• Title/Summary/Keyword: ${\omega}-3$

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Temperature and Ligand Effects on the Ho(Ⅲ) Absorption Spectra in Aqueous Solution (수용액에서의 Ho(III) 착물의 흡수 스펙트럼에 영향을 미치는 온도 및 리간드 효과에 관한 연구)

  • Mi Kyeong Kim;Wha-Jin Han;Seung Jun Jeon;Keon Kim
    • Journal of the Korean Chemical Society
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    • v.36 no.6
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    • pp.824-831
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    • 1992
  • Absorption spectra were observed for several Ho(III)-ligand systems in aqueous solution under the changes of ligand concentration and temperature. The intensity change of hypersensitive band $(^5I_8\;\to\;^5G_6)$ was quite remarkable with temperature and concentration, and was interpreted as the change of coordination environments. The transition intensities observed in these spectra were analyzed in terms of the Judd-Ofelt intensity parameters, $\Omega_\lambda$ ($\lambda$ = 2, 4, 6), for 4f $\to$ 4f electric dipole transitions. The $\Omega_2$ parameter was the most sensitive to the temperature and concentration. Using the changes of $\Omega_2$, $Cl^-$ and ${NO_3}^-$ ions were found to form inner sphere complexes in aqueous solution.

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An XMT Authoring System supporting Multiple Presentation Environments (다양한 재생 환경을 지원하는 XMT 저작 시스템)

  • 김희선;임영순
    • Journal of KIISE:Computing Practices and Letters
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    • v.10 no.3
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    • pp.251-258
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    • 2004
  • The XMT standard is MPEG-4 Scene Description of textual format. It can be utilized to edit the audio/video media for broadcasting and develop the user oriented media contents. This paper proposes XMT authoring system that supports exchange among contents in various presentation environment. The XMT authoring system creates two levels of textual syntax and semantics: XMT-$\alpha$ format and XMT-$\Omega$ format. Because XMT-$\alpha$ and XMT-$\Omega$ have different expression method about an object, the authoring tool offers interface for them. the authoring tool offers interface for them. Also, it defines interior data structure that can support two file formats, and offers the function that transforms XMT-$\alpha$ into BIFS and transforms XMT-$\Omega$ into SMIL or XMT-$\alpha$. It offers interoperability among multimedia data in various environment that is XMT's characteristic.

Study on diffusion barrier properties of Tantalum films deposited by substrate bias voltage (Ta 확산 방지막 특성에 미치는 기판 바이어스에 관한 연구)

  • ;;Minoru Isshiki
    • Journal of the Korean Vacuum Society
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    • v.12 no.3
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    • pp.174-181
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    • 2003
  • Ta diffusion barriers have been deposited on Si (100) substrate by applying a negative substrate bias voltage. The effect of the substrate bias voltage on the properties of the Ta films was investigated. In the case of the Ta films deposited without the substrate bias voltage, a columnar structure and small grains were observed distinctly, and the electrical resistivity of the deposited Ta films was very high (250 $\mu\Omega$cm). By applying the substrate bias voltage, no clear columnar structure and grain boundary were observed. The resistivity of the Ta films decreased remarkably and at a bias voltage of -125 V, reaching a minimum value of 40 $\mu\Omega$cm, which is close to that of Ta bulk (13 $\mu\Omega$cm). The thermal stability of Cu(100 mm)/Ta(50 mm)/Si structures was evaluated after annealing in H2 atmosphere for 60 min at various temperatures. The Ta films deposited by applying the substrate bias voltage were found to be stable up to $600^{\circ}C$, while the Ta films deposited without the substrate bias voltage degraded at $400^{\circ}C$.

Grain boundary structure and electrical characteristics of alkaline metallic cation-diffused $(SrCa)TiO_3$ ceramics (알칼리 금속 이온의 입계확산에 따른 $(SrCa)TiO_3$ 소결체의 입계구조 및 전기적 특성)

  • Heo, Hyeon;Cho, Nam-Hui
    • Journal of the Korea Institute of Military Science and Technology
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    • v.2 no.1
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    • pp.183-193
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    • 1999
  • Semiconducting (Sr0.85Ca0.15)TiO3 ceramics were prepared by conventional powder synthesis techniques, and then alkaline metallic cations were diffused into the ceramic bodies. The threshold voltage of the ceramics increases with increasing diffusion time and the amount of diffused materials. The ceramics had boundary potential heights of 0.01 ~ 2.89 eV, while their boundary resistance ranged from 2.2 $M{\Omega}$ to 120.4 $M{\Omega}$. Such electrical characteristics of the boundaries were correlated with the boundary structure of the ceramics obtained by transmission electron microscopy.

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A study of PTC thermistor characteristics by dopant Mn&Nb for $BaTiO_3$ semiconducting ceramics with Ca addition (Ca가 첨가된 $BaTiO_3$ 반도성 세라믹스에 있어서 첨가제 Mn과 Nb에 의한 PTC 써미스터 특성 연구)

  • Choi, K.C.;Lee, N.H.;Park, S.H.;Kim, Y.H.;Chu, S.N.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1999.11d
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    • pp.987-990
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    • 1999
  • 본 연구에서는 $BaTiO_3$를 기본 조성으로 하여 PTC 써미스터를 제조하였으며 여기에 첨가제로서 Ca, Mn, Nb의 양을 순차적으로 변화시켜 미세구조 및 전기적 특성을 연구하였다. 또한 복소 임피던스 측정을 통해서 PTC 효과에 미치는 주 저항 성분에 대해서 고찰하였다. Ca 첨가 실험에서는 5[mol%] 첨가된 시편에서 $2.3{\times}10^7[\Omega{\cdot}cm]$의 높은 peak 비저항이 나왔으며 Mn과 Nb에서는 각각 0.1[mol%], 0.2[mol%]에서 $1.5{\times}10^8[\Omega{\cdot}cm]$$3.71{\times}10^9[\Omega{\cdot}cm]$의 수치가 측정되었다. 또한 Nb 첨가 실험에서는 첨가량이 증가할수록 결정립의 크기가 조밀해지는 현상을 보였다. PTC 효과에 미치는 주 저항 요소에 대해서 관찰한 복소 임피던스 측정에서는 결정립계 저항 성분이 주가 됨을 확인 하였다.

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Electrical and Structural Properties of GAZO Films Deposited by DC Magnetron Co-sputtering System with Two Cathodes (DC 마그네트론 Co-sputtering 시스템을 이용하여 증착한 GAZO 박막의 전기적 및 구조적 특성)

  • Jie, Luo;Park, Se-Hun;Song, Pung-Keun
    • Journal of the Korean institute of surface engineering
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    • v.42 no.3
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    • pp.122-127
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    • 2009
  • Ga/Al doped ZnO (GAZO) thin films were prepared on non-alkali glass substrate by co-sputtering system using two DC cathodes equipped with AZO ($Al_2O_3$:2.0 wt%) target and GZO ($Ga_2O_3$:6.65 wt%) target. This study examined the influence of Al/Ga concentration and substrate temperature on the electrical, structural and optical properties of GAZO films. The lowest resistivity $1.95{\times}10^{-3}{\Omega}cm$ was obtained at room temperature. With increasing substrate temperature, resistivity of GAZO film decreased to a minimum value of $7.47{\times}10^{-4}{\Omega}cm$ at below $300^{\circ}C$. Furthermore, when 0.05% $H_2$ gas was introduced, resistivity of GAZO film decreased to $6.69{\times}10^{-4}{\Omega}cm$. All the films had a preferred orientation along the (002) direction, indicating that the deposited films have hexagonal wurtzite structure formed by the textured growth along the c-axis. The average transmittance of the films was more than 85% in the visible light range.

Molybdeum Oxide Film Preparation by a Magnetic Null Discharge Sputtering and its Application (자기 중성방전 스퍼터링에 의한 산화몰리브덴 박막의 제작 및 그 응용)

  • Kim, Doo-Hwan;Park, Cha-Soo;Sung, Youl-Moon
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.23 no.1
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    • pp.169-175
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    • 2009
  • In this experiment molybdeum oxide($MoO_3$) films were prepared by a magnetic null discharge(MND) sputtering system and fundamental properties by XRD, XPS and SEM analysis were investigated. The initial and mean insulation resistance of the same with $MoO_3$ film were about 1.4[$M{\Omega}$] and 800[$k{\Omega}$] under the condition of applied voltage of 400[V]. The preferred orientation in the films changed from(100) to (210) with substrate temperature. Two XPS peaks of the $MoO_3$ photoelectron were detected at the binding energies of 228.9[eV] and 232.4[eV], while the binding energy of the O1s peak was 532.6[eV]. The substrate temperature and reactivity gives large effects to the structure and growth of the film and system is also very useful for performing the uniform reactive deposition. It can be found from the result of a $MoO_3$ film deposition that the system is very useful for performing the uniform reactive sputtering.

Changes of Fatty Acid Compositions in Brain Phospholipids of Developing Chicken Embryos (발생중인 닭의 배자에서 뇌 조직내 인지질의 지방산 조성 변화)

  • 김희성;최인숙;지규만
    • Korean Journal of Poultry Science
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    • v.22 no.1
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    • pp.31-42
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    • 1995
  • This study was to investigate the effects of dietary linoleic acid(18:2\omega6, LA) and aipha-linolenic acid(18:3\omega3. \alpha-LNA) levels on brain development and fatty acid compositions of various lipid classes in the chicken embryo brain tissues. Thirty two ISA Brown layers, 52 weeks-old, were divided into four groups. Birds of each group were given corn-soybean meal based diets added with 1) safflower oil 8%, 2) safflower oil 6% + perilla oil 2%, 3) safflower oil 2% + perilla oil 6%, or 4) perilla oil 8%. Mter 15 days fed the diets. the layers were artificially inseminated to obtain fertile eggs. During the incubation. embryonic brains were sampled at 15th and 21st days. Fatty acid contents were quantitated by using heptadecanoic acid (17:0) as an internal standard. No significant differences in brain weight and in contents of various lipids such as phospholipid. triglyceride, cholesterol. cholesterol ester and free fatty acid in the tissues were found among the dietary groups (P<0.05). The ratios of AA/LA in the brain lipid classes were lowered as the dietary levels of perilla oil were increased. Higher LA was found in phosphatidylcholine(PC) than arachidonic acid (20:4\omega6. AA), meanwhile the level of LA was less than AA in phosphatidylethanolamine(PE). Docosahexaenoic acid(22:6\omega3, DHA) was the* major fatty acid in the tissue and its content in PE was 2.5~3 times higher than in PC. DHA level in the phospholipid reached at a peak (1.7~1.8 mg/brain) in dietary groups added with 6% or 8% perilla oil. suggesting that no more increase in that fatty acid level in the brain tissue could be obtained by consuming more \alpha-LNA, the major precursor of DHA.

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Resistive Humidity Sensor from Copolymers Containing Quaternary Ammonium Salt (I): Three Component Copolymers (4차 암모늄염을 포함하는 공중합체를 이용한 저항형 습도센서(I) : 3원 공중합체)

  • Lee, Dong-Geun;Lim, Tae-Ho;Jeon, Young-Min;Gong, Myoung-Seon
    • Polymer(Korea)
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    • v.31 no.3
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    • pp.194-200
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    • 2007
  • The resistive-type polymeric humidity sensors were prepared from the copolymers of [2- [(methacryloyloxy)ethyl] dimethyl] propylammonium bromide(MEPAB), [2- [(methacryloyloxy)ethyl]-2-hydroxyethyl]dimethylmonium bromide (MEHDAB), n-butyl methylacrylate(MBA), 2-hydroxyethyl methylacrylate(HEMA) and styrene. Four kinds of copolymers, ie, MEPAB/styrene/MEHDAB MEHDAB/BMA/HEMA, MEPAB/BMA/MEHDAB, and MEPAB/styrene/HEMA crosslinked with blocked-isocyanate on the Ag/Pd electrode/alumina substrate showed good durability at high humidities. The various electrical properties such as frequency dependency, temperature dependency, hysteresis, response time and water durability were examined. In the case of copolymer MEPAB/BMA/MEHDAB= 3/6/1, the resistance was varied from $2.9 M{\Omega}$ to $1.84k{\Omega}$ at $25^{\circ}C$ in the range of $30{\sim}90%RH$ and this copolymers showed a good linearity and low hysteresis.

Protective effect of dietary oils containing omega-3 fatty acids against glucocorticoid-induced osteoporosis

  • Elbahnasawy, Amr Samir;Valeeva, Emiliya Ramzievna;El-Sayed, Eman Mustafa;Stepanova, Natalya Vladimirovna
    • Journal of Nutrition and Health
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    • v.52 no.4
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    • pp.323-331
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    • 2019
  • Purpose: Glucocorticoids (GCs) are implicated in secondary osteoporosis, and the resulting fractures cause significant morbidity. Polyunsaturated fatty acids (PUFAs) play a vital role in bone metabolism. However, few trials have studied the impact of omega-3 PUFA-containing oils against GC-induced osteoporosis. Therefore, the present study was undertaken to determine whether supplementation with omega-3 PUFA-containing dietary oils such as fish oil, flaxseed oil or soybean oil can impede the development of GC-induced osteoporosis. Methods: The fatty acids (FAs) content of oils was determined using gas chromatography. Male rats were subdivided into 5 groups (8 rats each): normal control (balanced diet), prednisolone control (10 mg/kg prednisolone daily), soybean oil (prednisolone 10 mg/kg + soybean oil 7% w/w), flaxseed oil (prednisolone 10 mg/kg + flaxseed oil 7% w/w), and fish oil (from cod liver; prednisolone 10 mg/kg + fish oil 7% w/w). Results: The study data exhibited a significant depletion in bone mineral density (BMD) and femur mass in the prednisolone control compared to the normal control, accompanied with a marked decrease in the levels of plasma calcium and 1,25-$(OH)_2$-vitamin $D_3$, and elevated levels of C-terminal telopeptide (CTX), tumor necrosis factor-alpha (TNF-${\alpha}$) and malondialdehyde (MDA). Supplementation with fish oil, soybean oil or flaxseed oil helped to improve plasma calcium levels, and suppress oxidative stress and inflammatory markers. Additionally, bone resorption was suppressed as reflected by the decreased CTX levels. However, fish oil was more effective than the other two oils with a significant improvement in BMD and normal histological results compared to the normal control. Conclusion: This study demonstrated that supplementation with dietary oils containing omega-3 PUFAs such as fish oil, soybean oil or flaxseed oil can play a role in the prevention of bone loss and in the regulation of bone metabolism, especially fish oil which demonstrated a greater level of protection against GC-induced osteoporosis.