• Title/Summary/Keyword: $BaTiO_{3}$

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Remote Controlled PTC Thermistor by YAG Laser Irradiation (YAG 레이저를 이용한 PTC 서미스터의 원격작동)

  • 박용동
    • Journal of the Microelectronics and Packaging Society
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    • v.4 no.2
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    • pp.41-46
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    • 1997
  • 지향성이 좋고 에너지밀도가 높고 집광성이 뛰어난 Nd:YAG레이저를 이용해서 원거 리 레이저 조사를 통한 서미스터의 PTCR 특성을 관찰하여 원격 제어를 시도를하였다. 1064nm의 Nd:YAG레이저 광선을 BaTiO3 서미터 표면에 1m 거리에서 5mm2 빔 사이즈로 50~200mJ/pulse, 10Hz의 조건에서 조사하였을 때 서미스터의 전기저항변화는 약 103 정도 로 레이저 조사에 의하여 원격으로 PTCR 특성을 제어 할수 있었다.

Current-voltage Characteristics of PTC Ceramics by Changing Donor Concentration and Specimen Thickness (Donor 첨가량과 시편두께에 따른 PTC 세라믹스의 전류-전압 특성)

  • 한응학;강영석;박순자
    • Journal of the Korean Ceramic Society
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    • v.28 no.8
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    • pp.619-625
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    • 1991
  • The current-voltage characteristics of the semiconducting BaTiO3 ceramics are measured in the range of 0.01∼100 Volt. Non ohmic behavior was observed above Tc. This behavior is not dependent on specimen thickness and is not observed at the incomplete semiconducting sepcimen. From this experiment, non-ohmic behavior of PTC is attributed to Heywang's potential barrier not to space change limited current. In the low voltage range, current-voltage characteristics of PTC ceramics can be explained by Heywang model.

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Geochemistry and Mineralogy of Metapelite and Barium-Vanadium Muscovite from the Ogcheon Supergroup of the Deokpyeong Area, Korea (덕평지역(德平地域)의 옥천누층군(沃川累層群)에 분포(分布)하는 변성이질암(變成泥質岩)과 바륨-바나듐 백운모(白雲母)의 지구화학적(地球化學的) 및 광물학적(鑛物學的) 특성(特性))

  • Lee, Chan Hee;Lee, Hyun Koo
    • Economic and Environmental Geology
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    • v.30 no.1
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    • pp.35-49
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    • 1997
  • The coal formation of the Deokpyeong area are interbedded along metapelites of the Ogcheon Supergroup, which are composed mainly of graphite, quartz, muscovite and associated with small amounts of biotite, chlorite, pyrite and barite. The ratios of $SiO_2/Al_2O_3$, $Al_2O_3/Na_2O$ and $K_2O/Na_2O$ of the coaly metapelite are variable and wide range from 1.80 to 10.21, from 27.8 to 388.8 and from 7.6 to 61.8, respectively. These coal formation were deposited in basin of marine environments, and the REE of these rocks are not influenced with metamorphism and hydrothermal alterations on the basis of $Al_2O_3$ versus La, La against Ce, the ratios of La/Ce (0.19 to 0.99) and Th/U (0.02 to 4.75). These rocks also show much variation in $La_N/Yb_N$ (1.19 to 22.89), Th/Yb (0.14 to 21.43) and La/Th (0.44 to 13.67), and their origin is explained by derivation from a mixture of sedimentary and igneous rocks. The wide range in trace and REE element characteristics as Co/Th (0.12 to 2.78), La/Sc (0.33 to 10.18), Sc/Th (0.57 to 5.73), V/Ni (8 to 2347), Cr/V (0.02 to 0.67) and Ni/Co (1.56 to 32.95) of these coaly metapelites argues for inefficient mixing of the various source lithologies during sedimentation. Deep to pale green barium-vanadium muscovites (vanadium-oellacherite) have been found in this coal formations. Modes of occurrence and grain size of muscovite are heterogeneous, but most of the barium and vanadium-bearing muscovites occur along the boundaries between graphite and quartz grains, ranging from 200 to $350{\mu}m$ in length and from 40 to $60{\mu}m$ in width. Results of X-ray diffraction data of the minerals characterized to be monoclinic system with $a=5.249{\AA}$, $b=8.939{\AA}$, $c=20.924{\AA}$ and ${\beta}=95.894^{\circ}$. Representative chemical formula of the muscovite was $(Na_{0.09}K_{1.44}Ba_{0.46})(Al_{2.75}Ti_{0.07}V_{0.56}Fe_{0.08}Mg_{0.50})(Si_{6.12}Al_{1.88})O_{22}$. The V possibly substitute octahedral Al, and the Ba is coupled substitution of $K^+Si^{4+}=Ba^{2+}Na^+Ca^{2+}$, which compositional ranges of V and Ba are from 0.42 to 0.69 and from 0.34 to 0.56 based on $O_{22}$, respectively. Formation mechanism of the barium-vanadium muscovites in the coaly metapelite is shown that the formed by high pressure and temperature from regional metamorphism origanated during diagenesis at the interface between a basinal brine and organic matter.

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Corona Discharge and Strong Electrolyzed Water Generation Characteristics of the Electrode System Bedded by Dielectric Pellets (유전체구 충진형 전극계의 코로나방전과 강전해수 발생특성)

  • 김진규
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.16 no.4
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    • pp.46-54
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    • 2002
  • A dielectric pellets bedded parallel plates with a membrane centered have been proposed as an ion separation and collection system in water. and effects of the relative dielectric constant and the applied square wave pulse voltage on the characteristics of ion separation and collection in tap water and NaCl dissolved tap water have been investigated. As a result, electrolyzed water of pH 3.1 and 10.6 were obtained with only tap water at the pulse current of 1.0[A] and flow rate of 0.5[LPM]. And the higher ionized water of pH 2.8 and pH 11.7 ware obtained in 0.1[%wt] NaCl dissolved water. When the dielectric pellets of BaTiO$_3$ having the highest dielectric constant were bedded in the ion separation and collection cell, the ionized water of pH 2.7 and pH 11.7 were obtained with only tap water. And the ionized water of pH 2.4 and pH 12.0 were obtained in 0.1[wt%] NaCl dissolved tap water with the dielectrics pellets bedded ones.

Leaching Behavior of Nickel from Waste Multi-Layer Ceramic Capacitor (폐(廢) 적층형(積層形)세라믹콘덴서에 함유(含有)된 니켈의 침출거동(浸出擧動))

  • Kim, Eun-Young;Kim, Byung-Su;Kim, Min-Seuk;Jeong, Jin-Ki;Lee, Jae-Chun
    • Resources Recycling
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    • v.14 no.5 s.67
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    • pp.32-39
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    • 2005
  • Leaching behavior of nickel contained in waste Multi-Layer Ceramic Capacitor (MLCC) was investigated using a batch reactor. The effects of acid type, acid concentration, leaching temperature, particle size, and reaction time on the extraction of nickel metal from waste MLCC were examined. As a result, 97% of nickel contained in waste MLCC was leached out in 30 min at the temperature of $90^{\circ}C$ under the condition of $HNO_3$ concentration 1N, solid/liquid ratio 5 g/L and particle size $-300/+180{\mu}m$. It was also found that a Jander equation was useful to fit well the leaching rate data. The rate of nickel leaching is controlled by pore diffusion in $BaTiO_3$ layer and has an activation energy of 37.6 kJ/mol (9.0 kcal/mol).

Relation between Metamorphic P-T Conditions and Boron Concentrations of Metasedimentary Rocks and Biotite Granitic Gneisses from NE Yeongnam Massif around Samcheok Area, South Korea (영남 육괴 북동부 변성퇴적암과 흑운모 화강편마암의 변성 온도-압력 조건과 전압 붕소 함량사이의 상관관계)

  • Cheong, Won-Seok;Sun, Gwang-Min;Na, Ki-Chang
    • Economic and Environmental Geology
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    • v.42 no.3
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    • pp.247-259
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    • 2009
  • This study is focused on the relationship between whole rock boron contents and metamorphic P-T conditions of metasedimentary rocks from northeastern Yeongnam massif around Samcheok area, Korea. Metamorphic P-T conditions of sillimanite and garnet zones based on the Ti-biotite geothermometer is 553-687$^{\circ}C$ and 582-722$^{\circ}C$ at 4-6 kbar, respectively. In the metasedimentary rocks, boron contents in whole rock decrease with increasing metamorphic grade, from sillimanite zone (9.60-189 ppm B) to garnet zone (2.63-15.97 ppm B), except one sample (90.9 ppm B) from garnet zone containing graphites. Boron depletion in garnet zone has relation with mode of tourmaline which are broken down with increasing metamorphic temperature. Boron contents are indirectly proportional to major and trace elements such as $Al_2O_3$, MgO, $Fe_2O_3$, $K_2O$, Li, Ba, Sc, Co, Cr, Rb and Cs that are abundant in tourmalines. In conclustion, tourmalines and graphite are modulator of boron contents in metasedimentary rocks. In the biotite granitic gneisses, boron contents (2.62-12.2 ppm B) are similar or lower than those of metasedimentary rocks and have no relation with metamorphic P-T conditions.

Petrology and Geochemical Characteristics of A-type Granite with Particular Reference to the Namsan Granite, Kyeongju (경주 남산일대의 A-형 화강암의 암석학 및 지화학적 특성)

  • 고정선;윤성효;이상원
    • The Journal of the Petrological Society of Korea
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    • v.5 no.2
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    • pp.142-160
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    • 1996
  • Petrological and geochemical characteristics of A-type granite were studied from the Namsan and Tohamsan granites in the vicinity of Kyeongju city, southeastern Korea. The Namsan granite consists of hypersolvus alkali-feldspar granite in the northern part and subsolvus alkali-feldspar to biotite granite in the southern part. This hypersolvus granite usually has miarolitic cavities and is characteristically composed of quartz, single homogeneous one-feldspar (alkali feldspar) forming tabular microperthite crystals, or micrographic intergrowth with quartz, and interstitial biotite (Fe-rich annite), alkali amphibole (riebeckitic arfvedsonite) and fluorite. Petrographic and petrochemical characteristics indicate that the hypersolvus granite and subsolvus granite from the Namsan belogn to the A-type and I-type granitoid, respectively. The A-type granite is petrochemically distinguished from the I-type Bulgugsa granites of Late Cretaceous in South Korea, by higher abundance of $SiO_2$, $Na_2O$, $Na_2O+K_2O$, large highly charged cations such as Rb, Nb, Y, Zr, Ga, Th, Ce. U the REEs and Ga/Al ratio, and lower abundance of $TiO_2$, $Al_2O_3$, CaO, $P_2O_5$, MnO, MgO, Ba, Sr, Eu. The total abundance of REEs is 293 ppm to 466 ppm, showing extensively fractionated granitic compositon, and REEs/chondrite normalized pattern shows flat form with strong Eu '-' anomaly ($Eu/Eu^{\ast}$=0.03-0.05). A-type granite from the Namsan area is thought to have been generated late in the magmatic/orogenic cycle after the production of I-type granite and by direct, high-temperature partial melting of melt-depleted, relatively dry tonalitic/granulitic lower crustal material with underplating by mantle-derived basaltic magmas associated with subduction.

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Phase Transition Characteristics of the BLN - PZT Ceramics. (BLN-PZT 세라믹의 상전이 특성)

  • 류기원;이영종;배선기;이영회
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.25-33
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    • 1994
  • Temperature dependences of the remanent polarization $P_{\gamma}$/(T), effective birefringence ㅿn(T). dielectric constant K(T) and quadratic electro-optic coefficient R(T) of the two-stage sintered xBa(La$_{1/2}$Nb$_{1/2}$)O$_3$Pb$(Zr_{y}Ti_{1-y})O-{3}$(x=0.085, 0.09, 0.40$\leq$y$\leq$0.70)ceramics were investigated. Increasing the PbZrO$_3$ contents, the crystal structure of a specimen was varied from tetragonal and rhombohedral to cubic, and the phase transition was showed a diffuse phase transition(DPT) characteristics. Especially. in the compositions which located on the PE-FE phase boundary were showed a discrepancy between curie temperature and temperature range which a macroscopic polarization and a effective birefringence were disappeared.

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