• Title/Summary/Keyword: $-NO_{x}-$

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Estimation of growth stage-based nitrogen supply levels for greenhouse semi-forcing zucchini cultivation (시설애호박 관비재배 시 생육단계별 질소요구량 산정)

  • Ha, Sang-Keun;Sonn, Yeon-Kyu;Jung, Kang-Ho;Lee, Ye-Jin;Cho, Min-Ji;Yun, Hye-Jin;Sung, Jwa-Kyung
    • Korean Journal of Agricultural Science
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    • v.42 no.4
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    • pp.319-324
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    • 2015
  • An estimation of the requirement of minerals based on growth stage and cropping pattern is very important for greenhouse zucchini. This study was performed at farmer's field which was applied with a fertigation system and a semi-forcing cultivation from Feb. to July in 2014, and nitrogen levels were set up with x0.5, x0.75, x1.0 and x1.5 of the NO3-N-based soil-testing recommendation for zucchini cultivation. Top dressing of nitrogen (basal : top = 4 : 6) and potassium (basal : top = 3 : 7) was applied with an interval of every two weeks from two and six weeks after transplanting, respectively, and phosphorus was totally supplied with basal dressing. The nitrogen uptake was the order of x1.0, x0.75, x1.5 and x0.5, phosphorus, x1.0, x0.75, x0.5 and x1.5, and potassium, x0.75, x1.0, x1.5 and x0.5. From these results, it was suggested that highest mineral uptake could be reached between x0.75 and x1.0 of the NO3-N-based soil-testing recommendation. In conclusion, nutrient management based on the growth stage was proven to be better method for favorable growth and yield of zucchini.

Synthesis and electrochemical properties of layered $Li[Ni_xCo_{1-2x}Mn_x]O_2$ materials for lithium secondary batteries prepared by mechanical alloying (기계적 합금법을 이용한 리튬 2차 전지용 층상 양극물질 $Li[Ni_xCo_{1-2x}Mn_x]O_2$ 의 합성 및 전기화학적 특성에 관한 연구)

  • 박상호;신선식;선양국
    • Proceedings of the Korea Crystallographic Association Conference
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    • 2002.11a
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    • pp.16-16
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    • 2002
  • The presently commercialized lithium-ion batteries use layer structured LiCoO₂ cathodes. Because of the high cost and toxicity of cobalt, an intensive search for new cathode materials has been underway in recent years. Recently, a concept of a one-to-one solid state mixture of LiNO₂ and LiMnO₂, i.e., Li[Ni/sub 0.5/Mn/sub 0.5/]O₂, was adopted by Ohzuku and Makimura to overcome the disadvantage of LiNiO₂ and LiMnO₂. Li[Ni/sub 0.5/Mn/sub 0.5/]O₂ has the -NaFeO₂ structure, which is characteristic of the layered LiCoO₂ and LiNiO₂ structures and shows excellent cycleability with no indication of spinel formation during electrochemical cycling. Layered Li[Ni/sub x/Co/sub 1-2x/Mn/sub x/]O₂ (x = 0.5 and 0.475) materials with high homogeneity and crystallinity were synthesized using a mechanical alloying method. The Li[Ni/sub 0.475/Co/sub 0.05/Mn/sub 0.475/]O₂ electrode delivers a high discharge capacity of 187 mAh/g between 2.8 and 4.6 V at a high current density of 0.3 mA/㎠(30 mA/g) with excellent cycleability. The charge/discharge and differential capacity vs. voltage studies of the Li[Ni/sub x/Co/sub 1-2x/Mn/sub x/]O₂ (x = 0.5 and 0.475) materials showed only one redox peak up to 50 cycles, which indicates that structural phase transitions are not occurred during electrochemical cycling. The magnitude of the diffusion coefficients of lithium ions for Li[Ni/sub x/Co/sub 1-2x/Mn/sub x/]O₂(x = 0.5 and 0.475) are around 10/sup -9/ ㎠/s measured by the galvanostatic intermittent titration technique (GITT).

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Temperature and Ligand Effects on the Eu(Ⅲ) Emission Spectra in the Aqueous Solution (수용액에서의 Eu(Ⅲ) 착물의 형광스펙트럼에 영향을 미치는 온도 및 리간드 효과에 관한 연구)

  • Lee, In Suk;Kim, Geon
    • Journal of the Korean Chemical Society
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    • v.34 no.6
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    • pp.548-554
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    • 1990
  • Temperature effects on the fluorescence emission spectra of 0.01 M Eu(III) ion with ClO$_4$, Cl$^-$, NO$_3$ were studied. Relative intensity change of hypersensitive band ($^5D0\; {\to}\;^7F_2$) and nonhypersensitive band ($^5D0 \;{\to}\;^7F_1$) was quite remarkable with temperature and ligand. The relative intensity change was interpreted as the change of formation constant and used to calculation the enthalpy change of $Eu(H_2O)_X^{3+}$+ to EuL(H$_2O)_{X-1}^{2+}$ complex. $\Delta{H}$ of $Eu(H_2O)_X^{3+}$ to EuCl(H$_2O)_{X-1}^{2+}$ was roughly 15 kJ/mol and temperature independent, but $\Delta{H}$ of EuNO$_3(H_2O)_{X-1}^{2+}$ was changed with temperature; -11 kJ/mol at 25$^{\circ}C$ and 47 kJ/mol at 250$^{\circ}C$.

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Performance Evaluation of Nitrogen Oxide Removal by Air Purification Blocks with Titanium Dioxide (이산화티타늄을 이용한 대기정화 블록의 질소산화물 제거 성능 평가)

  • Oh, Ri-On;Kim, Hwang-Hee;Park, Sung-Ki;Cha, Sang-Sun;Park, Chan-Gi
    • Journal of The Korean Society of Agricultural Engineers
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    • v.62 no.5
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    • pp.39-46
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    • 2020
  • This study evaluated the nitrogen oxide (NOx) removal efficiency by air purification concrete blocks with titanium dioxide (TiO2). The concrete in the mixtures had a 30% water:cement ratio, to which TiO2 was added at 0%, 5%, and 10% of cement weight. The compressive strength reduction rate and removal efficiency of NOx were investigated. The result of the compressive strength test in the study indicated that addition rate of TiO2 did not lead to signifcant effect. In terms of the average removal efficiency of NOx, mix No. 1 using a TiO2 mixing ratio of 0% had a removal efficiency of 0.57% on average; thus, the removal effect w as not significant. For the other samples prepared by mixing, the average removal efficiencies for mix No. 2 (5% TiO2) were 58.86% and 62.05% for normal and washing surface treatments, respectively, and those of sample No. 3 (10% TiO2) were 59.94% and 67.61%. mixs No. 4 (5%) and No. 5 (10%), in which TiO2 diluted with distilled water was sprayed onto the block surface, had an average NOx removal efficiency of 61.72% and 68.48%, respectively. In terms of NOx removal efficiency, Mixs No. 3 and No. 5 with 10% TiO2 were better than Mixs No. 2 and No. 4 with 5% TiO2. In addition, analyzing the NOx removal efficiency results from the fixing method, it was capable to apply mixing (washing) and the diluted spray methods. Therefore, it was found that the diluted spray method applied in this study can be employed in any manufacture of air purification concrete blocks.

Fabrication and Gas-Sensing Characteristics of $NO_x$ Sensors using $WO_3$ Thin Films ($WO_3$ 박막을 이용한 $NO_x$ 센서의 제조 및 가스감도 특성)

  • 유광수;김태송;정형진
    • Journal of the Korean Ceramic Society
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    • v.32 no.12
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    • pp.1369-1376
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    • 1995
  • The WO3 thin-film NOx sensor which is of practical use and includes the heater and the temperature sensor was fabricated. The WO3 thin films as a gas-sensing layer was deposited at ambient temperature in a high-vacuum resistance heated evaporator. The highest sensitivity of the WO3 thin-film sensor to NOx was obtained under the condition of the annealing temperature of 50$0^{\circ}C$ and the operating temperature of 30$0^{\circ}C$. The gas sensing characteristics of this sensor was excellent, i.e. high sensitivity (Rgas/Rair in 3 ppm NO2=53) and fast response time (4 seconds).

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Flow Analysis of PM/NOX Reduction System for Emergency Generator (비상발전기용 PM/NOX 저감장치의 유동특성 연구)

  • Bang, Hyo-Won;Park, Gi-Young;Lee, Seong-Wock
    • Journal of ILASS-Korea
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    • v.26 no.4
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    • pp.163-170
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    • 2021
  • Emergency generators normally use diesel engines. The generators need to conduct weekly no-load operation inspections to ensure stable performance at emergency situations. In particular, the generators with large diesel engines mainly use rectangle type filter substrates. In order to minimize hazardous emissions generated by generators, optimizing the reduction efficiency through CFD analysis of flow characteristics of PM/NOX reduction system is important. In this study, we analyzed internal flow by CFD, which is difficult to confirm by experimental method. The main factors in our numerical study are the changes of flow uniformity and back pressure. Therefore, changes in flow characteristics were studied according to urea injector locations, selective catalyst reduction (SCR) diffuser angle, and filter porosity.