• Title/Summary/Keyword: $Al_2O_3$ Bead

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A Study of Catalysts for Decomposition of ADN-Based Liquid Monopropellant (ADN기반 단일액상추진제 분해용 촉매 제조 및 특성 연구)

  • Jeon, Jong-Ki;Heo, Sujeong;Jo, Young Min;Kim, Taegyu
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.412-415
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    • 2017
  • In this study, the decomposition performance of ammonia dinitramide (ADN) based liquid monopropellant was evaluated by using metal supported alumina bead catalyst. Alumina bead was calcined at $1200^{\circ}C$, and Pt and Cu were impregnated on alumina bead by excess water impregnation using a rotary evaporator. The decomposition temperature ($T_{dec}$) of ADN-based liquid monopropellant was measured in a home-made batch reactor. The decomposition temperature of Cu/$Al_2O_3$ catalyst was lower than that of Pt/$Al_2O_3$ catalyst, and $T_{dec}$ was about $130^{\circ}C$.

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Electric Field Simulation and Removal Characteristics of Escherichia coli for Discharge Tube with $Al_2O_3$ Bead ($Al_2O_3$ 비드를 가지는 방전관의 전계 및 대장균 제거 특성)

  • Lee, Tae-Gwan;Lee, Dong-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.6
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    • pp.634-639
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    • 2006
  • The simulation of electric field distribution of discharge tube with globular $Al_2O_3$ and the removal characteristic of Escherichia coli by the discharge tube with globular $Al_2O_3$ were estimated. The removal characteristic of Escherichia coli was related to the input voltage because the electric field is increased according to input voltage. As the passing amount of test water in discharge tube is increased, the removal ratio of Escherichia coli was increased because passing numbers of electric field section is increased. As the particle size of globular $Al_2O_3$ increased, the removal time of Escherichia coli was shortened due to the dielectric polarization of globular dielectric $Al_2O_3$. Also, the removal efficiency of Escherichia coli for the discharge tube with globular dielectric $Al_2O_3$ was higher than that of the discharge tube without it.

A study on Harmful Bacillus Removal Analysis (유해 세균 제거 분석 연구)

  • Cho, Kook-Hee;Kim, Young-Bae;Cho, Moon-Soo;Park, Bo-Hyun;Shin, Kwang-Chul;Lee, Dong-Hoon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05b
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    • pp.38-42
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    • 2004
  • In this research, we used discharge tube without dielectric bead or with dielectric beads($SiO_2$, $Al_2O_3$, or $ZrO_2$), and discharge in water for removal of Escherichia coli. At the result of experiments, the removal characteristics of Escherichia coli appeared relation ratio to input voltage. Because, the electric field of discharge tube is increased when input voltage is increased. And, discharge tube used dielectric bead($ZrO_2$), the removal characteristics of Escherichia coli was better than cases of else.

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Dispersion Property of Al2O3 Nanosol Prepared by Various Dispersion Factors and Silane Modification under Non-Aqueous Solvent (비수계 용매하에서 다양한 분산인자 및 실란 표면개질에 의해 제조된 Al2O3 나노졸의 분산 특성)

  • Na, Ho Seong;Park, Min-Gyeong;Lim, Hyung Mi;Kim, Dae Sung
    • Korean Journal of Materials Research
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    • v.26 no.12
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    • pp.733-740
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    • 2016
  • $Al_2O_3$ nanosol dispersed under ethanol or N-Methyl-2-pyrrolidone(NMP) was studied and optimized with various dispersion factors and by utilizing the silane modification method. The two kinds of $Al_2O_3$ powders used were prepared by thermal decomposition method from aluminum ammonium sulfate$(AlNH_4(SO_4)_2)$ while controlling the calcination temperature. $Al_2O_3$ sol was prepared under ethanol solvent by using a batch-type bead mill. The dispersion properties of the $Al_2O_3$ sol have a close relationship to the dispersion factors such as the pH, the amount of acid additive(nitric acid, acetic acid), the milling time, and the size and combination of zirconia beads. Especially, $Al_2O_3$ sol added 4 wt% acetic acid was found to maintain the dispersion stability while its solid concentration increased to 15 wt%, this stability maintenance was the result of the electrostatic and steric repulsion of acetic acid molecules adsorbed on the surface of the $Al_2O_3$ particles. In order to observe the dispersion property of $Al_2O_3$ sol under NMP solvent, $Al_2O_3$ sol dispersed under ethanol solvent was modified and solvent-exchanged with N-Phenyl-(3-aminopropyl)trimethoxy silane(APTMS) through a binary solvent system. Characterization of the $Al_2O_3$ powder and the nanosol was observed by XRD, SEM, ICP, FT-IR, TGA, Particles size analysis, etc.

Development of Silent Discharge Chamber with Al2O3 Dielectric Pellet to Improve Ozone Generation Characteristics (오존발생특성 향상을 위한 강유전성 알루미나 무성방전관의 개발)

  • Kwak, Dong-Joo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.7
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    • pp.58-64
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    • 2006
  • Recently deep interests have been paid on the effective generation of ozone, which has been widely used for water treatment, deodorization, color removal, and chemical processing of exhausted smoke. The silent discharge reaction has been proposed as the most effective one in the many ozone generation methods, because the silent discharge can be generated under the conditions of lower applied voltage and power consumption, compared other ones. In this paper, in order to improve the ozone generation and ozone generation efficiency, the conventional silent discharge chamber with $Al_2O_3$ dielectric layer and tubular ferroelectric bed discharge reactor packed with $Al_2O_3$ pellets were made, and the silent discharge of the reactors were studied experimentally. The ozone generation characteristics are also discussed based on the discharge characteristics, especially on the wall charge accumulation properties and power consumption. The results show that the electric charges of discharge tube with bead are around 2.5 times as large as those without bead. In the discharge chamber packed with dielectric beads, the ozone concentration and the energy yield characteristics were also improved, compared with those in the conventional silent discharge reactor.

Effect of Pt-Sn/Al2O3 catalysts mixed with metal oxides for propane dehydrogenation (프로판 탈수소 반응에 미치는 금속산화물과 혼합된 Pt-Sn/Al2O3 촉매의 영향)

  • Jung, Jae Won;Koh, Hyoung Lim
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.2
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    • pp.401-410
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    • 2016
  • The $Pt-Sn/Al_2O_3$ catalysts mixed with metal oxides for propane dehydrogenation were studied. $Cu-Mn/{\gamma}-Al_2O_3$, $Ni-Mn/{\gamma}-Al_2O_3$, $Cu/{\alpha}-Al_2O_3$ was prepared and mixed with $Pt-Sn/Al_2O_3$ to measure the activity for propane dehydrogenation. As standard sample, $Pt-Sn/Al_2O_3$ catalyst mixed with glassbead was adopted. In the case of catalytic activity test after non-reductive pretreatment of catalyst and metal oxide, $Pt-Sn/Al_2O_3$ mixed with $Cu-Mn/{\gamma}-Al_2O_3$ showed higher conversion of 15% and similar selectivity at $576.5^{\circ}C$, compared to conversion of 8% in standard sample. In the case of catalytic activity test after reductive pretreatment of catalyst and metal oxde, $Cu/{\alpha}-Al_2O_3$ showed higer yield than standard sample. But, increase of yield of most of samples after reductive pretreatment was not significant, so it was found that lattice oxygen of $Cu-Mn/{\gamma}-Al_2O_3$ is effective to propane dehydrogenation.

A Characteristics on Water Quality Analysis Used the High-Voltage Discharge (고전압 방전을 이용한 수질분식에 관한 특성)

  • Cho, Kook-Hee;Kim, Young-Bae;Cho, Moon-Soo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.18 no.5
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    • pp.156-161
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    • 2004
  • In this research, we used discharge tube without dielectric bead or with dielectric beads(SiO$_2$, $Al_2$O$_3$, or ZrO$_2$), and discharge in water at High-voltage pulse$.$DC power supply for removal of Escherichia coli. At the result of experiments, the removal characteristics of Escherichia coli appeared relation ratio to input voltage. Because, the electric field of discharge tube is increased when input voltage is increased. And, discharge tube used dielectric bead(ZrO$_2$), the removal characteristics of Escherichia coli was better than cases of else. And discharge used DC Power, the removal characteristics of Escherichia coli was better than AC Pulse Power.

Fabrication of catalytic combustible gas sensor for hydrocarbon gas detection (탄화수소계 가스 감지용 접촉연소식 가스센서의 제조)

  • Park, Hyo-Derk;Lee, Jae-Suk;Kim, Kun-Nyun;Park, Jong-Wan;Shin, Sang-Mo
    • Journal of Sensor Science and Technology
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    • v.3 no.3
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    • pp.9-15
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    • 1994
  • Catalytic combustible gas sensors were fabricated by using ${\gamma}-Al_{2}O_{3}$ with large surface area and noble metal catalysts. The optimum conditions for ${\gamma}-Al_{2}O_{3}$ fabrication were investigated by DT/TGA and XRD analyses and it was found that fabricated ${\gamma}-Al_{2}O_{3}$ had superior value as surface area of $215.5m^{2}/g$. Gas sensors were manufactured and tested to inflammable gases by using Pt coil as a heater and temperature sensing part, fine ${\gamma}-Al_{2}O_{3}$ powder as a bead material and Pt, Pd noble metal powder as a catalyst. From the results, fabricated sensor showed good sensitivity to LPG and LNG of 20mV/l000ppm, 6.5mV/l000ppm respectively.

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Effect of Dispersion Technique on Heat Transfer Properties of Transformer Oil with Nanoparticles (변압기 나노절연유의 열전달특성에 미치는 분산기술의 영향)

  • Song, Hyun-Woo;Choi, Cheol;Oh, Je-Myung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.151-152
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    • 2005
  • Both $Al_2O_3$ and AlN nanopowders with diameters from ${\mu}m$ to mm were bead-milled and surface-modified by stabilizing agent. The size of bead-milled nanoparticles compared with the primary powder was effectively decreased and was dependent on milling time and bead size. The results of dispersion stability analysis indicated that chemical bonding between nanoparticles and surfactant is more effective than chemical adsorption to prepare the stable transformer oils containing nanoparticles. In this study, the thermal conductivity of the transformer oils containing nanoparticles was measured by transient hot-wire and laser flash methods.

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A study on Harmful Bacillus Detection used discharge in water (수중 방전을 이용한 유해 세균 검출 분석 연구)

  • Cho, Kook-Hee;Kim, Young-Bae;Cho, Moon-Soo;Park, Bo-Hyun;Shin, Kwang-Chul;Lee, Dong-Hoon
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2004.05a
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    • pp.285-289
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    • 2004
  • In this research, we used discharge tube without dielectric bead or with dielectric beads$(SiO_2,\;Al_2O_3,\;or\;ZrO_2)$ for removal of Escherichia coli. At the result of experiments, the removal characteristics of Escherichia coli appeared relation ratio to input voltage. Because, the electric field of discharge tube is increased when input voltage is increased. And, discharge tube used dielectric $bead(ZrO_2)$, the removal characteristics of Escherichia coli was better than cases of else.

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