• 제목/요약/키워드: ${\gamma}'$ phase

검색결과 688건 처리시간 0.026초

Phase Stability Studies of Unirradiated Al-U-10wt.%Mo Fuel at Elevated Temperature

  • Kim, Ki-Hwan;Jang, Se-Jung;Hyun suk Ahn;Park, Jong-Man;Kim, Chang-Kyu;Sohn, Dong-Seong
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1998년도 춘계학술발표회논문집(2)
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    • pp.273-278
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    • 1998
  • The phase stability of atomized U-10wt. %Mo powder and the thermal compatibility of dispersed fuel meats at 40$0^{\circ}C$ and 50$0^{\circ}C$ have been characterized. Atomized U-10Mo powder has a good \ulcorner-U phase stability, and excellent thermal compatibility with aluminum matrix in a dispersion fuel. It is thought that the good phase stability is related to th large supersaturation of Mo atoms in the atomized particles. The reasons for the excellent thermal compatibility have been considered to be as follows. Before thermal decomposition of ${\gamma}$-U in particle, supersaturated Mo atoms at ${\gamma}$-U grain boundaries inhibit the diffusion of Al atoms. After thermal decomposition of ${\gamma}$-U into ${\gamma}$-U and U$_2$Mo, the intermetallic compound of U$_2$Mo seems to retard the penetration of Al atoms. The penetration mechanisms of aluminum atoms in the atomized particles are assumed be classified as (a) diffusion through the reacted layer between fuel particles and Al matrix leaving a kernel-like unreacted island and (b) diffusion along grain boundaries showing several unreacted islands and more reacted regions.

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Diffusion barrier characteristics of molybdenum nitride films for ultra-large-scale-integrated Cu metallization (I); Surface morphologies and characteristics of sputtered molybdenum nitride films

  • Jeon, Seok-Ryong;Lee, You-Kee;Park, Jong-Wan
    • Journal of Korean Vacuum Science & Technology
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    • 제1권1호
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    • pp.24-29
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    • 1997
  • Surface morphologies and fundamental characteristics of molybdenum nitride films deposited by reactive dc magnetron sputtering were studied for application to Cu diffusion barrier. A phase transformation from Mo to $\gamma$-Mo$_2$N phase at 0.5$N_2$ flow ratio.($N_2$/(Ar+$N_2$)) equal to and larger than 0.2, whereas a second phase transformation to $\gamma$-MoN phase at 0.5 N2 flow ratio, With the variation of the N2 ratio the surface morphologies of the films were generally smooth except the cases of 0.2 and 0.3$N_2$ gas rations, where build-up of film stresses occurred. $\gamma$-Mo$_2$N film was found to crystallize at the deposition temperature of 40$0^{\circ}C$. The surfaces of $\gamma$-Mo$_2$N films deposited up to 40$0^{\circ}C$ were smooth, but the film deposited at 50$0^{\circ}C$ had very rough surface morphology. It seems that this was due to the building-up of thermal stresses at the high deposition temperature, which might lead to hillock formation.

감마선 조사 당귀(Angelica gigas Nakai)의 유효성분 안정성 및 유전독성학적 안전성 연구 (Evaluation on the Safety of ${\gamma}$-Irradiated Angelica gigas Nakai: Stability of Active Components and Safety in Genotoxicity Test)

  • 조성기;유영법
    • 한국식품영양과학회지
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    • 제29권2호
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    • pp.300-306
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    • 2000
  • In the present studies, we assessed the stability of active components and toxicological safety of irradiated Angelica gigas Nakai(Danggui). In order to confirm the stability of active components in the ${\gamma}$-irradiated roots of Danggui, the quantitative analysis of decursin and decursinol angelate of ${\gamma}$-irradiated sample was carried out by high performance liquid chromatographic (HPLC) methods using reverse phase columns and normal phase columns. From the root of Danggui, decursin and decursinol angelate were isolated by a silica gel column chromatography(toluene : ether (1 : 1), Hexane : EtOAc(15 : 1)). And then the structures were confirmed in the 1H and 13C-NMR analysis. The HPLC chromatograms of decursin and decursinol angelate in ${\gamma}$-irradiated Danggui were similar with those of non-irradiated sample. In the examination of in vitro genotoxicity of the water extract from ${\gamma}$-irradiated Danggui using Salmonella reversion assay(Ames test) and micronucleus test in Chinese hamster ovary (CHO) cells, mutagenicity was not exhibited in the two assays with or without metabolic activation. These resutls suggest that active components in the ${\gamma}$-irradiated Danggui should be stable and that the safety of ${\gamma}$-irradiated Danggui could be revealed in further test in vivo.

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Polymer Adsorption at the Oil-Water Interface

  • Lee, Woong-Ki;Pak, Hyung-Suk
    • Bulletin of the Korean Chemical Society
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    • 제8권5호
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    • pp.398-403
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    • 1987
  • A general theory of polymer adsorption at a semi-permeable oil-water interface of the biphasic solution is presented. The configurational factor of the solution in the presence of the semi-open boundary at the interface is evaluated by the quasicrystalline lattice model. The present theory gives the feature of the bulk concentration equilibria between oil-water subsystems and the surface excesses of ${\Gamma}^{\alpha}$ and ${\Gamma}^\{beta}$ of the polymer segments as a function of the degree of polymerization $\gamma$, the Flory-Huggins parameter in $\beta$-phase $x_{\rho}^{{\beta}_{\rho}}$, the differential adsorption energy parameter in $\beta$-phase $x_{\sigma}^{{\beta}_{\rho}}$, the differential interaction energy parameter ${\Delta}x_{\rho}$ and the bulk concentration of the polymer in ${\beta}-phase ${\varphi}_2^{{\beta(*)}_2}$. From our numerical results, the characteristics of ${\Gamma}^{\alpha}$ are shown to be significantly different from those of ${\Gamma}^{\beta}$ in the case of high polymers, and this would be the most apparent feature of the adsorption behavior of the polymer at a semi-permeable oil-water interface, which is sensitively dependent on ${\Delta}x_{\rho}$ and r.

DESIGN AND APPLICATION OF A SINGLE-BEAM GAMMA DENSITOMETER FOR VOID FRACTION MEASUREMENT IN A SMALL DIAMETER STAINLESS STEEL PIPE IN A CRITICAL FLOW CONDITION

  • Park, Hyun-Sik;Chung, Chang-Hwan
    • Nuclear Engineering and Technology
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    • 제39권4호
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    • pp.349-358
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    • 2007
  • A single-beam gamma densitometer is utilized to measure the average void fraction in a small diameter stainless steel pipe under critical flow conditions. A typical design of a single-beam gamma densitometer is composed of a sealed gammaray source, a collimator, a scintillation detector, and a data acquisition system that includes an amplifier and a single channel analyzer. It is operated in the count mode and can be calibrated with a test pipe and various types of phantoms made of polyethylene. A good average void fraction is obtained for a small diameter pipe with various flow regimes of the core, annular, stratified, and bubbly flows. Several factors influencing the performance of the gamma densitometer are examined, including the distance between the source and the detector, the measuring time, and the ambient temperature. The void fraction is measured during an adiabatic downward two-phase critical flow in a vertical pipe. The test pipe has an inner diameter of 10.9 mm and a thickness of 3.2 mm. The average void fraction was reasonably measured for a two-phase critical flow in the presence of nitrogen gas.

CFD 코드의 기포류 유동 예측을 위한 기포크기모델 평가 (Evaluation of Bubble Size Models for the Prediction of Bubbly Flow with CFD Code)

  • 박진영;윤병조
    • 에너지공학
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    • 제25권1호
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    • pp.69-75
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    • 2016
  • 기포크기는 다차원 이상유동에서 정확한 기포거동의 예측을 위해 중요한 인자이다. 현재 CFD 코드인 STAR CCM+에서는 유동채널에서 기포크기예측을 위해 역학적인 기포크기모델인 $S{\gamma}$ 모델을 제공하고 있다. 기포크기 예측을 위한 또 다른 모델로써 고압조건의 과냉 비등 실험인 DEBORA 실험을 바탕으로 개발된 Yun 모델이 있다. 본 연구에서는 상용 CFD 코드인 STAR CCM+ ver. 10.02를 이용하여 물-공기 이상유동에 대한 수치해석을 통해 $S{\gamma}$ 모델과 Yun 모델의 성능을 확인하고 평가하였다. 이를 위해 두 모델은 수직관에서의 물-공기 실험인 DEDALE 실험과 Hibiki 등의 실험에 대하여 평가되었다. 해석 결과 $S{\gamma}$ 모델은 이상유동 인자들을 합리적으로 예측하였으며, Yun 모델은 저압조건의 물-공기 유동에는 적합하지 않음을 확인하였다.

The Analysis of Gamma Oscillation and Phase-Synchronization for Memory Retrieval Tasks

  • 김성필;최승현;김현택;이승환
    • 한국인지과학회:학술대회논문집
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    • 한국인지과학회 2010년도 춘계학술대회
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    • pp.37-41
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    • 2010
  • The previous investigations of electroencephalogram (EEG) activity in the memory retrieval tasks demonstrated that event-related potentials (ERP) during recollection showed different durations and the peak levels from those without recollection. However, it has been unknown that recollection in memory retrieval also modulates high-frequency brain rhythms as well as establishes large-scale synchronization across different cortical areas. In this study, we examined the spectral components of the EEG signals, especially the gamma bands (20-80Hz), measured during the memory retrieval tasks. Specifically, we focused on two major spectral components: first, we evaluated the temporal patterns of the power spectral density before and after the onset of the memory retrieval task; second, we estimated phase synchrony between all possible pairs of EEG channels to evaluate large-scale synchronization. Fourteen healthy subjects performed the memory retrieval task in the virtual reality environment where they selected whether or not t he present item was seen in the previous training period. When the subjects viewed the unseen items, the middle gamma power (40-60Hz) appeared to increase 200-500ms after stimulus onset while the low gamma power (20Hz) was suppressed all the way through the post-stimulus period 150ms after onset. The degree of phase synchronization in this low gamma level, however, increased when the subjects fetched the item from memory. This suggests that phase synchrony analysis might reveal different aspects of the memory retrieval process than the gamma power, providing additional information to the inference on the brain dynamics during memory retrieval.

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고온 가스질화 된 STS 430 스테인리스강의 냉간 가공성에 미치는 항온변태 열처리 시간 변화의 영향 (Effect of Isothermal Transformation Heat-treatment Time on Cold Workability of STS 430 Stainless Steel after High Temperature Gas Nitriding)

  • 김정민;현양기;송상우;김기동;손영호;성장현
    • 열처리공학회지
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    • 제27권1호
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    • pp.15-22
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    • 2014
  • This study is to investigate the phase changes and cold workability after isothermal transformation at $780^{\circ}C$ by using the high temperature gas nitrided (HTGN) STS 430 ferritic stainless steel specimens. The phase diagram of STS 430 steel obtained by calculation showed that the phase appeared at $1100^{\circ}C$ showed as ${\alpha}+{\gamma}{\rightarrow}{\gamma}{\rightarrow}{\gamma}+Cr_2N{\rightarrow}{\gamma}+Cr_2N+CrN$ with increasing nitrogen concentration. Also, the transformation of ${\gamma}{\rightarrow}Cr_2N$ during heat treatment isothermally at $780^{\circ}C$, nitrogen pearlite with lamellar type was fully formed at the nitrogen permated surface layer for 10 hrs. However, this transformation was not completed for 1 hr, resulting nitrogen pearlite plus martensite. The cold rolled specimen of isothermally transformed at $780^{\circ}C$ for 10 hrs after high temperature gas nitriding decreased the layer thickness of nitrogen pearlite inducing the deformation of hard $Cr_2N$ phase. the dissolution rate of $Cr_2N$ phase increased rapidly with increasing cold rolling ratio. Specimens with the microstructure of nitrogen pearlite (isothermally transformed at $780^{\circ}C$ for 10 hrs) were possible to cold rolling without crack formation. However, the mixed structures of nitrogen pearlite + martensite (isothermally transformed at $780^{\circ}C$ for 1 hr) were impossible to cold deformation without cracking.

BER Analysis of Coherent Free Space Optical Systems with BPSK over Gamma-Gamma Channels

  • Lim, Wansu
    • Journal of the Optical Society of Korea
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    • 제19권3호
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    • pp.237-240
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    • 2015
  • We derived the average bit error rate (BER) of coherent free-space optical (FSO) systems with digital binary phase shift keying (BPSK) modulations over atmospheric turbulence channels with a gamma-gamma distribution. To obtain a generalized derivation in a closed-form expression, we used special integrals and transformations of the Meijer G function. Furthermore, we numerically analyzed and simulated the average BER behavior according to the average SNR for different turbulence strengths. Simulation results are demonstrated to confirm the analytical results.

IN792+Hf 초내열합금의 응고거동에 미치는 응고속도의 영향 (The Effect of Solidification Rate on Solidification Behavior in IN792+Hf Superalloy)

  • 배재식;김현철;이재현;유영수;조창용
    • 한국재료학회지
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    • 제11권6호
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    • pp.502-507
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    • 2001
  • 일방향응고법으로 IN792+Hf 초내열합금의 응고속도에 따른 응고거동의 변화에 대해 연구하였다. 조직관찰을 통해 각 상의 응고과정과 석출거동을 분석하였다 일방향응고시 응고속도가 감소하면 문자형의 탄화물은 면상 탄화물로 변화하였고 ${\gamma}$상과 탄화물의 결합은 탄화물의 수지상 성장에 의한 것임을 확인할 수 있었다. 긴 막대형상의 탄화물이 0.5$\mu\textrm{m}$/s의 응고속도에서 입계를 따라 형성되었으며 잔류액상지역에서 ${\gamma}$'형성원소가 풍부한 구역과 고갈된 구역이 발견되었다. 공정 ${\gamma}$/${\gamma}$'은 형성원소가 풍부한 구역에서 핵생성하였으며 공정 ${\gamma}$/${\gamma}$'의 형성은 잔류액상지역의 (Ti+Hf+Ta+W)/Al 비율을 높여 η상의 석출을 유발하였다. 느린 응고속도에서는 잔류액상지역으로부터의 충분한 역확산으로 (Ti+Hf+Ta+W)/Al 비율이 낮아져 η상의 석출이 억제되었다.

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