• Title/Summary/Keyword: $-NO_{x}-$

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NO Removal Efficiency by Pulsed Corona Discharge Process at Room Temperature (상온 펄스 코로나 방전 공정에 의한 NO 제거 효율)

  • 김동주;박정환;김교선
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.5
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    • pp.337-344
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    • 2002
  • In this study, we analyzed the NO removal efficiency by the pulsed corona discharge process and investigated the effects of several process variables such as initial concentrations of NO, $H_2O$, and NH$_3$, applied voltage, pulse frequency, diameter of the discharge electrode, and residence time. The removal efficiency of NO increased by the addition of $H_2O$ or NH$_3$, but the changes of initial NH$_3$ and $H_2O$ concentrations did not affect the removal efficiency of NO significantly. With the increases of the applied voltage or the residence time, the removal efficiency of NO increased. In addition, with the increases of the pulse frequency of applied voltage, or the diameter of the discharge electrode, the removal efficiency of NO increased. The experimental results can be used as a basis to design the pulsed corona discharge process to remove NO$_{x}$, SO$_{x}$ and VOCs.OCs.

Removal Characteristics of Nitrogen Oxides (NOx) in Low Concentration using Peat-Mixed Media (피트(peat) 혼합담체를 이용한 저농도 질소산화물(NOx) 제거특성)

  • Kang, Young-Heoun;Kim, Deok-Woo;Kang, Seon-Hong;Kwon, Pil-Joo;Kim, Dal-Woo;Hwang, Pil-Gi;Shim, Sang-Bo
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.3
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    • pp.330-338
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    • 2010
  • In this study, removal characteristics of nitrogen oxides $(NO_x)$ from road transport by using peat as the packing media for biodegradation have been investigated in the long term. Physicochemical and biological treatment of peatmixed media eliminates any requirement to use chemical substances and also facilitates the biodegradable actions of microorganism. Safe biodegradation of pollutants, no need to apply additional microbes owing to their active growth, and no generation of secondary pollutants were found in this experiment. It was concluded that average removal efficiencies of nitric oxide (NO) and nitrogen dioxide $(NO_2)$ were 80% and 97% respectively with respect to the linear velocity 35~40 mm/s and 0.3 ppm ozone concentration in the long period operation. Inflow concentration of nitric oxide over 0.05 ppm was suitable when pretreated with ozone. Non-ozone stage was performed with linear velocity 20~100 mm/s and then the average removal efficiency of nitric oxide and nitrogen dioxide were 38% and 94% respectively. Other results showed that the apparent static pressure was raised with increases in applied water content and aerial velocity in mixed media during fan operation.

Studies on The Microbial Utilization of Agricultural Wastes (Part 5) Isolation and Selection of Cellulase Producing Fungi (농산폐자원의 미생물학적 이용에 관한 연구 (제오보) 섬유소분해효소 생산 곰팡이의 분리 및 선별)

  • Bae, Moo;Kim, Byung-Hong;Lee, Gye-Jun
    • Microbiology and Biotechnology Letters
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    • v.4 no.3
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    • pp.105-110
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    • 1976
  • In the studies of microbiological utilization of cellulosic wastes, cellulolytic fungi were isolated and screened out. At the first stage, 221 cellulolytic fungi were isolated from different sources such as soils, humus, composts and rotten wood debris by enrichment culture techniques. In the second stage, 36 strains of fungi out of those previously isolated were selected for their cellulase activities estimated by means of filter paper degradation, carboxy methyl cellulose liquefaction and cup method. Activities of C$_1$-cellulase, C$\sub$x/-cellulase and filter paper activity were adopted on the final screening stage and five different strains which are tentatively identified as Aspergillus sp.(strain No. AS-9), Penicillium sp. (strain No. KNI-1-2), Trichoderma, sp. (strain No. KI-7-2, KI-7-5, KI-4-1-1B) were selected for their high potency of C$_1$ and C$\sub$x/-cellulase activities. When rice straw milled and treated with NH$_4$OH was hydrolyzed with the crude enzyme Prepared from the culture broth of Trichoderma sp. (strain No. KI-4-1-1B), saccharification rate was obtained up to 26%.

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Removal of $NO_x$ by using of $TiB_2$ Photocatalysis ($TiB_2$ 광촉매를 이용한 $NO_x$ 제거)

  • Lee, Yong-Hwan;Choi, Im-Ho
    • Journal of environmental and Sanitary engineering
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    • v.24 no.4
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    • pp.112-115
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    • 2009
  • This research was performed to purify water quality through removing T-N, and T-P and to estimating rate of $NO_x$ by the response of photocatalyst using ceramics. The ceramics was a mixtures of Titanium Diboride($TiB_2$) which is used to develop armored cars with excellent protective power and lightness, Olivine, and Hwangto with water and was furnaced for an hour at $1160^{\circ}C$. Hwangto and Olivine used in the study are produced at Haenam-gun, Jeonnam, and Andong-city, Gyeongsangbuk-do, respectively. The ground Hwangto and Olivine were seived through PR $100{\times}200$, and $TiB_2$ was a product of SIGMA ALDRICH. The experiment was performed under the sunlight, Mass flow controller was used for constant flow to pass through the pyrex reactor which was fully charged with furnaced ceramics. The concentration of $NO_2$ gas passed through the pyrex reactor was measured by Multi Gas Monitor. The reaction took for 60 minutes, The material was exposed to sunlight for 40 minutes. The sunlight was interrupted before and after the exposure for 10 minutes. The result showed that the concentration of $NO_2$ gas of the ceramics with $TiB_2$ and without $TiB_2$ became reduced and then maintained the same concentration under the sunlight, and became increased when the sunlight is interrupted. The $NO_2$ removing efficiency of the ceramics mixed with $TiB_2$ was 14~43% higher than that of the ceramics without $TiB_2$ under the sunlight. The study showed that the removing rate of $NO_2$ was 80% when the mixture rate of Hwangto, Olivine, and $TiB_2$ was 68%, 30% and 2%.

A Study on Reduction of Nitrogen Oxide (NOx) and Stability of Incineration Facility by the Food Wastewater Incineration (음식물류 폐수 소각처리에 따른 질소산화물 저감 및 소각설비의 안정성 평가에 관한 연구)

  • Hwang, Seung-Min;Chung, Jin-Do;Song, Jang-Heon
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.10
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    • pp.901-908
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    • 2009
  • We examine the processing method of the food wastewater to direct spray at living waste incinerator. The demoscale stoker system is used as a incineration facility. The results show that it brings effect on the reduction of nitrogen oxide ($NO_x$) concentration as well as the ammonia ($NH_3$) amount in SNCR (selective non-catalytic reduction) by the incineration of food wastewater which is containing a plentiful ammoniac nitrogen ($NH_3$-N). Furthermore, the stability of incineration facility and the extension of operation period is actualized as a improvement of clogging phenomenon on outer wall of water pipe as the 870~$950^{\circ}C$ maintain of exit temperature in a second combustor by spray of the food wastewater. The 26 items of air pollution matter of nitrogen oxide ($NO_x$), sulfur oxide ($SO_x$) and dioxin etc. are measured. The results show that it is under the value of allowable exhaust standard.

Synthesis and Characterization of Tetranuclear Molybdenum(Ⅵ) Complexes with Butylamidoxime Derivatives (부틸아미드옥심 유도체의 몰리브덴(Ⅵ) 사핵 착물의 합성과 성질)

  • Roh, Soo-Gyun;Oh, Sang Oh
    • Journal of the Korean Chemical Society
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    • v.39 no.7
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    • pp.552-558
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    • 1995
  • The tetranuclear complexes, $X_2[M_{O4}O_12{R'C(NH_2)NO}_2](X= n-Bu_4N^+$, $R'=(CH_3)_2CH$, $CH_3CH_2CH_2$, $CH_3SCH_2$; $X=(CH_3)_2CHC(=NH_2)NH_2^+$, $R'=(CH_3)_2CH$; $X = CH_3CH_2CH_2C(=NH_2)NH_2^+$, $R'=CH_3_CH_2CH_2$; $X=CH_3SCH_2C(=NH_2)NH_2^+$, $R'=CH_3SCH_2)$ have been synthesized by the reactions of monomeric and polynuclear complexes with isobutyl-, butyl- and thiomethylacetamidoxime. The prepared complexes were identified by elemental analysis, infrared, $^1H$ NMR and $^{13}C$ NMR spectroscopy. The structure of complex ${(CH_3)_2CHC(NH_2)_2}_2[M_{O4}O_{12}{(CH_3)_2CHC(NH_2)NO}_2]$ was determined by X-ray single crystal diffraction. Crystal data are follows: Monoclinic, $P2_{1/c}$, $a=10.168(3){\AA}$, $b=11.768(1){\AA}$, $c=13.557(1){\AA}$, ${\beta}=102.08(1)^{\circ}$, $V=1586.2(5){\AA}^3$, Z=2, final R=0.026 for 2951($F_0>3s(F_0)$). This complex is composed of a planar cyclic $[Mo_4({\mu}-O)_4]$ and two ${\mu}_4$-amidoximate.

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Correlation Analysis of The X-Factor, X-Factor Stretch and Swing-Related Factors during Drive Swing (드라이버 스윙 시 X-Factor, X-Factor Stretch와 스윙 관련 변인의 상관관계 분석)

  • Lee, Kyung-Hun;Kwon, Moon-Seok;Lim, Young-Tae
    • Korean Journal of Applied Biomechanics
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    • v.25 no.2
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    • pp.149-155
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    • 2015
  • Purpose : Recently, many researchers and golf coachers demonstrated that X-factor and X-factor stretch had a co-relationship with driving distance. However, its relationship is still controversial and ambiguous. Thus, the aim of this study was to examine the relationship among X-factor, X-factor stretch and swing-related factors, including driving distance in elite golfers. Method : Seventeen male elite golfers (handicap: ${\leq}4$) with no history of musculo-skeletal injuries participated in the study. Thirty spherical retro-reflective markers were placed on including the middle point of PSIS, the right/left ASIS, the right/left lateral acromion of the scapula, driver head and shaft grip. All motion capture data was collected at 100Hz using 6 infrared cameras. Carry distance, club speed, ball speed, smash factor, launch angle, and spin rate were collected from radar-based device, TrackMan. Results : Pearson's correlation coefficient method was used to find the correlations among X-factor, X-factor stretch and swing-related factors. Positive correlations between driving distance and other swing-related factors which include club speed(r=.798, p<.001), and ball speed(r=.948, p<.001) were observed. In contrast to the swing-related factors, X-factor and X-factor stretch had no relationship to driving distance. Conclusion : These results indicate that X-factor and X-factor stretch are not key regulators in driving distance.

Evaluation of the Amount of Gas Generated through Combustion of Wood Charcoal and Agglomerated Charcoal Depending on Air Ventilation (숯과 성형숯의 연소를 통해 배출되는 가스 발생량 및 실내공간 환기량 평가)

  • JU, Young Min;JEONG, Hanseob;CHEA, Kwang-Seok;AHN, Byung-Jun;LEE, Soo Min
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.6
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    • pp.847-860
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    • 2020
  • This study was conducted into combustion characteristics and gases generated by the combustion of charcoal and agglomerated charcoal distributed in the domestic using a combustion chamber based on the average space per crater of a charcoal-grilled restaurant in South Korea. Each of the three types of charcoals and agglomerated wood charcoals was analyzed for fuel and combustion characteristics. In addition, the concentration changes of CO, CO2, NOx, and O2 were measured for 20 minutes depending on ventilation. As a result, CO yield without ventilation was measured in the range of 1390 to 4703 ppm, and CO yield with ventilation decreases about 29.8% to 57.4%. CO2 yield without ventilation was measured in the range of 1.34% to 2.42%, and CO2 yield was about 44.1% to 53.6% when the emission was more than about 1.5% at 10 minutes. The NOx yield was divided into two cases where the NOx yield was continuously increased because of incomplete combustion, emitted ranging from 29 ppm to 47 ppm, and where emission was constant after 1 minute in the range of 9 ppm to 18 ppm. The NOx yield with ventilation tends to be similar to the without ventilation, and NOx yield decreases up to 62.5%. Therefore, it could be used for health risk assessment with the simulation of the usage environment of charcoal and agglomerated wood charcoal.

Electrical properties of n-type $WO_{3}$ based gas sensors (N-형 $WO_{3}$계 가스센서의 전기적 특성)

  • Yang, Jong-In;Kim, Il-Jin;Lim, Han-Jo;Han, Sang-Do;Chung, Kwan-Soo
    • Journal of Sensor Science and Technology
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    • v.7 no.3
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    • pp.188-196
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    • 1998
  • The sensing and electrical characteristics of $WO_{3}$-based n-type semiconductor gas sensors are investigated. In normal air condition, $TiO_{2}$(4 wt. %)-doped $WO_{3}$-based sensor fabricated without any binder shows the grain boundary ( GB ) potential barrier height of 0.26 V. Sensors fabricated with alumina, PVA and silica sol binders show 0.17, 0.22 and 0.26 V of GB potential barrier height, respectively. In the ambience of 120 ppm $NO_{x}$ concentration, the GB potential barrier height of the sensor fablicated without binder is increased to 0.59 V. The sensors were fabricated with alumina, PVA, silica sol binders show 0.43, 0.66 and 0.52 V of potential barrier, respectively. Thus the variation of the potential barrier at GB is largest in the sensor fabricated with the PVA binder. This is found to be the main reason why the sensor fabricated with the PVA binder shows the best sensitivity. It is also found that the decrease of sensitivity at a temperature higher than the optimum operation temperature is due to the temperature dependence of the sensor resistance in normal air condition rather than the desorption of the adsorbed $NO_{x}$ gas particles. In the ambience of 250 ppm CO concentration, the GB potential barrier heights of the sensors fabricated without binder and with PVA binder are about 0.2 V showing negligible change compared to the case of normal air ambience. This fact indicates that these sensors are good candidates for the selective detection of $NO_{x}$ gas in the mixture of CO and $NO_{x}$ gases.

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A Study on the Ozone Control Strategy using the OZIPR in the Seoul Metropolitan Area

  • Jin, Lan;Lee, Sun-Hwa;Shin, Hye-Jung;Kim, Yong-Pyo
    • Asian Journal of Atmospheric Environment
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    • v.6 no.2
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    • pp.111-117
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    • 2012
  • To establish area specific control strategy for ambient ozone in the Seoul Metropolitan Area (SMA), the maximum ozone concentration in each local government district in the SMA were estimated by using the OZone Isopleth Plotting Package for Research (OZIPR) model. The modeling period was June 2000 and the emission inventory data used were from National Institute of Environmental Research (NIER). Except the islands of Incheon, whole Seoul and Incheon areas were volatile organic compounds (VOCs) limited, i.e., decreasing the oxides of nitrogen ($NO_X$) emission alone may increase the maximum ozone concentration upto certain point. In Gyeonggi, 12 areas were VOCs limited while 12 areas were in between VOCs limited and $NO_X$ limited, i.e., decreasing both $NO_X$ and VOCs emission may decrease the maximum ozone concentration. Majority of the estimated ozone values were lower than the measured values. The reason could be inaccuracy in emission inventories and/or transport from other areas. The same calculation was carried out for June 2004 and it was found that Seoul was still in the VOCs limited condition.