• Transactions of Materials Processing
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• v.3 no.4
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• pp.427-439
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• 1994

The high temperature deformation behavior of $SiC_p/Al-Si$ composites and Al-Si matrix was studied by hot torsion test in a range of temperature from $270^{\circ}C$ to $520^{\circ}C$ and at strain rate range of $1.2{\times}10_{-3}~2.16{\times}10_{-1}/sec$. The hot restoration mechanisms for both matrix and composites were found to be dynamic recrystallization(DRX) from the investigation of flow curves and microstructural evolutions. The Si precipitates and SiC particles promoted DRX, and the peak strain$({\varepsilon}_p)$ of the composites was smaller than that of the matrix. Flow stresses of $SiC_p/Al-Si$ composites were found to be generally higher than the matrix, but the difference was quite small at higher temperature due to the decrease of capability of load transfer by SiC particles. With increasing temperature, failure strain of matrix and composites are inclined to increase, the increasing value of failure strain for the $SiC_p/Al-Si$ composites was small compared to that of matrix. The stress dependence of both materials on strain rate() and temperature(T) was examined by hyperbolic sine law, $\.{\varepsilon}=A_1[sinh({\alpha}{\cdot}{\sigma})]_n$exp(-Q/RT)

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.31 no.2
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• pp.69-73
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• 2018

The power law is very important in gas sensing for the determination of gas concentration. In this study, the resistance of a gas sensor based on poly (3, 4-ethylenedioxythiophene) polystyrene sulfonate+graphene oxide composite was found to exhibit a power law dependence on hydrogen concentration at $150^{\circ}C$. Experiments were carried out in the gas concentration range of 30~180 ppm at which the sensor showed a sensitivity of 6~9% with a response and recovery time of 30s.

• Journal of the Korean Society of Safety
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• v.4 no.1
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• pp.25-39
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• 1989

Cyclic temperature creep tests were carried out an AS 7075 alloy specimens were subjected to a constant load and stepwise temperature cycles in which temperature was fluctuated between 30$0^{\circ}C$ and 25$0^{\circ}C$ with three different cycle ratios. The highest frequency of cycling was 1 cycle per 10 hr and the lowest one was 1 cycle per 12 hr. From the creep experimental results with the above conditions the creep strain under cyclic temperature can be predicted easily by introd ucing the equivalent steady temperature because defined by Eq.(16), but the rupture life is 1.1 time than those of constant temperature because of effect of temperature history at tertiary creep range. Besides thlis result, the results of the creep test under cyclic temperature conditions are respectively compayiea with calculated rupture lives using the life fraction law and Eq.(18). The agreement between the obseried rupture times and calculated ones is fairly good. So creep rupture lives can be respectively predicted using life fraction law and Eq.(18).

• Journal of the Korean GEO-environmental Society
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• v.13 no.10
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• pp.25-32
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• 2012

The application of electrical resistivity, which is related to charge mobility, has increased in the field of geotechnical engineering for the detection of underground cavern, faults and subsurface pollution level. The purpose of this study is to investigate the variation of electrical resistivity due to temperature change. Sand-silt mixture specimens prepared in the square freezing nylon cell are frozen in the frozen chamber. Four electrodes are attached on the four side walls of the freezing cell for the measurement of electrical resistance during temperature change. Electrical resistances of sand-silt mixtures with different degrees of saturation (0%, 2.5%, 5%, 10%, 20%, 40%, 60% and 100%) are measured as the temperature of specimens decrease from $20^{\circ}C$ to $-10^{\circ}C$. The electrical resistances determined by Ohm's law are transformed into the electrical resistivity by calibration. Experimental results show that the higher degree of saturation, the lower electrical resistivity at $20^{\circ}C$. Electrical resistivity gradually increases as the temperature decrease from $20^{\circ}C$ to $0^{\circ}C$. For the specimens with the degree of saturation of 15% or higer, electrical resistivity dramatically changes near the temperature of $0^{\circ}C$. In addition, very high electrical resistivity is observed regardless of the degree of saturation if the specimens are frozen. This study provides the fundamental information of electrical resistivity according to the soil freezing and temperature change demonstrates that electrical resistivity be a practical method for frozen soil investigation.

• 한국유가공학회:학술대회논문집
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• 2002.11a
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• pp.23-40
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• 2002

This study was conducted to investigate the quality changes of the UHT(ultra-high temperature), LTLT(law temperature long time) and HTST(high temperature short time) treated milk samples by storage conditions for 6 months from August 2000 to February 2001. The UHT treated milk samples collected from 3 plants(A, B and C) were stored at l0$^{\circ}$C and room temperature(dark and light exposure) for 6 months, and the LTLT and HTST treated milk samples(D and E) were also stored for 30 days. The UHT pasteurized milk of A, B and C plant was treated at 130$^{\circ}$C for 2-3s, 133$^{\circ}$C for 2-3s and 135$^{\circ}$C for 4s, respectively. The UHT sterilized milk of A and B plant was treated at 140$^{\circ}$C for 2-3s and 145$^{\circ}$C for 3-4s, respectively. The LTLT milk of D plant was treated at 63$^{\circ}$C for 30 mins, and the HTST milk of E plant was treated at 72$^{\circ}$C for 15s. All of the raw milk samples collected from storage tank in 5 milk plants were showed less than 4.0 X 10$^5$cfu/ml in standard plate count, and normal level in acidity, specific gravity, and component of milk. Preservatives, antibiotics, sulfonamides and available chloride were not detected in both raw and heat treated milk samples obtained from 5 plants. One(10%) of 10 UHT pasteurized milk samples obtained from B plant and 2 (20%) of 10 from C were not detected in bacterial count after storage at 37$^{\circ}$C for 14 days, but all of the 10 milk samples from A were detected. No coliforms were detected in all samples tested. No bacteria were also detected in carton, polyethylene and tetra packs collected from the milk plants. A total of 300 UHT pasteurized milk samples collected from 3 plants were stored at room(3$^{\circ}$C ${\sim}$ 30$^{\circ}$C) for 3 and 6 months, 11.3%(34/300) were kept normal in sensory test, and 10.7%(32/300)were negative in bacterial count. The UHT pasteurized milk from A deteriorated faster than the UHT pasteurized milk from B and C. The bacterial counts in the UHT pasteurized milk samples stored at 10$^{\circ}$C were kept less than standard limit(2 ${\times}$ 10$^4$ cfu/ml) of bacteria for 5 days, and bacterial counts in some milk samples were a slightly increased more than the standard limit as time elapsed for 6 months. When the milk samples were stored at room(3$^{\circ}$C ${\sim}$ 30$^{\circ}$C), the bacterial counts in most of the milk samples from A plant were more than the standard limit after 3 days of storage, but in the 20%${\sim}$30%(4${\sim}$6/20) of the milk samples from B and C were less than the standard limit after 6 months of storage. The bacterial counts in the LTLT and HTST pasteurized milk samples were about 4.0 ${\times}$ 10$^3$ and 1.5 ${\times}$ 101CFU/ml at the production day, respectively. The bacterial counts in the samples were rapidly increased to more than 10$^7$ CFU/ml at room temperature(12$^{\circ}$C ${\sim}$ 30$^{\circ}$C) for 3 days, but were kept less than 2 ${\times}$ 10$^3$ CFU/ml at refrigerator(l0$^{\circ}$C) for 7 days of storage. The sensory quality and acidity of pasteurized milk were gradually changed in proportion to bacterial counts during storage at room temperature and 10$^{\circ}$C for 30 days or 6 months. The standard limit of bacteria in whole market milk was more sensitive than those of sensory and chemical test as standards to determine the unaccepted milk. No significant correlation was found in keeping quality of the milk samples between dark and light exposure at room for 30 days or 6 months. The compositions of fat, solids not fat, protein and lactose in milk samples were not significantly changed according to the storage conditions and time for 30 days or 6 months. The UHT sterilized milk samples(A plant ; 20 samples, B plant ; 110 samples) collected from 2 plants were not changed sensory, chemical and microbiological quality by storage conditions for 6 months, but only one sample from B was detected the bacteria after 60 days of storage. The shelflife of UHT pasteurized milk in this study was a little longer than that reported by previous surveys. Although the shelflife of UHT pasteurized milk made a significant difference among three milk plants, the results indicated that some UHT pasteurized milk in polyethylene coated carton pack could be stored at room temperature for 6 months. The LTLT and HTST pasteurized milk should be sanitarily handled, kept and transported under refrigerated condition(below 7$^{\circ}$C) in order to supply wholesome milk to consumers.

• Bulletin of the Korean Chemical Society
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• v.11 no.4
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• pp.318-323
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• 1990

The bis(malonato)diaquochromate(III) ion, $Cr(C_3H_2O_4)_2^-$ in acidic solution hydrolyzes to give $Cr(C_3H_2O_4)^{+}.$ This reaction is catalyzed by ferric ion and the rate law for this cation catalyzed-aquation in a $HClO_4/NaClO_4$ medium, $I = 1.00 M, is-d[Cr(C_3H_2O_4)_2^-]/dt = ({\kappa}_1[Fe^{3+}] + {\kappa}_2[H^+])[Cr(C_3H_2O_4)_2^-]$ where ${\kappa}_1(25^{\circ}C) = 4.72×10^{-5} M^{-1}sec^{-1} ({\Delta}H^{\neq} = 22.5 Kcal/mol, {\Delta}S^{\neq} = - 2.58 eu) and {\kappa}_2(25^{\circ}C) = 4.75{\times}10^{-5} M^{-1}sec^{-1} ({\Delta}H^{\neq} = 21.2 Kcal/mol, {\Delta}S^{\neq} = - 7.13 eu).$ Rapid preequilibrium association of basic Cr-bound oxygen with $Fe^{3+},$ followed by rate-determining ring opening, is proposed to account for the ${\kappa}_1,$ hydrolysis pathway.

• Journal of the Korean institute of surface engineering
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• v.40 no.1
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• pp.23-31
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• 2007

The objective of this study is to investigate the effect of Al addition on the reaction behavior of cobalt with molten zinc. Pure cobalt specimen was immersion tested in the three kinds of molten zinc (pure, 0.12%Al added and 0.24%Al added) baths at $460^{\circ}C,\;490^{\circ}C\;and\;520^{\circ}C$. For the understanding of degradation processes, specimens were analyzed with scanning electron microscope (SEM) and energy dispersive spectrum (EDS), and electrochemical stripping method. When 0.12% and 0.24% Al was added in molten zinc baths, three intermetallic compounds layers of ${\gamma},\;{\gamma}_1,\;and\;{\gamma}_2$ were formed on the Co matrix and ${\beta}_1$ layer was not formed between the Co matrix and the ${\gamma}$ layer. Particles of CoAl intermetallic compound were formed at the interface between the ${\gamma}_2$ layer and zinc melt and they did not adhere to the Co-Zn intermetallic layer. Weight loss of the Co specimen increased as Al content in the molten zinc increased and the relationship of weight loss vs. immersion time followed parabolic rate law. Rate controlling process for the reaction rate of Co with Al added molten zinc was analyzed as the diffusion process of Al atom through a boundary layer between the ${\gamma}_2$ layer and the Al added zinc melt.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2002.05a
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• pp.117-124
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• 2002

The lightness of components required in automobile and machinery industry is requiring high strength of components. In particular, manufacturing process and new materials development for solving the fatigue fracture problem attendant upon high strength of suspension of automobile are actively advanced. In this paper, the effect of compressive residual stress of spring steel(JISG SUP-9) by shot-peening on fatigue crack growth characteristics in high temperatures($100^{\circ}C,\;150^{\circ}C,\;180^{\circ}C$) was investigated with considering fracture mechanics. So, we can obtain followings. (1) Compressive residual stress is decreased in high temperature, that is, with increasing temperature. (2) The effect of compressive residual stress on fatigue crack growth behavior in high temperature is increased below ${\Delta}K=17{\sim}19MPa\sqrt{m}$. The fatigue crack growth rate is increased with increasing temperature. The fatigue life is decreased with increasing temperature. (3) The dependence of temperature and compressive residual stress on the parameters C and m in Paris' law formed the formulas such as equations (3),(4),(5),(6),(7),(8),(9),(10). (4) It was investigated by SEM that the constraint of compress residual stress for plastic zone of fatigue crack tip was decreased in high temperature as compared with room temperature.

• Food Engineering Progress
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• v.14 no.4
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• pp.354-358
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• 2010

The methods for determining the diffusion parameters for the diffusion of d-limonene, a major volatile compound of orange juice, through a multi-layered food packaging material and predicting its absorption into the packaging material have been investigated. The packaging material used was the 1.5-mm thick multi-layered packaging material composed of high impact polystyrene (HIPS), polyvinylidene chloride (PVDC), and low density polyethylene (LDPE). Orange juice was placed in a cell where volatiles were absorbed in the sample package and kept at $23{\pm}2^{\circ}C$ for 72 hr. The d-limonene absorbed in a 1.5-mm thick multi-layered food packaging material was analyzed by a solid phase micro-extraction (SPME). The absorption parameters for the absorption of d-limonene in the packaging material were determined and absorption of d-limonene into the packaging material was predicted using absorption storage data. The SPME desorption at $60^{\circ}C$ for 1 hr resulted in the most sensitive and reproducible results. The diffusion coefficients of d-limonene in the packaging material and the partition coefficient at $23{\pm}2^{\circ}C$ were approximately $1-2{\times}10^{12}m^2$/s and 0.03, respectively. The absorption profile no earlier than 30 hr was fit well by a model derived from the Fick's law.

• Korean Journal of Food Science and Technology
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• v.24 no.6
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• pp.619-622
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• 1992

To increase utilization of Korean yam, the rheological properties of gelatinized yam (Dioscorea aimadoimo) starch solutions at various concentrations $(1{\sim}5%)$ and temperature $(30{\sim}60^{\circ}C)$ were investigated. The rheological behavior of gelatinized yam starch solutions was illustrated by power-law model and Casson equation and exhibited pseudoplastic behavior with yield stress. The pseudoplasticity of starch solutions increased largly concentration of starch increased. As the temperature increased from $30^{\circ}C$ to $60^{\circ}C$, the dependency of starch concentration decreased, B were decreased from 0.40449 to 0.39352. The activation energy of flow of gelatinized yam starch solutions were increased from 4.1415 to $5.45329{\times}10^6\;J/kg{\cdot}mol$ by increasing starch concentration from 1% to 5%.