• Title/Summary/Keyword: ${\gamma}'$ phase

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Crystallization of Poly(vinylidene fluoride)-SiO2 Hybrid Composites Prepared by a Sol-gel Process

  • Cho, Jae Whan;Sul, Kyun Il
    • Fibers and Polymers
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    • v.2 no.3
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    • pp.135-140
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    • 2001
  • Organic-inorganic hybrid composites consisting of poly(vinylidene fluoride) (PVDF) and SiO$_2$ were prepared through a sol-gel process and the crystallization behavior of PVDF in the presence of $SiO_2$ networks was investigated by spectroscopic, thermal and x-ray diffraction measurements. The hybrid composites obtained were relatively transparent, and brittleness increased with increasing content of tetraethoxysilane (TEOS). It was regarded from FT-lR and DSC thermal analyses that at least a certain interaction existed between PVDF molecules and the $SiO_2$ networks. X-ray diffraction measurements showed that all of the hybrid samples had a crystal structure of PVDF ${\gamma}$-phase. Fresh gel prepared from the sol-gel reaction showed a very weak x-ray diffraction peak near 2$\theta$=$21^{\circ}$ due to PVDF crystallization, and Intensity increased grade-ally with time after gelation. The crystallization behavior of PVDF was strongly affected by the amount of $SiO_2$ networks. That is, $SiO_2$ content directly influenced preference and disturbance fur crystallization. In polymer-rich hybrids, $SiO_2$ networks had a favorable effect on the extent of PVDF crystallization. In particular, the maximum portent crystallinity of PVDF occurred at the content of 3.7 wt% $SiO_2$ and was higher than that of pure PVDF. However. beyond about 10 wt% $SiO_2$, the crystallization of PVDF was strongly confined.

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The manufacture of poly(vinylidene fluoride) thin film through vapor deposition method (진공증착법을 이용한 PVDF 박막의 제작)

  • Park, S.H.;Im, U.C.;Han, S.O.;Jin, G.S.;Chung, H.D.;Park, K.S.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1995.07c
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    • pp.1190-1192
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    • 1995
  • Poly(vinylidene fluoride)(PVDF) is one of the most studied polymers in the latest date. The interest in PVDF lies in its remarkable piezoelectric and pyroelectric properties. Also, PVDF has at least four known crystalline structures(; they are referred to as the ${\alpha},\;{\beta},\;{\gamma}\;and\;{\alpha}_p$ phase or forms II, I, III and $IV_p$). In this study, the manufactured PVDF thin film through vapor deposition method had form II(; the glass at $70^{\circ}C$). This thin film was investigated by x-ray diffraction(XRD), Fourier Transform Infrared(FT-IR) spectroscopy and Differential Thermal Analysis(DTA). XRD and FT-IR indicate crystallization forms from the glass at $70^{\circ}C$ into form II.

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Causality Assessment of Adverse Events on Acupuncture (침의 유해사례 인과성 평가 연구)

  • Jung, Hee-Jung;Choi, Jun-Yong;Park, Ji-Eun;Kim, Kun-Hyung;Choi, Sun-Mi;Oh, Dal-Seok
    • Korean Journal of Acupuncture
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    • v.25 no.2
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    • pp.95-105
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    • 2008
  • Objectives : This study is to establish the appropriate assessment of causalities from adverse events (AEs) which are related to acupuncture treatment. Methods : We assessed thirty AEs which were caused in the early phase trial on concomitant use of acupuncture and herbal medicines. We scored each AE on the questionnaire in Naranjo and SNU algorithm scale which are for drug causality assessment in pharmacoepidemiology. Results : In Naranjo scale, there were consistencies among the evaluators qualitatively with "Probable", "Possible" degree. In reliability test, parameters, such as, gamma and kendall's tau-b revealed the degrees of 73%, and 32%, respectively. There were disaccordant tendency in SNU algorithm scale. Conclusion : A new algorithm which reflects acupuncture properties should be developed and elucidated.

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Immune Responses of NIH Mice Infected with Avirulent and Virulent Strains of Plasmodium chabaudi adami Single and Mixed Infections

  • Namazi, M.J.;Phillips, R.S.
    • Parasites, Hosts and Diseases
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    • v.48 no.1
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    • pp.23-33
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    • 2010
  • An understanding of the nature of the immune response to asexual erythrocytic stages of malaria parasites will facilitate vaccine development by identifying which responses the vaccine should preferentially induce. The present study examined and compared the immune responses of NIH mice in either single or mixed infections with avirulent (DK) or virulent (DS) strains of Plasmodium chabaudi adami using the ELISA test for detecting and measurement of cytokines and antibody production. In both single and mixed infections, the study showed that both cell- and antibody-mediated responses were activated. In all experiments, an early relatively high level of IFN-$\gamma$ and IgG2a during the acute phase of the infection, and later elevation of IL-4 and IgG1, suggested that there was a sequential Th1/Th2 response. However, in the avirulent DK strain infection a stronger Th1 response was observed compared to the virulent DS strain-infection or in mixed infections. In the virulent DS infection, there was a stronger Th2 response compared to that in the DK and mixed infections. The faster proliferation rate of the virulent DS strain compared to the DK strain was also evident.

Serum Carotenoid, Retinol and Tocopherol Concentrations and Risk of Cervical Cancer among Chinese Women

  • Zhang, Yuan-Yuan;Lu, Ling;Abliz, Guzalnur;Mijit, Fatima
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.7
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    • pp.2981-2986
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    • 2015
  • Background: Despite many epidemiological studies on the effects of dietary antioxidant micronutrients on risk of cervical cancer, the findings remain uncertain and little evidence is available for serum nutrient markers. The present study aimed to examine the relationship between serum carotenoid, retinol and tocopherol concentrations and risk of cervical cancer among Chinese women. Materials and Methods: We conducted a hospital-based case-control study in which 358 adults (158 incident cases and 200 controls) were recruited from Xinjiang, China. Serum levels of carotenoids (${\alpha}$-carotene, ${\beta}$-carotene, ${\beta}$-cryptoxanthin, lycopene and lutein/zeaxanthin), retinol, and tocopherols (${\alpha}$-tocopherol and ${\gamma}$-tocopherol) were assessed by reverse-phase high-performance liquid chromatography. Results: We found inverse associations between serum carotenoid (${\alpha}$-carotene, ${\beta}$-carotene, and lutein/zeaxanthin) and tocopherol (${\alpha}$-tocopherol) concentrations and the risk of cervical cancer after adjusting for potential confounders, but a null association for retinol. The ORs for 1-SD increase were 0.71 (95 % CI: 0.56-0.92; p=0.003) for total carotenoids and 0.75 (95 % CI: 0.60-0.94; p=0.008) for total tocopherols. Conclusions: These results show that higher serum concentrations of some carotenoids and tocopherols are associated with a lower risk of cervical cancer among Chinese women.

Effect of composition and structure on exchange anisotropy of IrxMn(100-x)/NiFe films

  • Suh, Su-jung;Park, Young-suk;Ro, Jae-chul;Yong-sung;Yoon, Dae-ho
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.06a
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    • pp.91-95
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    • 1998
  • Exchange anisotropy between IrMn antiferromagnetic layer and NiFe ferromagnetic layer has been studied in IrxMn(100-x)/NiFe/Buffr/Si(100) films deposited by D. C. magnetron sputtering method. Among Zr, Ta, and Cu used as buffer layer, Zr and Ta enhanced the fcc(111) texture of NiFe and IeMn layer, but Cu did not affect microstructure of those layer. Strong fcc(111) texture of IrMn layer was confirmed to be the origin of exchange anisotropy of IrMn. Ir composition control in IrMn layer showed that {{{{ gamma -phase}}}} IrMn is stabilized between 10 and 30 at % Ir, an 21 at. % Ir in IrMn layer was optimum composition that showed maximum exchange anisotropy field. above 200 ${\AA}$ thickness of IrMn, antiferromagnetic property is stabilzed to show saturated exchange anisotropy field. Based pressure was confirmed to be critical requisite in IrMn-based spin-valve GMR system.

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Development of high capacity stirling cryocooler

  • Ko, Junseok;Yeom, Hankil;Kim, Hyobong;Hong, Yong-Ju;In, Sehwan;Park, Seong-Je
    • Progress in Superconductivity and Cryogenics
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    • v.17 no.3
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    • pp.51-56
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    • 2015
  • Cryogenic cooling system for HTS electric power devices requires a reliable and efficient high-capacity cryocooler. A Striling cryocooler with a linear compressor can be a good candidate. It has advantages of low vibration and long maintenance cycle compared with a kinematic-driven Stirling cryocooler. In this study, we developed dual-opposed linear compressor of 12 kW electric input power with two 6 kW linear motors. Electrical performance of fabricated linear compressor is verified by experimental measurement of thrust constant. The developed Stirling cryocooler has gamma-type configuration. Piston and displacer are supported with flexure spring. A slit-type heat exchanger is adopted for cold and warm-end, and the generated heat is rejected by cooling water. In cooling performance test, waveforms of voltage, current, displacement and pressure are obtained and their amplitude and phase difference are analysed. Moreover, temperatures of cooling water, housing and linear motor are recorded and electric power parameters of driving circuit are also obtained. The developed Stirling cryocooler reaches to 47.8 K within 23.4 min. with no-load. From heat load tests, it shows cooling capacity of 440 W at 78.1 K with 6.45 kW of electric input power and 19.4 of % Carnot COP.

Preferential Oxidation of CO over Alumina Supported Pt Catalysts in Hydrogen-rich Fuels (수소연료에서 알루미나 담지 백금 촉매상에서의 일산화탄소 선택적 산화 반응)

  • Choi, Jin-Soon;Suh, Dong-Jin
    • Journal of Hydrogen and New Energy
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    • v.17 no.3
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    • pp.241-247
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    • 2006
  • The catalytic performances for CO preferential oxidation in hydrogen-rich fuels were investigated by varying the types of alumina supports, additives excluding platinum, and synthetic methods of impregnation and sol-gel synthesis. The reactions were conducted in the range of $25{\sim}300^{\circ}C$ over Pt, Co, and/or Na impregnated catalysts supported on commercial gamma-alumina, pseudoboehmite, or sol-gel derived xerogels. Catalytic activities were enhanced by cobalt addition due to strong Pt-Co interactions in the bimetallic phase. Additional sodium promoted not only the formation of the Pt-Co bimetallic interphase but also oxygen adsorption capability, giving rise to increase in the CO oxidation rate at lower temperatures. Moreover, chemical interaction between Pt and Co was considerably enhanced by sol-gel synthesis.

Derris scandens Benth Extract Potentiates Radioresistance of Hep-2 Laryngeal Cancer Cells

  • Hematulin, Arunee;Meethang, Sutiwan;Ingkaninan, Kornkanok;Sagan, Daniel
    • Asian Pacific Journal of Cancer Prevention
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    • v.13 no.4
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    • pp.1289-1295
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    • 2012
  • The use of herbal products as radiosensitizers is a promising approach to increase the efficacy of radiotherapy. However, adverse effects related to the use of herbal medicine on radiotherapy are not well characterized. The present study concerns the impact of Derris scandens Benth extract on the radiosensitivity of Hep-2 laryngeal cancer cells. Pretreatment with D. scandens extract prior to gamma irradiation significantly increased clonogenic survival and decreased the proportion of radiation-induced abnormal nuclei of Hep-2 cells. Furthermore, the extract was found to enhance radiation-induced G2/M phase arrest, induce Akt activation, and increase motility of Hep-2 cells. The study thus indicated that D. scandens extract potentiates radioresistance of Hep-2 cells, further demonstrating the importance of cellular background for the adverse effect of D. scandens extract on radiation response in a laryngeal cancer cell line.

Monitoring of Rotational Movements of Two Piston Rings in a Cylinder Using Radioisotopes

  • Jung, Sunghee;Jin, Joonha
    • Nuclear Engineering and Technology
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    • v.31 no.4
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    • pp.423-431
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    • 1999
  • A radiotracer technique has been developed to monitor the rotational movement of two piston rings in one cylinder during engine operation. The rings were labeled with two different kinds of radioisotopes, i.e. $^{60}$ Co and $^{192}$ Ir, for identification of the top ring from the second ring. The radiotracers were implanted in a small hole bored on the inner side of each piston ring. The rings were installed in a single cylinder hydrogen engine and three Nal scintillation detectors were mounted around the engine block to measure the gamma radiation. The angle of ring-gap orientation was determined from the radiation counts measured with the three detectors during engine operation. Two windows (upper window for $^{60}$ Co and lower window for $^{192}$ Ir) were set on each ratemeter to count radiation from the two isotopes separately. Procedure to convert the radiation counts to the position of the ring gap was established. With the software programmed with MS-Visualbasic, radiation counts were compared with the reference responses that were measured at angular intervals of 10$^{\circ}$for each piston ring in advance of the experiment. The result was used for the evaluation of the relationship between the orientation of ring-gaps and oil consumption. It was found that an increase in the oil consumption rate of a specific operation condition was closely related to the relative phase angle of the two piston rings.

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