mechanisms. Considering that the mole fraction of the products varied depending on the strain rates, the major products: CO2, H2O, O2 and N2 were recirculated as a diluent to reflect the actual combustion system. With the application of the FGR technique, a turning point of maximum flame temperature under certain strain rate condition was found. Furthermore as the recirculation ratio increased, the tendency of NO was changed before and after the turning point and the analysis on thermal NO and Fenimore NO production was conducted.

The Effects of N2 Diluent and Preheated Air on Soot Emission in Laminar Diffusion Flames (층류확산화염에서 질소 첨가와 예열온도가 매연 생성에 미치는 영향)

  • Jeong, Yong-Ki;Lee, Jong-Ho;Jeon, Chung-Hwan;Jang, Young-June
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.1
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    • pp.1-8
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    • 2004
  • An study has been performed with axisymmetric coflow diffusion flames to investigate the influence of air-side fuel side dilution and initial preheated temperature on the soot formation in methan/air flames. Soot quantities are determined by using PLII(Planar Laser Induced Incandescence), such a $C_2$H$_2$ major species(CH$_4$, $O_2$, $N_2$) and temperature are simulated by chemkin code. The numerical analysis was performed with transport properties and detailed reaction mechanisms m axisymmetric coflow diffusion flames. The study of how flame temperature and $N_2$ dilution of air and fuel side influence the soot concentrations is focused. Soot concentrations results on PLII show that preheated temperature contributes to an increase in the soot volume fraction, and soot formation Is more productive to air side dilution than to fuel side dilution. $C_2$H$_2$ concentrations have a similar tendency to soot concentrations.

Numerical Investigation of Low-pollution Combustion with applying Flue Gas Recirculation in Counterflow Flames: Part II. Analysis of NOx formation mechanism (대향류 화염에서 FGR이 적용된 저공해 연소의 수치적 해석: Part II. NOx 생성기구 분석)

  • Cho, Seo-Hee;Kim, Gyeong-Mo;Lee, Kee-Man
    • Journal of the Korean Institute of Gas
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    • v.24 no.4
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    • pp.39-47
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    • 2020
  • Flue gas recirculation(FGR) is an effective combustion technique for reducing nitrogen oxides(NOx) and is applied in various fields of low-pollution combustion. Continuing the previous study, a numerical analysis was conducted to identify changes of flame characteristics and NOx formation mechanism with applying FGR technique in CH4/air premixed counterflow flames. NOx emitted was divided into four main reaction paths(thermal NO, prompt NO, N2H and N2O), showing relatively the production rate of NO with the recirculation ratio. As a result, thermal NO contributed greatly to the overall NO whereas the effect of N2H was minimal. In addition, emission index of NO was compared as the recirculation ratio increased by modifying the UC San Diego mechanism to examine the contribution of thermal NO.

A Study on the Safe Gap for Explosion-proof (내압방폭을 위한 Safe Gap의 측정에 관한 연구)

  • Oh Kyu-hyung
    • Journal of the Korean Institute of Gas
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    • v.1 no.1
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    • pp.1-6
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    • 1997
  • In case of using the electrical apparatus in the hazardous atmosphere which exist flammable gas mixtures, There is a dangerosity of gas explosion accident by the electrical spark. The most general method to prevent the explosion by the spark is to use the flame-proof type electrical apparatus to isolate the ignition source. from the flammable atmosphere. But actualy it is impossible to isolate the ignition sources from the atmosphere. So it was needed to find the safe gap which prevent ignition of flammable atmosphere by transmission of flame or heat when a flammable gas mixture exploded inside the apparatus. In this study we tried to find the maximum experimental safe gap(MESG) of $H_2$-air, and $CH_4$-air mixtures by using the 8 litre spherical vessel with 25mm flange. The experiment parameter were ignition position, concentration and initial pressure before explosion. From the experiment the ignition position was affected to the MESG. MESG value was minimum near the stoichiometric concentration of gas mixtures, and according to the increase of initial pressure MESG was decreased.

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Numerical and Experimental Studies on the NOx Emission Characteristics of CH4-Air Coflow Jet Flames (CH4-공기 동축 제트화염의 NOx 배출특성에 관한 수치 및 실험적 연구)

  • Kim, Jong-Hyun;Oh, Chang-Bo;Lee, Chang-Eon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.11
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    • pp.1531-1541
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    • 2002
  • The NOx emission characteristics of C$H_4$-Air coflow jet flames were numerically and experimentally investigated. NOx was measured using a chemiluminescent detection and calculated by the parabolic -type equation solver with a detatiled NOx chemistry. The fuel flow rate( $Q_{F}$), the diameter of mixture nozzle and the equivalence rate(Ф) were varied to discuss the EINOx of each flames at the various combustion conditions. The NOx emission index(EINOx) was introduced to quantify the NOx emission from the parametrically varied flames. The results show that Prompt EINOx increases on a logarithmic profile with increasing ${\Phi}$ and keeps nearly constant for the variation of $Q_{F}$. Thermal EINOx reaches the maximum value at around ${\Phi}$ =1.5 and then slowly decrease for ${\Phi}$ >1.5. In addition, Thermal EINOx increases with increasing $Q_{F}$, but nearly indifferent to the variation of the mixture nozzle diameter. Total EINOx also shows a peak at around ${\Phi}$ =1.5, followed by a relatively sharp decrease for 1.5< ${\Phi}$ <2.5 and increase slowly for 2.5 < ${\Phi}$ < $\infty$ The present Total EINOx trend is well explained by a combination of above Thermal and Prompt EINOx trend with the variation of ${\Phi}$ n of ${\Phi}$.

Temperature and Concentration measurement using Semi-conductor diode laser (반도체레이져를 이용한 온도 및 농도의 계측)

  • Chung, D.H.;Noh, D.S.;Ikeda, Yuji
    • 한국연소학회:학술대회논문집
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    • 2000.12a
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    • pp.168-174
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    • 2000
  • A diode laser sensor system based on absorption spectroscopy techniques has been developed to measure $CO_2$ concentration and temperature non-intrusively in high temperature combustion environments using a 2.0 ${\mu}m$ DFB(Distributed Feedback) laser. Two optics was fabricated in pig-tail fashion and all optical components were implemented in a single box. The evolution of measurement sensitivity was done using test cell by changing sweep frequency and $CO_2$ concentration. Gas temperature was determined from the ratio of integrated line strengths. Species concentration was determined from the integrated line intensity and the measured temperature. The result show that the system has 2% error in wide operation frequency range and accuracy of $CO_2$ concentration was about 3%. The system was applied to measure temperature and concentration in the combustion region of a premixed $CH_4$ +air triangular flame. The measurement results of gas temperature agreed well with thermocouple results. Many considerations were taken into account to reduce optical noise, etalon effect, beam steering and base line matching problem. The evaluations results and actual combustion measurement demonstrate the practical and applicability for in-situ and real time combustion monitoring in a practical system.

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Examination of GC-TD sensitivity for reduced sulfur compounds in relation to temporal stability and reproducibility (환원 황화합물의 열탈착 분석기법에 대한 감도의 경시변화 및 재현성에 대한 연구)

  • Hong, One-Feel;Kim, Ki-Hyun
    • Analytical Science and Technology
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    • v.23 no.1
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    • pp.24-35
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    • 2010
  • To learn more about the calibration properties of reduced sulfur compounds (RSCs) by the combination of gas chromatography(GC)-pulsed flame photometric detector (PFPD) and thermal desorption method, a series of calibration experiments were conducted on the basis of both internal and external calibration approaches. For these experiments, gaseous standards of 4 RSCs ($H_2S$, $CH_3SH$, DMS, and DMDS) were prepared at two different concentration levels of both low (10, 20, 50,and 100 ppb) and high ranges (100, 200, 500, and 1000 ppb) along with $CS_2$ as an internal standard. First, the external calibration results were compared between fixed standard volume (FSV) and fixed standard concentration (FSC) method. Secondly, FSV-based calibration results were compared between external and internal calibration results. As FSV method suffers from sensitivity variations less significantly than FSC, the former is recommended to maintain the consistency in GC-TD sensitivity for RSC analysis. In addition, when the calibration data were examined in terms of RSE between external and internal calibration data, the results were not consistent enough to show improvements in internal method. Hence, diverse efforts are desirable to optimize the reproducibility in terms of GC-TD sensitivity for RSC analysis.