• 한국진공학회지
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• 제3권1호
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• pp.122-129
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• 1994

MWPECVD법으로 CH3CHO-H2 계와 CH4-H2-O2 계로부터 Si 기판 위에 다이아몬드박막을 성장 시키고 성장된 박막을 SEM XRD 및 Raman 분광기로 평가하고 박막과 입자의 성장률을 조사하였다. 마이크로 판전력 950W 반응관압력 80torr 수소유량 200sccm 기판온도 95$0^{\circ}C$ 및 CH3CHO농도 3.5%로 5시간 성장시킨 다이아몬드의 박막성장율은 $4mu$m/hr가 되어고 12%$960^{\circ}C$로 Si기판 위에 5시간 성장시킨 다이아몬드의 박막성장율은 3.2$\mu$m/hr가 되었다.

• 한국가금학회지
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• 제24권3호
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• pp.139-143
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• 1997

This experiment was conducted to investigate the effect of dietary supplemental charcoal(CH) or charcoal extract(CE) on performance and meat quality of broiler chicks for 5 weeks. Basal diets based on corn and soybean meal contained 21% crude protein for the first 3 weeks and 19% for the rest two weeks. Two levels of dietary CH(O, 0.5%) and CE(0, 0.2%) were fed in a factorial design. There were four replicates of 10 chicks each per treatment. An increased growth rate was observed in chicks fed the basal diet supplemented with CE alone. Chicks fed the diet containing both CH and CE tended to depress the growth rate. Dietary supplemental CH and CE improved the feed conversion efficiency compared to the control group, but was not significantly different between them. The abdominal fat(%) of chicks fed CH alone or both CH and CE tended to de-crease without significant difference. The total lipid content of breast meat of chicks fed CE alone showed significant difference among treatments (P

• 한국산업융합학회 논문집
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• 제15권4호
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• pp.95-101
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• 2012

In order to explain observed catalytic reactivity of aminophosphine complexes (seven-membered chelate), total energy, net charge, atomic orbital electron population, HOMO and LUMO energy of free ligands are calculated by PM3 methods of HyperChem 6.0. Free ligands are 1,2-bis{(diphosphino)amino}propane{$H_2PNHCH_2CH(CH_3)NHPH_2$;ligand 1},1,2-bis{(dimenylphosphino)amino}propane{$(CH_3)_2PNHCH_2CH(CH_3)NHP(CH_3)_2$;ligand 2},1,2-bis{(diphenylphosphino)amino}propane{$(C_6H_5)_2PNHCH_2CH(CH_3)NHP(C_6H_5)_2$;ligand 3}. The result showed that ligand 3 is stable than ligand 2 and ligand 1 and ligand 2 is stable than ligand 1 in total energy. Net charge of P atom is changed by H atom, methyl groups and phenyl groups in P atoms. Net charge of N atoms in ligands is nagative. The results of atomic orbital electron population are similar net charge data..

• 환경위생공학
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• 제23권3호
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• pp.39-46
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• 2008

In order to study the estimate of $CH_4$ emission factors in the municipal wastewater treatment plants, the active sludge process, 5-stage process, Denipho process, and SBR process were investigated. When active sludge process, 5-stage process, and Denipho process were used in wastewater treatment plant, the $CH_4$ emission factors were 2.88, 1.61, and 0.57 g-$CH_4/kg$-BOD, respectively. On the other hand, in the case of SBR process, it was 4.14 g-$CH_4/kg$-BOD. These results indicate that SBR process was effective for $CH_4$ emission in municipal wastewater treatment plants. Using the above processes, the methane emission factor and amount of waste water sludge were $4.78m^3/t$ and $12,204,506m^3/yr$, respectively. The remove of BOD was a range of $93.91{\sim}98.63%$.

• Bulletin of the Korean Chemical Society
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• 제5권1호
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• pp.3-16
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• 1984

The effect of solvent on the dipole moments for (chloromethyl) stannanes has been investigated by applying EHT calculation for the isomers of trigonal bipyramidal Sn(Ⅳ)$Cl_4X$ and $Cl_n$Sn(Ⅳ) $(CH_2Cl)_{4-n}$, octahedral Sn(Ⅳ)$Cl_42X$ and $Cl_nSn$(Ⅳ)$(CH_2Cl)_{4-n}$ 2X type complexes in dioxane and ethylacetate solutions (X: dioxane or ethylacetate). For Sn(Ⅳ)$Cl_4$ in dioxane solution, the calculated dipole moment for the trigonal bipyramidal Sn(Ⅳ)$Cl_4X$ type complex [isomer (b)] is closer to the experimental dipole moment than octahedral Sn(Ⅳ)$Cl_4X$2X type complexes. This calculated dipole moment suggests that Sn(Ⅳ)$Cl_4X$ may have the trigonal bipyramidal structure in dioxane solution. However, the calculated dipole moment for octahedral $Cl_3$Sn(Ⅳ) ($CH_2$Cl)2X type complex [Isomer (d)], ClSn(Ⅳ)(CH2Cl)32X type complex [Isomer(k)] and Cl2Sn(Ⅳ)(CH2Cl)22X type complex [Isomer(h)] are closer to the experimental dipole moments than other isomers for octahedral complexes and trigonal bipyramidal complexes. Such theoretical results indicate that $Cl_3Sn$(Ⅳ )($CH_2Cl$), ClSn(Ⅳ)$(CH_2Cl)_3$ and $Cl2Sn$(Ⅳ)$(CH_2Cl)_2$ complexes may have octahedral structures, Isomer(d), (k) and (h) in ethylacetate solution, respectively.

• Korean Chemical Engineering Research
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• 제50권5호
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• pp.802-807
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• 2012

본 연구에서는 메탄으로부터 합성가스를 만드는 자열 개질(Autothermal reforming)반응 특성을 Ni (15 wt%)-Ru (1 wt%)/$Al_2O_3$-MgO 금속모노리스 촉매체와 전기 발열식 촉매를 사용하여 조사하였다. 자체 가동 형 반응기는 자열 개질 반응기에 $700^{\circ}C$ 반응물을 공급하는데 걸리는 start-up 시간이 2분 이내였다. 반응물의 $O_2/CH_4$와 $H_2O/CH_4$ 비가 메탄의 전환율과 반응기의 온도 분포에 미치는 영향은 매우 크다. 반응기의 온도는 $H_2O/CH_4$ 비가 감소할수록 흡열반응에서 발열반응으로 전환되어 증가한다. 또한 $H_2O/CH_4$ 비가 증가함에 따라 수성가스화 전이반응에 의하여 생성물 중에 $CO_2$양이 증가한다. $GHSV=10,000\;h^{-1}$, 반응물 조성($H_2O/CH_4=0.6$과 $O_2/CH_4=0.5$)의 자열 개질반응에서, 97%의 메탄의 전환율을 얻었으며, 반응기의 온도는 $600^{\circ}C$로 유지되었다. 이 반응조건에서 170 cc 금속모노리스 촉매체를 충진한 반응기에서 자열개질 반응으로 생성된 최대 합성가스의 유량은 $0.94\;Nm^3/h$ 이었다.

• Bulletin of the Korean Chemical Society
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• 제5권4호
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• pp.167-169
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• 1984

Analyses of $_1$H-NMR, infrared and electronic spectral data for $[Ir(CH_2 = CHCN)(CO)(P(C_6H_5)_3)_2]ClO_4 (1)$prepared by the reaction of $Ir(OClO_3)(CO)(P(C_6H_5)_3)_2$ with $CH_2 = CHCN$, agree with the suggestion that 1 is a mixture of the nitrogen-bonded acrylonitrile complex, $[(CO)(P(C_6H_5)_3)_2Ir-NCCH = CH_2]ClO_4$ and other compound which may be the C = C ${\Pi}$ -system-bonded acrylonitrile complex, "[(CO)(P(C6H5)3)2Ir-CHCN = CH2]ClO4.

• 한국재료학회지
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• 제25권6호
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• pp.300-304
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• 2015

Nanorod ZnO and spherical nano ZnO for gas sensors were prepared by hydrothermal reaction method and hydrazine method, respectively. The nano-ZnO gas sensors were fabricated by a screen printing method on alumina substrates. The gas sensing properties were investigated for hydrocarbon gas. The effects of Co concentration on the structural and morphological properties of the nano ZnO:Co were investigated by X-ray diffraction and scanning electron microscope (SEM), respectively. XRD patterns revealed that nanorod and spherical ZnO:Co with a wurtzite structure were grown with (100), (002), (101) peaks. The sensitivity of nanorod and spherical ZnO:Co sensors was measured for 5 ppm $CH_4$ and $CH_3CH_2CH_3$ gas at room temperature by comparing the resistance in air with that in target gases. The highest sensitivity to the $CH_4$ and $CH_3CH_2CH_3$ gas of spherical nano ZnO:Co sensors was observed at Co 6 wt%. The spherical nano ZnO:Co sensor exhibited a higher sensitivity to hydrocarbon gas than nanorod ZnO.

• 한국진공학회지
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• 제10권1호
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• pp.104-111
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• 2001

$SiH_4$, $CH_4$, $B_2H_6$ 혼합기체를 이용하여 플라즈마 화학증착법으로 비정질 탄화실리콘(a-SiC:H) 박막을 증착하였다. 기상 doping 농도를 0에서 $2.5\times10^{-2}$ 범위에서 변화시켜 얻은 박막의 물성을 SEM, XRD, Raman 분광법, FTIR, SIMS, 광흡수도와 전기전도도 분석을 통하여 살펴보았다. $B_2H_6$/($CH_4+SiH_4$) 기체유량비가 증가할수록 붕소의 도핑효율와 미세결정성은 감소하였다. 증착 중 $B_2H_6$ 기체가 첨가됨에 따라 비정질 탄화실리콘 박막의 Si-C-H 결합기의 강도는 감소하였으며, 이의 영향으로 박막내의 수소함량은 $B_2H_6/(SiH_4+CH_4$) 기체 유량비가 증가함에 따라 16.5%에서 7.5%로 단조감소하였다. $B_2H_6(CH_4+SiH_4$) 기체유량비가 증가할수록 a-SiC:H 박막의 광학적 밴드갭과 전기활성화 에너지는 감소하였고, 전기전도도는 증가하였다.

• 공업화학
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• 제3권4호
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• pp.639-648
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• 1992

시멘트 수화물(CH)을 모르타르 콘크리트용 방수제 또는 고무 플라스틱용 충전제로 활용하기 위하여 스테아린산(SA)으로 처리하고 FT-IR, TGA, SEM, XRD, 접촉각층정기 등을 이용하여 CH-SA compound의 결합특성과 발수성을 측정하고, CH-SA compound를 레미탈에 사용하여 레미탈의 방수성을 알아 본 결과는 다음과 같이 요약된다. 1) 시멘트 수화물에 스테아린산을 2.0%이상만 처리하면 물레 대한 접촉각이 $120^{\circ}$이상으로 증가되면서 강한 발수성을 나타낸다. 2) 시멘트 수화물에 처리된 스테아린산은 스테아린산염 형태로 시멘트 수화물 표면에 고정된다. 3) 시멘트 수화물에 스테아린산을 5~10%처리한 CH-SA compound를 레미탈 중량의 3~6%정도 사용하면 레미탈의 압축강도는 5%정도 증가되며, 흡수비와 투수비는 각각 25%이하로 격감되어서 우수한 방수성을 나타낸다.