• Title/Summary/Keyword: $BaTiO_{3}$

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The Effects of $TiO_2$ Underlayer on Magnetic Properties of Hexagonal Barium-Ferrite(BaM) Thin Films (Hexagonal Barium-Ferrite(BaM) 박막의 미세구조와 자기적 특성에 미치는 $TiO_2$하지층의 효과)

  • 김동현;남인탁;홍양기
    • Journal of the Korean Magnetics Society
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    • v.11 no.3
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    • pp.129-133
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    • 2001
  • In this paper, we studied structural and magnetic properties of Ba-ferrite thin film deposited on Si(100) substrate with TiO$_2$ underlayer. Ba-ferrite thin films with TiO$_2$ underlayer were deposited by reactive RF/DC magnetron sputtering system at room temperature. TiO$_2$ underlayer was reactive sputtered with $O_2$. After deposition, the thin films were annealed at vatious temperatures to get the crystallized sample. Underlayer was used to prevent interdiffusion from Ba-ferrite thin film to substrate. The growth of Ba-ferrite thin films was influenced by TiO$_2$ underlayer. Easy magnetization direction is in-plane. From these results the Ba-ferrite film with TiO$_2$ underlayer can be used as longitudinal recording media.

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A study on the tunning properties of BST-MgO thick film (BST-MgO 강유전체 후막의 가변 튜닝 특성에 관한 연구)

  • Kim, I.S.;Min, B.K.;Song, J.S.;Jeon, S.Y.
    • Proceedings of the KIEE Conference
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    • 2005.11a
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    • pp.15-17
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    • 2005
  • In this study, tunable dielectric materials are important for resonator, variable capacitor, phased array antenna and other devices application. In this paper, Dielectric constant increased and tuning range increased with the increased of $BaSrTiO_3/Li_{2}CO_{3}$ content, which probably can be explained by the substitution of Ba3+, Li1+ on BaTiO3 lattice. The tunability and dielectric loss of the $BaSrTiO_2/Li_{2}CO_{3}$ thick film, sintered at $1150^{\circ}C$, were about 43 % and 0.234 at 10$\sim$15 MHz, respectively. In case of BaSrTi/MgO, Dielectric constant decreased and tenability increased with the added of $BaSrTiO_3/MgO$. The ferroelectrics properties were distinct when adding Li to BST ceramic thick film, and paraelectrics pattern was distinct when adding Mg.

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Manufacture and properties of Thick Film Ferroelectric PTC Thermistor (강유전성 후막 PTC 서미스터의 제조 및물성)

  • 구본급
    • Journal of the Microelectronics and Packaging Society
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    • v.5 no.1
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    • pp.63-72
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    • 1998
  • 후막 PTC를 제조하기 위하여 BaTiO3 주원료에 Sb2O3와 MnO2를 첨가한 PTC 페이 스트를 ZrO2와 BaTiO3 기판위에 인쇄한후 13$25^{\circ}C$에서 1시간 동안 소결하였다. BaTiO3 기판 위에 형성된 PTC후막은 PTCR 특성을 나타내었다. 그러나 ZrO2기판위에 인쇄된 시편의 경 우 PTCR특성이 나타나지 않았다. 이것은 ZrO2기판과 인쇄된 PTC페이스트간의 열팽창계수 차이에 의한 thermal cracking 때문에 후막 PTC 형성이 불가능함을 보여주었다.

Investigation of Slury Properties for Aqueous Casting of Nano-Size Barium Titanate (나도 티탄산 바륨의 수계 성형을 위한 슬러리 특성연구)

  • 김상우;신용욱;이해원;손용배
    • Journal of the Korean Ceramic Society
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    • v.36 no.7
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    • pp.705-710
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    • 1999
  • Stability and chemical durability for aqueous casting of BaTiO3 slurry with polycarylic acid(PAA) were studied. PAA was well chemisorbed on surface of BaTiO3 powder at neutral pH but did not chemically adsorbed at low pH. The amount of Ba dissolution in aqueous BaTiO3 slurry was abruptly increased at strong acid pH2 and also at high amount of PAA. Protection of Ba dissolution and stability of slurry could be obtained through the optimization of slurry conditions such as pH amount of surfactant and solid content.

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A Study on the Characterstics of the $BaTiO_{3}$ PTC Thermistor ($BaTiO_{3}$계 PTC 서미스터의 특성에 관한 연구)

  • Park, Jung-Cheul;Chu, Soon-Nam;Lee, Neung-Heon;Soh, Dae-Wha
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05b
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    • pp.66-70
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    • 2003
  • This dissertation is about the development of $BaTiO_{3}$-type PTC(Positive Temperature Coefficient) thermistor by composition method. PTC samples were fabricated after setting the experimental composition equation as $(Ba_{0.95-x}Sr_{0.05}Ca_x)TiO_3\;-\;0.01TiO_2\;-\;0.01SiO_2\;-\;aMnCO_3\;-\;0.2Nb_{2}O_{5}$ and their testing results were analyzed. a PTC thermistor, having the characteristics of relatively low resistance at room temperature and c and a good temperature coefficient, has been developed.

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Growth of $BaTiO_3$ Single Crystals by TSSG Technique (TSSG법에 의한 $BaTiO_3$ 단결정 육성)

  • 박봉모;정수진
    • Korean Journal of Crystallography
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    • v.3 no.2
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    • pp.120-128
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    • 1992
  • Single crysals of BaTiO3 were grown by TSSG technique at various cooling rates. Morpolo girts, defects and domain structures of the grown crystals were investigated. At the cooling rates below 0.5℃/hr, equant single crystals were obtained and the 11111 faces were dominantly developed. If the cooling rate was much faster or if the vortical temperature gradient in the so lotion was very large, the solution became unstable and the needle formed BasTil04 o crystals were precipitated. Two sets of parallel lamella domains are arranged perpendicular to each other and the irregularly shaped boundaries are fixed between them. These sets of domains show remarkable orientation contrast in x-ray topography. Heating the crystal above 127℃, the phase transition from tetragonal to cubic occurs. The phase transition front (PTF) moves in the direction of temperature gradient. Domains in the tetragonal phase are successively rearranged and regular strain patterns appear in the cubic phase. The habit plane of PTF in BaTi03 is found to deviate from a l1101 lattice plane by app roximately 9°.

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Fabrication of YBCO superconducting film with $CeO_{2}/BaTiO_{3}$double buffer layer ($CeO_{2}/BaTiO_{3}$ 이중완충막을 이용한 YBCO 박막 제작)

  • 김성민;이상렬
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.790-793
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    • 2000
  • We have fabricated good quality superconducting YBa$_2$Cu$_3$$O_{7-x}$(YBCO) thin films on Hastelloy(Ni-Cr-Mo alloys) metallic substrates with CeO$_2$and BaTiO$_3$buffer layers in-situ by pulsed laser deposition in a multi-target processing chamber. YBCO film with CeO$_2$ single buffer layer shows T$_{c}$ of 71.64 K and the grain size less than 0.1 ${\mu}{\textrm}{m}$. When BaTiO$_3$is used as a single buffer layer, the grain size of YBCO is observed to be larger than that of YBCO/CeO$_2$by 200 times and the transition temperature of the film is enhanced to be about 84 K. CeO$_2$/BaTiO$_3$double buffer layer has been adopted to enhance the superconducting properties, which results in the enhancement of the critical temperature and the critical current density to be about 85 K and 8.4 $\times$ 10$^4$ A/cm$^2$ at 77 K, respectively mainly due to the enlargement of the grain size of YBCO film.ilm.

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PTCR Effects of Semiconducting (Ba1-xPbx)TiO3 Ceramics with 0.5 mol% Pb5Ge3O11 (0.5 mol% Pb5Ge3O11가 첨가된 반도성 (Ba1-xPbx)TiO3 세라믹스의 PTCR 효과)

  • 윤상옥;정형진;윤기현
    • Journal of the Korean Ceramic Society
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    • v.28 no.7
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    • pp.525-530
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    • 1991
  • The effects of 0.15mol% Y2O3 doped semiconducting (Ba1-xPbx)TiO3 ceramics with 0.5 mol% Pb5Ge3O11 as sintering additives have been investigated as function of Pb contents (from 0.05 mol to 0.3 mol) and sintering temperatures (from 1050$^{\circ}C$ to 1200$^{\circ}C$). As the Pb content increases in the (Ba1-xPbx)TiO3 system, the size and resistance of the grain increase but the capacitance of the grain boundary decreases due to the formation of liquid phase during the sintering. And with increasing the sintering temperatures, the resistance of the grain decreases but the capacitance of the grain boundary increases. The PTCR effects decrease with increasing the Pb content and the sintering temperature.

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Magnetic Ordering in (1-x)BaTiO3-xLaFeO3 Solid Solutions

  • Rajagukguk, R.;Shin, D.G.;Lee, B.W.
    • Journal of Magnetics
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    • v.16 no.2
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    • pp.101-103
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    • 2011
  • Solid solutions between $BaTiO_3$ and $LaFeO_3$ have been prepared through a solid state reaction method. The X-ray diffraction results reveal that $Ba_{1-x}La_xTi_{1-x}Fe_xO_3$ ($0.1\;{\leq}\;x\;{\leq}\;0.7$) compounds have a cubic structure, whereas the parent material $BaTiO_3$ has a tetragonal structure. The magnetization measurements indicate that the materials have a magnetic ordering at room temperature and the magnetic properties of the solid solutions depending on the doping amount of $LaFeO_3$. The origin of magnetic behaviors is believed to be from $Fe^{3+}$ ions.

The Behavior of the Formation of (111) Twins in $BaTiO_3$ Synthesized by Sol-Gel Route (졸-겔법으로 제조한 $BaTiO_3$에서(111)쌍정의 생성거동)

  • Yoo, Young-Sung;Kim, Young-Jung;Kim, Hwan
    • Korean Journal of Materials Research
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    • v.6 no.2
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    • pp.175-181
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    • 1996
  • Ti(i-OC3H7)와 Ba(OH)2.8H2Or 그리고 공통용매로서 2-Methoxy Ethanol을 이용하여 균일 용액을 제조하고, 이로부터 미세하고 조성비가 균일한 BaTiO3분말을 제조하였다. 이러한 졸-겔법으로 제조된 분말을 TG-DTA와 XRD 분석으로 결정화 및 상변화를 관찰하였다. 각 온도별로 하소된 분말에서 (111)쌍정의 생성여부를 TEM을 이용해 관찰한 결과, 합성된 BaTiO3 분말에서는 하소중(111)쌍정의 생성이 활발히 일어나지 않는 것으로 판단되었다. 특히(111) 쌍정판은 합성된 겔을 120$0^{\circ}C$에서 하소한 후 이를 140$0^{\circ}C$에서 소결한 경우에만 관찰할 수 있었다. 이러한 하소온도의 영향은 원료분말의 입자크기나 형상이 쌍정 생성에 큰 영향을 미침을 의미하는 것으로, 본 연구에서는 이를 근거하여 (111) 쌍정의 생성에 대해서 고찰하였다.

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