• 한국환경과학회지
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• 제23권11호
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• pp.1953-1961
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• 2014

Increasing public concerns over odors and air regulations necessitates the remediation of a wide range of odor substances for industrial and indoor purpose. Currently, the wet scrubbing technique by neutralization using oils is being used to treat odor substances such as Ammonia($NH_3$), Methyl Mercaptan($CH_3SH$), Hydrogen Sulfide($H_2S$), Methylamine($CH_3NH_2$), Acetaldehyde($CH_3CHO$). The chemical analysis is performed to analyze the composition of an Arctium Lappa Root extract by VOC analyzer(Phocheck 5000Ex, ION SCIENCE co.) The objectives of the this study are to clarify the possibility of the neutralization of odors sprayed in the fixed bed and determine the removal efficiencies for different input odor concentrations. It is found that Ammonia($NH_3$), Methyl Mercaptan($CH_3SH$), Hydrogen Sulfide($H_2S$), Methylamine($CH_3NH_2$), Acetaldehyde($CH_3CHO$) are significantly removed and their removal efficiencies are higher than 98%. The kitchen detergent with Arctium Lappa Root extract showed excellent removal efficiencies of odor substances and high possibility for the development of kitchen detergent with odor removal.

• Bulletin of the Korean Chemical Society
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• 제5권5호
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• pp.199-201
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• 1984

It has been found that $Rh(ClO_4)(CO)(P(C_6H_5)_3)_2$ catalyzes the hydrogenation and isomerization of soybean oil at room temperature under the atmospheric pressure of hydrogen. The hydrogenation occurs at the olefinic groups to produce saturated groups leaving the ester groups intact, and the isomerization converts $-CH = CH- CH_2-CH = CH-$ units to conjugated dienes and the dienes separated by more than two $-CH_2-$ groups. The rate of the hydrogenation is faster than that of the isomerization.

• Bulletin of the Korean Chemical Society
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• 제29권11호
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• pp.2273-2276
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• 2008

• 대한화학회지
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• 제25권5호
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• pp.311-317
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• 1981

새로운 니켈(II) 화합물, 비스(트리메틸실릴메틸)1,2-(비스디페닐포스피노) 에탄니켈(II)(1)이 디클로로-1,2-비스(디페닐포스피노)에탄니켈(Ⅱ)와 트리메틸실릴메틸리튬의 반응으로부터 합성되었다. 화합물 1은 질소하, 상온에서 안정하다. 화합물 1은 열분해하여 환원성짝지음 생성물, 1,2-비스(트리메틸실릴)에탄을 생성한다. 화합물 1은 상온에서 일산화탄소 및 산소와, 그리고 80${\circ}$C에서 1,2-비스(디페닐포스피노)에탄과 반응하여 역시 1,2-비스(트리메틸실릴)에탄을 생성한다.

• 한국식품과학회지
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• 제35권6호
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• pp.1188-1192
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• 2003

새우나 게 껍질로부터 chitin을 유일한 탄소원으로 하는 집적배양에 의하여 chitinase 활성이 우수한 균주를 2종 분리하였다. 분리균주는 형태학적, 그람염색, 16s rDNA 서열분석을 통하여 Arthrobacter nicotianae로 동정되어, 각각 Arthrobacter nicotianae CH4와 Arthrobacter nicotianae CH13으로 명명하였다. 두 종의 분리균주로부터의 chitinase는 모두 pH $3.0{\sim}9.0$에서 90% 이상의 효소활성을 유지하여 높은 pH안정성을 나타내었다. 온도의 영향은 $20{\sim}60^{\circ}C$ 구간에서 최적 효소 활성의 $70{\sim}90%$를 유지하여 열안정성도 뛰어났다. A. nicotianae CH4와 A. nicotianae CH13이 분비하는 chitinase 조효소를 0.1% colloidal chitin 기질에 반응시켜서 반응산물로 생산되는 chitin 올리고당을 HPLC를 사용하여 분석하였다. A. nicotianae CH4 조효소에 의한 효소반응산물로는 올리고머인 $(GlcNAc)_4$이, A. nicotianae CH13는 단량체인 $(GlcNAc)_1$이 전체 반응산물의 각각 98% 이상 생성되었다.

• 약학회지
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• 제51권6호
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• pp.495-499
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• 2007

Seven epoxy- and hydroxyandrostane derivatives ($DH-1{\sim}DH-7$) and nine epoxy- and hydroxycholestane derivatives ($CH-1{\sim}CH-9$) with unsaturation in ring A and ring B were synthesized from DHEA and cholesterol, respectively. The antinociceptive effects of all synthesized compounds were measured by hot plate method. Most of androstane derivatives except $1{\alpha},2{\alpha}$-epoxy-4,6-androstadiene-3,17-dione (DH-3), and CH-6, CH-7 and CH-9 exhibited antinociceptive effect. 1,4-Androstadiene-$3{\beta},17{\beta}$-diol (DH-5, 100 mg/kg, $35.8{\pm}7.39$), $6{\alpha},7{\alpha}$-epoxy-1,4-androstadiene-3,17-dione (DH-4, 100 mg/kg, $32.6{\pm}5.50$) and $5{\alpha},6{\alpha}$-epoxy-17-oxo-androstan-$3{\beta}$-ol (DH-1, 100 mg/kg, $32.5{\pm}2.98$) were more effective than morphine (10 mg/kg, $30.6{\pm}0.5$). The analgesic effects of androstane derivatives on acetic acid writhing in mice were lower than aspirin. The androstane derivatives were less effective than ibuprofen at inhibiting effects on the carrageenin induced paw oedema. 4,6-Cholestadien-$3{\beta}$-ol (CH-5), $1{\alpha},2{\alpha}$-epoxy-4,6-cholestadien-$3{\beta}$-ol (CH-7) and $7{\alpha}$-hydroxy4-cholesten-3-one (CH-9) showed the decrease of serum triglyceride and total cholesterol levels in poloxamer P-407 injected rat.

• 한국태양에너지학회 논문집
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• 제23권2호
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• pp.71-79
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• 2003

The goal of this paper is to measure and compare the performance of solar heat pump for refrigerants. To accomplish the goal, solar heat pump with aluminum roll bond type evaporator and indoor heat exchanged(condenser) was built. The test results showed that the COP and heating capacity of HFC-32/125/134a(23/25/52 wt%, $CH_2F_2/CF_3CHF_2/CF_3CH_2F$) were higher than those of HCFC-22$(CHClF_2)$. A study proved that best conditions to use heating system that is about $40m^2$ and $80m^2$. The COP range of the whole system was from 4 to 6 according to the solar collector's area variation. Hydrochlo-rofluorocarbon HCFC-22$(CHClF_2)$ is included in the compound to be controlled. HFC-32/125/134a(23/25/52 wt%, $CH_2F_2/CF_3CHF_2/CF_3CH_2F$) is the most suitable replacement HCFC-22$(CHClF_2)$ in solar heat pump application. The solar heat pump system was designed to show the best efficiency that the room temperature make $18\sim20^{\circ}C$ and $23\sim25^{\circ}C$ in Seoul during the fall season.

• 공업화학
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• 제3권4호
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• pp.639-648
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• 1992

시멘트 수화물(CH)을 모르타르 콘크리트용 방수제 또는 고무 플라스틱용 충전제로 활용하기 위하여 스테아린산(SA)으로 처리하고 FT-IR, TGA, SEM, XRD, 접촉각층정기 등을 이용하여 CH-SA compound의 결합특성과 발수성을 측정하고, CH-SA compound를 레미탈에 사용하여 레미탈의 방수성을 알아 본 결과는 다음과 같이 요약된다. 1) 시멘트 수화물에 스테아린산을 2.0%이상만 처리하면 물레 대한 접촉각이 $120^{\circ}$이상으로 증가되면서 강한 발수성을 나타낸다. 2) 시멘트 수화물에 처리된 스테아린산은 스테아린산염 형태로 시멘트 수화물 표면에 고정된다. 3) 시멘트 수화물에 스테아린산을 5~10%처리한 CH-SA compound를 레미탈 중량의 3~6%정도 사용하면 레미탈의 압축강도는 5%정도 증가되며, 흡수비와 투수비는 각각 25%이하로 격감되어서 우수한 방수성을 나타낸다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 춘계학술대회논문집B
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• pp.949-955
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• 2000

Numerical study with detailed chemistry has been conducted to investigate the NOx formation and structure in $CH_4/Air-CO_2$ counterflow diffusion flames. The importance of radiation effect is identified and the role of $CO_2$ addition is addressed to thermal and chemical reaction effects, which can be precisely specified through the introduction of an imaginary species. Also NO separation technique is utilized to distinguish the contribution of thermal and prompt NO formation mechanisms. The results are as follows : The radiation effect is dominant at low strain rates and it is intensified by $CO_2$ addition. Thermal effect mainly contributes to the changes in flame structure and the amount of NO formation but the chemical reaction effect also cannot be neglected. It is noted that flame structure is changed considerably due to the addition of $CO_2$ in such a manner that the path of methane oxidation prefers to take $CH_4 {\rightarrow}CH_3{\rightarrow}C_2H_6{\rightarrow}C_2H_5$ instead of $CH_4 {\rightarrow}CH_3{\rightarrow}CH_2{\rightarrow}CH$. At low strain rate(a=10) the reduction of thermal NO is dominant with respect to reduction rate, but that of prompt NO is dominant with respect to total amount.

• 대한화학회지
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• 제34권3호
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• pp.227-231
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• 1990

50-100% $CH_3CN-CH_3OH$ 혼합용매계에서 파라-치환된 질산벤질과 아닐린과의 친핵성 치환반응에 대한 2차 속도상수를 전기전도도법으로 구하였다. 속도자료를 이용하여 Hammett ${\rho}_N$과 ${\rho}_C$값, Bronsted $\beta$값 및 용매화 파라미터 계수들을 구하였으며 이들을 PES및 양자역학 모형에 적용하여 구조 변화를 논의하였다. 연구 결과 결합형성보다 결합절단이 비교적 많이 진행된 상태에서 치환기 변화에 따라 결합절단의 진척이 결합형성을 촉진하는 동시적 $S_N2$ 반응메카니즘으로 진행됨을 알았다.