• Title/Summary/Keyword: $Bi_2S_3$

Search Result 698, Processing Time 0.03 seconds

The Growth of Magnetic DyBiIG by sol-gel Method (Sol-gel법에의한 BiDy-철 석류석의 합성)

  • Park, C.M.;Lee, S.H.;Kim, Seung-Hoon;Jang, Hee-Dong
    • Journal of the Korean Magnetics Society
    • /
    • v.13 no.1
    • /
    • pp.36-40
    • /
    • 2003
  • We have grown D $y_{x}$B $i_{3-x}$F $e_{5}$ $O_{12}$ (x = 0.5,1.0, 1.5,2.0) magnetic garnet thin films upon $Al_2$O3i and GGG substrate using Pechini process. The annealing temperature to get single phase D $y_{x}$B $i_{3-x}$F $e_{5}$ $O_{12}$ garnet is dependent on substrate, i.e. the annealing temperature for GGG substrate il 5$0^{\circ}C$ lower than that for $Al_2$ $O_3$ substrate. The grains of garnet thin film grown on GGG (111) plane align along [111] direction, and in this case the hysteresis curve does not saturate up to H : 5000 Oe. We attribute this phenomenon to rotation magnetization process. The maximum amount of Bi substitution in polycrystalline D $y_{x}$B $i_{3-x}$F $e_{5}$ $O_{12}$ thin film prepared by Pechini process is restricted to 2.0 Bi atom/unit cell, and this value is less than that in single garnet crystall grown by LPE method.own by LPE method.ethod.

Chip Breaking Characteristics of S, PbS, and BiS Free Machining Steels (S, PbS 및 Bi S 쾌삭강의 칩절단 특성)

  • Lee, Young-Moon;Bae, Dae-Won;Jang, Jun-Ho
    • Journal of the Korean Society of Manufacturing Process Engineers
    • /
    • v.4 no.2
    • /
    • pp.3-9
    • /
    • 2005
  • In this study, the chip breaking characteristics of S, PbS and BiS free machining steels have been assessed. PbS free machining steel shows the lowest value of chip thickness ($t_c$) under the same cutting conditions. SM10C steel has the largest value of the chip cross-section area ratio ($R_{CA}$). As the feed rate becomes larger the chip breaking cycle time ($T_B$) decreases and the chip breaking index ($C_B$) increases. The properly controlled-C type chip has been obtained with the value of $C_B$ between 0.05 and 0.2. Free machining steel, PbS produces the properly controlled-C type chip in a wider feed rate range than other steels.

  • PDF

Effect of Mg Additive in the Bi1.84Pb0.34Sr1.91Ca2.03Cu3.06O10+δ(110 K phase) Superconductors (Bi1.84Pb0.34Sr1.91Ca2.03Cu3.06O10+δ(110 K 상)산화물 고온초전도체에 Mg 첨가에 따른 영향)

  • 이민수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.16 no.6
    • /
    • pp.522-531
    • /
    • 2003
  • Samples with the nominal composition, B $i_{1.84}$P $b_{0.34}$S $r_{1.91}$C $a_{2.03}$C $u_{3.06}$ $O_{10+{\delta}}$ high- $T_{c}$ superconductors containing MgO as an additive were fabricated by a solid-state reaction method. Samples with MgO of 5~30 wt% each were sintered at 820~86$0^{\circ}C$ for 24 hours. The structural characteristics, critical temperature, grain size and image of mapping with respect to MgO contents were analyzed by XRD(X-Ray Diffraction), SEM(Scanning Electron Microscope) and EDS(Energy dispersive X-ray spectrometer) respectively. As MgO contents increased, intensity of MgO Peaks and ratio of Bi-2212 phase in superconductors intensified and the proportion of the phase transition from Bi-2223 to Bi-2212 was increased.

A Study on the Characteristics of Sn-Ag-X Solder Joint (Sn-Ag-X계 무연솔더 접합부의 미세조직 및 전단강도에 관한 연구)

  • 김문일;문준권;정재필
    • Journal of Welding and Joining
    • /
    • v.20 no.2
    • /
    • pp.77-81
    • /
    • 2002
  • Many kinds of Pb-free solder have been investigated because of the environmental concerns. Sn-Ag-Cu system is well blown as most competitive Pb-free solder. However, since Sn-Ag-Cu system has relatively high melting point compared to Sn-Pb eutectic, it may a limitation, the some application. In this study, Bi and In contained solder of $Sn_3Ag_8Bi_5In$ which has relatively lower melting point, $188~204^{\circ}C$, was investigated. $Sn_3Ag_8Bi_5In$ solder ball of $500\mu\textrm{m}$ diameter was set on the Ni/Cu/Cr-UBM and reflow soldered in the range of $220~240^{\circ}C$ for 5~15s. The maximum shear strength of the solder ball was around 170mN by reflowing at $240^{\circ}C$ for 10s. Intermetallic compound formed on the UBM of Si-wafer was analysed by SEM(scanning electron microscope) and XRD(X-ray diffractometer).

Comparative Studies of Different Thermal Consolidation Techniques on Thermoelectric Properties of BiTeSe Alloy (BiTeSe 합금의 열적성형방법에 따른 열전특성)

  • Sharief, P.;Dharmaiah, P.;Lee, C.H.;Ahn, S.S.;Lee, S.H;Son, H.T;Hong, S.J.
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.31 no.3
    • /
    • pp.126-134
    • /
    • 2018
  • In this research, we produced polycrystalline n-type $Bi_2Te_{2.7}Se_{0.3}$ powder using water atomization. To obtain full benefit through water atomized powder, we have implemented spark plasma sintering and hot extrusion for powder compaction. The microstructure and thermoelectric properties were investigated and compared. The average grain size of SPS and extruded bulks were 3.08 and $3.86{\mu}m$ respectively. The extruded material microstructure contains layered grains with less grain boundaries and its counter-part SPS displays dense packed grains with high grain boundaries. Among both bulks, extrusion sample exhibited high power factor (PF) of $2.96{\times}10^{-3}Wm^{-1}K^{-2}$ which is 38% higher than SPS ($2.14{\times}10^{-3}$) bulk sample. Due to variations in grain size and grain boundaries, the SPS bulk shows low thermal conductivity than extruded bulk. However, the extruded bulk sample exhibited a peak ZT of 0.69 at 400 K, which is 19% higher than SPS bulk sample, due to its higher power factor.

Effect of the Ag Additive on the ${Bi_{1.84}}{Pb_{0.34}}{Sr_{1.91}}{Ca_{2.03}}{Cu_{3.06}}{O_{10+\delta}}$(110K Phase) High-$T_{c}$ Susperconductor (${Bi_{1.84}}{Pb_{0.34}}{Sr_{1.91}}{Ca_{2.03}}{Cu_{3.06}}{O_{10+\delta}}$(110K 상) 산화물 고온초전도체에 미치는 Ag 혼합효과)

  • 이민수;최봉수;최봉수
    • Journal of the Korean Ceramic Society
    • /
    • v.38 no.12
    • /
    • pp.1104-1109
    • /
    • 2001
  • Samples with the nominal composition, B $i_{1.84}$P $b_{0.34}$S $r_{1.91}$C $a_{2.03}$C $u_{3.06}$ $O_{10+}$$\delta$/ high $T_{c}$ superconductors containing As as an additive were fabricated by a solid-state reaction method. Samples with Ag of 10wt%, 30 wt% and 50 wt% each were sintered at 86$0^{\circ}C$~875$^{\circ}C$ for 24 hours. The structural characteristics, critical temperature and grain size with respect to Ag contents were analyzed by XRD(X-ray Diffraction) and SEM(Scanning Electron Microscope), respectively. As Ag contents increased, XRD peaks of g in Bi-2223 phase superconductors intensified and the proportion of the phase transition from Bi-2223 to Bi-2212 was increased.increased.

  • PDF

The Controller Design of Bi-directional DC-DC Converter for a Fuel Cell Energy Storage System (연료전지용 커패시터 충.방전을 위한 양방향 DC-DC 컨버터 제어기 설계)

  • Kim, Seung-Min;Yang, Seung-Dae;Choi, Ju-Yeop;An, Jin-Woong;Lee, Sang-Chul;Lee, Dong-Ha
    • 한국태양에너지학회:학술대회논문집
    • /
    • 2012.03a
    • /
    • pp.222-228
    • /
    • 2012
  • This paper presents a design and simulation of bi-directional DC/DC boost converter for a fuel cell system. In this paper, we analyze the equivalent model of both a boost converter and a buck converter. Also we propose the controller of bi-directional DC-DC converter, which has buck mode of charging a capacitor and boost mode of discharging a capacitor. In order to design a controller, we draw bode plots of the control-to-output transfer function using specific parameters and incorporate 3pole-2zero compensator in a closed loop. As a result, it has increased PM(Phase Margin) for better dynamic performance. The proposed bi-directional DC-DC converter's 3pole-2zero compensation method has been verified with computer simulation and simulation results obtained demonstrates the validity of the proposed control scheme.

  • PDF

A Note on Kruskal's Theorem

  • Lee, Gyesik;Na, Hyeon-Suk
    • Korean Journal of Logic
    • /
    • v.15 no.3
    • /
    • pp.307-322
    • /
    • 2012
  • It is demonstrated that there is a simple, canonical way to show the independency of the Friedman-style miniaturization of Kruskal's theorem with respect to $(\prod_{2}^{1}-BI)_0$. This is done by a non-trivial combination of some well-known, non-trivial previous works concerning directly or indirectly the (proof-theoretic) strength of Kruskal's theorem.

  • PDF

A Study on the Reference Electrode for Al Concentration Sensor in Zinc Galvanizing Melt (용융아연 도금욕중 Al농도 센서의 기준전극에 대한 연구)

  • Jung, W.G.;Jung, S.H.
    • Korean Journal of Materials Research
    • /
    • v.16 no.2
    • /
    • pp.129-136
    • /
    • 2006
  • In order to get basic information on the reference electrode material for the long life Al concentration sensor in zinc galvanizing melt, the workability and stability of fluorine potential cell with $CaF_2$ single crystal electrolyte were examined carefully at constant temperature for six kinds of reference materials (Zn, Sn, Cd, Bi, Pb, Al-Sn alloy + fluorides). Good workability and stability of the sensor were found in sensor with $Bi+BiF_3$ reference electrode. The Al sensor with $Bi+BiF_3$ reference electrode was assembled and was tested in Zn-Al melt with different Al concentration. The EMF was changed rapidly with the change of Al concentration and was stabilized in a short time. Thus the response of EMF was satisfactory for $CaF_2$ sensor. The correlationship between EMF from the sensor and logarithm of Al concentration has been derived from the least square regression method. E/mV=57.515log[wt% Al]+1883.3 R=0.9717 ($0.013{\leq}[wt% Al]{\leq}0.984$) The EMF from Al sensor was increased linearly against logarithm of [wt% Al]. The fluorine potential of Zn-Al melt was also calculated to be in the range of $10^{-60}{\sim}10^{-61}$ Pa for the present experiemental condition.

Study on the fabrication and the growth mechanism of Bi-2223 superconducting phase by diffusion method (확산법에 의한 Bi-2223 초전도상의 제조 및 성장기구에 관한 연구)

  • 최성환;최효상;한태희;황종선;한병성
    • Electrical & Electronic Materials
    • /
    • v.7 no.4
    • /
    • pp.281-288
    • /
    • 1994
  • According to spread volume of B(BiPbCuO) layer, composition ratio and each stage of sintering process, we studied stability of high Tc superconductor phase and generation and growth movement of superconducting phase. The dual layer composed of SrCaCuO and BiPbCuO compound were prepared to develop the Bi-2223 superconductor[108K] through interaction and diffusion during sintering process. The dual layer samples were sintered at 830.deg. C for 0-210 hours. From the result, the optimum conditions were : spread volume(A:B=1:0.6), sintering time(210h) and composition ratio(A:S $r_{2}$C $a_{2}$C $u_{2}$- $O_{x}$, B:B $i_{1.9}$P $b_{0.5}$C $u_{3}$ $O_{y}$) at 830.deg. C.. C.C.C.

  • PDF