Journal of the Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회논문지)

The Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회)
권호 표지
DOI QR코드

DOI QR Code

Effect of Mg Additive in the Bi1.84Pb0.34Sr1.91Ca2.03Cu3.06O10+δ(110 K phase) Superconductors

Bi1.84Pb0.34Sr1.91Ca2.03Cu3.06O10+δ(110 K 상)산화물 고온초전도체에 Mg 첨가에 따른 영향

  • 이민수 (한밭대학교 환경보전방재연구소)
  • Published : 2003.06.01
Download PDF
⟨ Previous Next ⟩

Abstract

Samples with the nominal composition, B $i_{1.84}$P $b_{0.34}$S $r_{1.91}$C $a_{2.03}$C $u_{3.06}$ $O_{10+{\delta}}$ high- $T_{c}$ superconductors containing MgO as an additive were fabricated by a solid-state reaction method. Samples with MgO of 5~30 wt% each were sintered at 820~86$0^{\circ}C$ for 24 hours. The structural characteristics, critical temperature, grain size and image of mapping with respect to MgO contents were analyzed by XRD(X-Ray Diffraction), SEM(Scanning Electron Microscope) and EDS(Energy dispersive X-ray spectrometer) respectively. As MgO contents increased, intensity of MgO Peaks and ratio of Bi-2212 phase in superconductors intensified and the proportion of the phase transition from Bi-2223 to Bi-2212 was increased.

Keywords

References

  1. Appl. Phys. Lett. v.51 no.1 Structure of the single-phase high-temperature superconductor $YBa_{2}Cu_{3}O_{7-d}$ M.A.Beno;L.Soderholm;D.W.Capone Ⅱ;D.G.Hinks;J.D.Jorgensen;J.D.Grace;I.K.Schuller;C.U.Segre;K.Zhang https://doi.org/10.1063/1.98886
  2. Jpn. J. Appl. Phys. v.27 no.10 Preparation of single 110 K phase of the Bi-Pb-Sr-Ca-Cu-O superconductor S.Ko.yama;U.Endo;T.Kawai https://doi.org/10.1143/JJAP.27.L1861
  3. Physica C v.161 no.5&6 Towards the synthesis of the single-phase Bi-2223 superconductor from stoichiometric $(Bi,Pb)_{2}Ca_{2}Sr_{2}Cu_{3}O_{y}$ compositions P.V.P.S.S.Sastry;J.V.Yakhmi;R.M.Iyer https://doi.org/10.1016/0921-4534(89)90401-2
  4. Phys. Rev. B v.41 no.10-A Preparation Process, Crystal Structure, and Physical properties of the 110-K Single-phase Pb-Bi-Sr-Ca-Cu-O Superconductor F.Shi;T.S.Rong;S.Z.Zhou;X.F.Wu;J.Du;Z.H.Shi;C.G.Cui;R.Y.Jin;J.L.Zhang;Q.Z.Ran;N.C.Shi https://doi.org/10.1103/PhysRevB.41.6541
  5. Jouranl of the Korean Ceramic Society v.29 no.2 The effect of sintering time on the stabilization of the Bi-Pb-Sr-Ca-Cu-O superconducting phase K.W.Hyung;S.H.Park;D.W.Lee;T.J.Han;B.S.Choi;C.E.Kim
  6. Physica C v.161 no.5&6 Effect of alkaline metal substitutions to Bi-Sr-Ca-Cu-O superconductor T.Kawai;T.Horiuchi;K.Mitsui;K.Ogura;S.Takagi;S.Kawai https://doi.org/10.1016/0921-4534(89)90390-0
  7. J. Mater. Res. v.7 no.7 Limit of superconductivity in silver/superconductor metal-matrix composites prepared with Bi-Pb-Sr-Ca-Cu-O Ceramic powders A.K.Sarkar;I.Maartense;T.L.Peterson https://doi.org/10.1557/JMR.1992.1672
  8. J. Appl. Phys. v.68 no.2 Investigation of connectivity in silver-ceramic superconductor composites by their field screening property S.Reich;V.M.Nabutovsky
  9. J. Appl. Phys. v.67 no.1 Nonrandom ceramic superconductor-metal composites S.Reich;I.Felner https://doi.org/10.1063/1.345267
  10. Appl. Phys. Lett. v.64 no.1 Influence of Ag-Au and Ag-Cu alloys on $Bi_{2}Sr_{2}CaCu_{2}O_{x}$ superconductor K.Nomura;T.Sasaoka;J.Sato;S.Kuma https://doi.org/10.1063/1.110895
  11. Supercond. Sci. Technol. v.12 Reaction between YBCO/Ag superconductor and melted silver J.Maeda;T.Izumi;Y.Shiohara https://doi.org/10.1088/0953-2048/12/1/008
  12. Physica C v.316 Effect of Ag, $Ag_{2}O$ and $AgNO_{3}$ addition in (Bi,Pb)-2223/Ag Powder-in-tube tapes A.Sobha;R.P.Aloysius;P.Guruswamy;K.G.K.Warrier;U.Syamaprasad https://doi.org/10.1016/S0921-4534(99)00245-2
  13. Applied Superconductivity v.6 no.6 Effect of Ag doping on structure and critical temperature of $Bi_{2}Sr_{2}CaCu_{2}O_{8+8}$ superconductors T.A.Deis;M.Lelovic;N.G.Eror;U.Balachandran https://doi.org/10.1016/S0964-1807(98)00045-3
  14. Physica C v.300 Improvement of formation and superconductivity of the $(BiPb)_{2}Sr_{2}Ca_{2}Cu_{3}O_{x}$ silver-sheathed tape with $B_{2}O_{3}$ addition L.Jiang;Y.Sun;X.Wan;K.Wang;G.Xu;X.Chen;K.Ruan;J.Du https://doi.org/10.1016/S0921-4534(98)00064-1
  15. Physica C v.290 Influences of Cu composition and sintering condition in Bi-2223 tapes using Ag-Cu alloy sheath doped with Ti, Zr or Hf M.Ishizuka;Y.Tanaka;T.Hashimoto;H.Maeda https://doi.org/10.1016/S0921-4534(97)01622-5
  16. Supercond. Sci. Technol. v.15 Effect of Nd substitution for Ca site in the 110 K phase of (Bi, Pb)-Sr-Ca-Cu-O superconductors Min Soo Lee;Ki Young Song https://doi.org/10.1088/0953-2048/15/6/301
  17. Journal of the Korean Ceramic Society v.35 no.1 Variation in the kind of formed superconducting oxide and microstructure with heat-treatment temperature in Yb-Ba-Cu-Ag ribbons M.Y.Song
  18. Journal of the Korean Ceramic Society v.35 no.10 Effect of Na substitution for the Ca Site in the $Bi_{2}Sr_{2}Ca{1-x}Na_{x}Cu_{2}O_{8+y}$ superconductors M.S.Lee;S.Y.Song;C.Y.Lee;K.Y.Song;B.S.Choi
  19. IEEE Transactions on Applied Superconductivity v.9 no.2 Phase stability and grain growth in an Ag/Bi-2223 composite conductor prepared using fine-grained Bi-2223 as a precursor N.N.Merchant;D.J.Miller;V.A.Maroni https://doi.org/10.1109/77.785005
  20. Supercond. Sci. Technol. v.12 Grain alignment and critical current densities of (Bi,Pb)-2223 phase in the partical-melting and sintering process X.Y.Lu;A.Nagata;K.Sugaware;S.Kamada https://doi.org/10.1088/0953-2048/12/12/315
  21. Supercond. Sci. Technol. v.8 Precipitation of Impurity Phase and its Effect on the Intergrain Conducting Properties of Ag-doped Bi(Pb)-Sr-Ca-Cu-O K.Yoshida;Y.Sano;Y.Tomil https://doi.org/10.1088/0953-2048/8/5/010
  22. IEEE Transactions on Applied Superconductivity v.5 no.2 Ag doping on the microstructure and properties of undirectional Grown Y-Ba-Cu-O superconductors N.Hirano;S.Nagaya https://doi.org/10.1109/77.402871
  23. IEEE Transactions on Applied Superconductivity v.5 no.2 Progress towards a long length metallic precursor process for multifilament Bi-2223 composite superconductors A.Otto;L.J.Masur;C.Craven;D.Daly;E.R.Podtburg;J.Screiber https://doi.org/10.1109/77.402766
  24. J. Superconductivity v.5 no.3 Effect of silver on the phase Formation of Bi-Pb-Sr-Ca-Cu-O Superconductors S.kao;Ahmed El-Hamalawy;K.Y.Simon Ng https://doi.org/10.1007/BF00617631
  25. J. Matter. Res. v.14 no.5 Effect of Po₂and Ag on the Phase Formation of the Bi(Pb)-2223 Superconductor W.Wong-Ng;L.P.Cook https://doi.org/10.1557/JMR.1999.0230
  26. J. Appl. Phys. v.67 no.1 Effect of silver doping in the high-$T_{c}$ superconductor system Y-Ba-Cu-O Y.H.Kao;Y.D.Yao;L.Y.Jang;F.Xu;A.Krol;L.W.Song;C.J.Sher https://doi.org/10.1063/1.345261
  27. Mater. Sci. B v.26 A.C. and D.C. Susceptibility Studies on Silver-doped BPSCCO(2223) Superconductors M.Muralidhar;K. Nanda Kishore;S.Satyavathi;O.Pena;V. Hari Babu https://doi.org/10.1016/0921-5107(94)90164-3
  28. Jpn. J. Appl. Phys. v.27 no.10 Preparation of single 110 K phase of the Bi-Pb-Sr-Ca-Cu-O superconductor S.Koyama;U.Endo;T.Kawai https://doi.org/10.1143/JJAP.27.L1861
  29. Jpn. J. Appl. Phys. v.28 Improvement of surface flatness on BiSrCaCuO film Y.Nagal;K.Tsuru
  30. Jpn. J. Appl. Phys. v.27 Densification and grain-orientaion of Bi-Pb-Sr-Ca-Cu-O superconductor by hot pressing N.Murayama;E.Sudo;M.Awano;K.Kani;Y.Torii https://doi.org/10.1143/JJAP.27.L1856
  31. Supercond. Sci. Technol. v.11 Mechanical and superconducting properties of BiPbSrCaCuO-PE and BiPbSrCaCuO-MgO composites E.Bruneel;F.Persyn;S.Hoste https://doi.org/10.1088/0953-2048/11/1/018
  32. Physica C v.384 Characterisation of an optimised high current $MgO/Bi_{2}Sr_{2}CaCu_{2}O_{8.21}$ composite conductor using pulsed transport currents with pulsed magnetic fields B.A.Glowacki;A.Gilewski;K.Rogacki;A.Kursumovic;J.E.Evetts;H.Jones;R.Henson;O.Tsukamoto https://doi.org/10.1016/S0921-4534(02)01878-6
  33. Physica C v.357-360 Effect of MgO content on the formation and superconducting properties of (Bi,Pb)-2223 phase in the partial-melting and sintering process X.Y.Lu;A.Nagata;D.Kamio;K.Sugawara;S.Kamada;K.Watanabe;S.Hanada https://doi.org/10.1016/S0921-4534(01)00377-X