• 한국전기전자재료학회논문지
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• 제33권1호
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• pp.37-44
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• 2020

This study investigated the microstructure and piezoelectric properties of lead-free 0.74(Bi_1/2Na_1/2)TiO₃-0.26SrTiO₃ (BNST26) piezoelectric ceramics sintered using a microwave furnace. For comparison, specimens were also prepared using a conventional furnace sintering (CFS). Average grain sizes of 2.4 ㎛ and 3.2 ㎛ were obtained in the sample sintered at 1,100℃ for 5 min using microwave sintering (MWS) and at 1,175℃ for 2 h using CFS, respectively. To quantify the changes in the microstructures and electrical properties according to the sintering conditions, the polarization hysteresis, bipolar and unipolar strain curves, and temperature dependence of permittivity were evaluated. As a result, it was determined that the P_max (maximum polarization), P_r (remanent polarization) and S_max (maximum strain) values tend to increase with the average grain size. Based on these results, it is concluded that the MWS method can produce lead-free ceramics with superior performance in a relatively short time compared to the conventional CFS method.

• 한국세라믹학회지
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• 제36권8호
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• pp.813-819
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• 1999

Ion implantation, photo-lithography, Ar ion milling과 hot press 법을 이용한 micro-fabrication techrique을 사용하여 고순도 알루미나 단결정인 사파이어의 내부에, 조절된 Ca의 첨가량을 갖고 있는, crack과 비슷한 형태의 기공들을 형성시켰다. 이 bi-cryslal을 각각의 온도에서 열처리하여 Ca 이온이 고온에서 알루미나의 morphology와 hcaling에 미치는 영향을 관찰하였다. 열처리 온도가 올라감에 따라서 crack-like pore의 내부에 hcxagonal bridging ligaments가 생성되었는데, 열처리 온도와 Ca의 첨가량이 증가할수록 크기가 커지는 것을 관찰할 수 있었고, 생성된 hexagonal bndgmg ligaments는 열처리가 진행됨에 따라 서서히 커지면서 모서리가 둥글어지는 현상을 관찰할 수 있었다. Bicrystal 내부에 형성된 crack-like pore는 열처리가 진행되면서 edge regression. ligamcnt growth 및 flow의 3가지의 특징적인 형태로 진행되었다. 이때 edge regression은 상대적으로 저온에서부터 전체 crack-like pore에서 서서히 일어나기 시작하였으며, ligament growth는 일부 crack-like pore에서 진행되있으며, 대단히 빠른 속도로 crack healing이 진행됨을 추정할 수 있었다. Flow는 $1800^{\circ}C$ 이상의 고온에서 모든 crack-like pore에 걸쳐서 느리게 일어남을 알 수 있었다.

• Journal of Electrochemical Science and Technology
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• 제14권1호
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• pp.59-65
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• 2023

Sodium hydroxide solutions are often employed as sterilization agents in the pharmaceutical industry. Here, the chloride content is considered as a critical impurity. In this study, an electrochemical method was developed to remove chloride ions (Cl^-) through the oxidative deposition of AgCl on a Ag anode. The Cl^- content in the commercially available 50% w/w NaOH solution employed was approximately 100 mg Cl^-/kg NaOH. As the OH^- content is approximately 18,000 times higher than the Cl^- content, the formation of AgCl may be expected to be thermodynamically less favorable than the formation of Ag₂O. However, activation energies for AgCl and Ag₂O formation have been reported to be approximately 3.8 and 31.2 kJ/mol, respectively, and indicate that AgCl formation is favored. AgCl can be selectively produced by controlling the anode potential. Here, the Cl^- concentration was reduced to less than 50 mg Cl^-/kg NaOH when an anode potential of 0.18 or 0.19 V vs. Hg/HgO (reference electrode) was applied for one hour at 50℃. XRD analysis and visual monitoring of the Ag anode confirmed the oxidative deposition of AgCl on the anode surface as well as the electrochemical desalination of the concentrated NaOH solution.

• 청정기술
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• 제24권1호
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• pp.27-34
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• 2018

분진과 질소 산화물을 동시에 처리할 수 있는 이원적 기능을 가진 촉매 필터는 산업체 적용에 많은 장점을 갖고 있다. 통기성이 높은 시트 형 세라믹 필터를 촉매 필터 소재로 활용하면 배기가스 처리 공정의 타당성을 더욱 높일 것이다. 그러나 시트 필터는 두께가 얇아서 촉매 지지층에 촉매를 부착할 수 있는 공간이 부족하므로 효과적인 촉매필터를 제조하기가 쉽지 않다. 본 연구에서는 국산 시트 필터를 사용하여 촉매 필터를 제조하고 실험실 장치에서 제조된 촉매 필터의 NO 환원 성능이 평가되었다. 현재 시판되고 있는 시트 필터로 촉매 필터를 제조할 경우 여과속도 $2m\;s^{-1}$에서 700 ppm NO 농도에 대한 NO 전환율이 92% 이하로써 촉매 필터 재료로써 좋은 특성을 나타내지 못했다. 이와 같이 저조한 특성을 보이는 이유는 시트 필터의 촉매 지지층의 기공이 균일하지 못하여 필요 이상의 큰 기공이 존재하기 대문으로 해석되었다. 필터에 존재하는 큰 기공의 사이즈를 줄이기 위하여 필터를 제조하는 원재료에 작은 입자를 혼합하여 시트 필터의 기공을 줄이는 효과를 통하여 NO 전환율 96% 이상을 달성하였다. 또한 촉매 지지체로써 큰 입자의 $TiO_2$를 혼합하여 촉매층의 기공을 팽창시켜서 개선된 촉매 필터는 상용 요구에 충족되는 98% 이상의 NO 전환율을 보였다. 위 두 경우 모두 촉매층 내에 존재할 수 있는 큰 기공을 효과적으로 메워서 적절한 촉매층이 형성되면 촉매 필터의 성능이 향상되는 결과를 보인 것이다. 따라서 이와 같이 통기도가 우수한 장점을 가진 시트 필터가 촉매 필터의 소재로 잘 활용될 수 있음을 보였다.

• 한국세라믹학회지
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• 제35권9호
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• pp.945-952
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• 1998

Ferroelectric Sr0.8Bi2.4Ta2O9 stock solutions were prepared by MOD(Metaloganic Decompostion) process. The phase transformation for the layered perovskite of the SBT thin films by changing RTA(Rapid her-mal Annealing) temperatuer from 700$^{\circ}C$to 780$^{\circ}C$ were observed using XRD and SEM. Layered perovskite phase began to appear above 740$^{\circ}C$ and then SBT thin films were annealed at 800$^{\circ}C$ for 1hr for its com-plete crystallization. The specimens showed well shaped hysteresis curves without post annealing that car-ried out after deposition of Pt top electrode. The SBT thin films showed the asymmetric ferroelectric pro-perties. It was confirmed that the properties were caused by interface effect to SBT and electrode by leak-age current density measurement and asymmetric properties reduced by post annealing. At post annealing temperature of 800$^{\circ}C$ remanant polarization values (2Pr) were 6.7 9 ${\mu}$C/cm2 and those of leakage current densities were 3.73${\times}$10-7 1.32${\times}$10-6 A/cm2 at 3, 5V respectively. Also bismuth bonding types of SBT thin film surface were observed by XPS.

• 구강회복응용과학지
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• 제23권1호
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• pp.79-84
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• 2007

Mineral Trioxide Aggregate(MTA) has been used in Endodontic treatment successfully for more than 10 years. But the high cost of MTA limits its use in endodontics in Korea. Recently many studies have been done to compare MTA and Portland cements. To investigate the chemical constitutions of MTA (Proroot MTA, Tulsa Dental), Gray Portland cement (Lafarge Halla cement), White Portland cement(Union corp), and fast setting cement (SSangyong cement), we performed SEM(scanning electron microscope)(S4700, Hitachi) examination and EDS(Energy dispersive spectrometry)(emax, Horiba) analysis. SEM examination and EDS analysis were committed to and performed in SNU DRI (Seoul National University Dental Research Institute). We found that particles of MTA were relatively round, uniform in size, and compactly packed compared to Portland cements. Chemical constitutions of MTA, GPC, WPC and FSC were similar. It was shown that MTA contains much BiO2 . MTA and WPC showed less heavy metals such as Fe and Mg compared to GPC and FSC. FSC showed remarkably high aluminum content.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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• pp.425-430
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• 2004

In this paper, in order to develop the low temperature sintering ceramics for multilayer piezoelectric transformer, PMN-PZT ceramics were manufactured with the variations of sintering times, and their microstructural, piezoelectric and dielectric properties were investigated. To manufacture multilayer piezoelectric transformer, the low temperature sintering composition is need, hence, $Li_2CO_3$ and $Bi_2O_3$ were used as sintering aids and the specimens were sintered during 30, 60, 90, 120, 150 and 180 minutes, respectively. At the specimen sintered during 90 minute, mechanical quality factor(Qm), electromechanical coupling factor(kp) and dielectric constant were showed the optimum values of 2356, 0.504 and 1266, respectively. All the specimens showed tetragonality phase, and pyrochlore phase was not shown.

• 천문학회보
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• 제37권1호
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• pp.80.1-80.1
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• 2012

NGC 6803 is an elliptical ring shape planetary nebula. We analyzed the high dispersion spectra which had been observed with the Hamilton Echelle Spectrograph attached to the 3-m Shane telescope of Lick Observatory. We also investigated the low dispersion UV spectral data obtained with the 60-cm interstellar ultraviolet explorer. Diverse excitation lines were found from neutral to quadruply ionized ions. The temperature diagnostic lines indicate relatively low electron temperatures, i.e., $T_{\epsilon}{\leq}9500$ K for most lines except for [ClIV] - 11,500 K. In spite of its simplistic bi-laterally symmetrical elliptical shape, the nebula appears to be very complex of a hugh density range from 1300 to 80,000 $cm^3$. A comparison of the two epoch data suggests that the density increase occurred in the high excitation line zone near the inner boundary. We derived the chemical abundances of He, C, N, O, Ne, S, Ar, Cl, and K. The chemical abundances of NGC 6803 are enhanced compared with the average Galactic planetary nebula. Our self-consistent photo-ionization model study implies that the effective temperature of the central star is 90,000 K and its luminosity is 2400 $L_{\odot}$. The evolutionary track suggests that the progenitor of NGC 6803 was about 0.9 -- 1.0 $M_{\odot}$ star, which might be born from a metal-rich zone near the galactic disk, but now relocated into the present high Galactic latitude.

• 식물분류학회지
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• 제43권3호
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• pp.223-226
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• 2013

국내 미기록 식물인 큰해오라비난초[Habenaria dentata (Sw.) Schltr.]를 경상남도 합천군 쌍책면과 가회면에서 확인하였다. 큰해오라비난초는 해오라비난초와 형태적으로 가장 유사한 종으로, 꽃받침이 꽃잎보다 크고 흰색이며, 입술꽃잎 곁갈래 가장자리에 얕게 갈라진 톱니가 있는 특징으로 구분된다. 새로운 국명은 해오라비난초에 비해 개체가 크며, 많은 꽃이 달리는 특징에 따라 '큰해오라비난초'로 하였고, 이에 대한 기재, 도해, 사진 및 유사분류군과의 검색표를 제시하였다.

• 한국전기전자재료학회논문지
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• 제16권10호
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• pp.923-930
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• 2003

We jointed Bi(Pb)-Sr-Ca-Cu-O multifilament tapes and evaluated their electrical and mechanical properties. In order to improve connectivity of multifilaments, one or two single-filament tape was inserted between two multifilament tapes. The critical current ratio(CCR) and n-value of the jointed tapes were evaluated as a function of uniaxial pressure. It was observed that critical current ratio and n-value were 24.8-29.0% and 2.5-2.8 for MM lap-jointed tape. On the other hand, the corresponding values were improved to 24.7-53.9% and 3.1-4.2 for MSM jointed tape, and 63.4-76.0% and 3.4-5.1 for double MS:vr lap-jointed tape, respectively. The highest electrical properties of double MSM lap-jointed tape are considered to be owing to the presence of single core, causing better interconnections of multifilaments between the two tapes. The mechanical property of jointed tape was evaluated and correlated to the microstructural evolution. The strength of jointed tapes was 44-64% less than that of the unjoined tape. The strain tolerance of jointed tape was also reduced compared to that of the unjoined tape. These lower mechanical properties of jointed tape are probably due to the induced nonuniform microstructure such as the existence of cracks and Ag-intrusion in the joined region.