• 제목/요약/키워드: ${\gamma}'$ phase

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A Study on Stimulus reaction and Physical Properties of PBDG (PBDG의 자격반응과 물성에 관한 연구)

  • Chang, Hun;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.1047-1049
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    • 2001
  • The displacemant current measuring system used for detecting the dynamic behavior of monolayers at the air-water interface is described. It basically consists of a film balance, a pair of electrodes connected to each other through a sensitive ammeter. Here, one electrode is suspended in air and the other electrode is placed in the water. With Maxwell-displacement-current-measuring method, the phase transitions of Poly-${\gamma}$ -benzyl D-glutamate(PBDG) on a water surface were detected. Measured surface pressure, displacement current and dipole moment of monolayers of PBDG on the water surface. We measured analyzed displacement current that occur when differed temperature. Could know that displacement current is proportional in increase of temperature and great as experiment result.

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Effects of V on the Formation of Ti-Nb-V Cabonitrides and Mechanical Properties in Low Carbon HSLA Steels (저탄소.저합금강의 Ti-Nb-V 복합 탄질화물 형성 및 기계적 특성에 미치는 V 첨가의 효과)

  • Kang, J.S.;Kim, D.J.;Park, C.G.
    • Transactions of Materials Processing
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    • v.15 no.8 s.89
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    • pp.581-585
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    • 2006
  • Effects of V on both the formation of Ti-Nb-V carbonitrides and mechanical properties of Ti-Nb bearing low carbon HSLA steels were investigated. Hot rolling process was simulated by using Gleeble 3500 system with the steels containing three different levels of V ($0{\sim}0.1wt.%$). Vanadium precipitated as Ti-Nb-V carbonitrides at austenite region but it did not precipitate as VC during austenite to acicular ferrite or bainitic ferrite phase transformation. As V content increased, the amount of Nb precipitates was decreased but the average size of Ti-Nb-V carbonitrides was increased due to larger diffusivity of V than that of Nb. Coarsened Ti-Nb-V carbonitrides could act as heterogeneous nucleation site during ${\gamma}{\rightarrow}{\alpha}$ phase transformation, thus, acicular ferrite transformation was promoted as V content increased, resulting in increase of upper shelf energy.

The study on cryogenic properties of austenitic stainless steels by the addition of Nitrogen (Austenite계 Stainless강의 저온특성변화에 관한 N의 영향)

  • Kim, J.O.;Chol, Y.;Choe, J.I.
    • Journal of the Korean Society for Heat Treatment
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    • v.15 no.4
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    • pp.166-171
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    • 2002
  • The effects of Ni and N addition to 304 stainless steel on mechanical properties and microstructure were investigated within temperature ranged from $-196^{\circ}C$ to $25^{\circ}C$. The addition of nickel and nitrogen induced the stability against the formation of provide significantly enhanced ductility at $-196^{\circ}C$ and reduce the Md temperature. Fe-18Cr-10Ni-0.2N alloy showed the ${\gamma}$ phase in deformed structure which it was beneficial to enhance the tensile strength and elongation at $25^{\circ}C$ and $-196^{\circ}C$.

High Temperature Oxidation Behavior and Surface Defect in Fe-25Mn-1.5Al-0.5C Steel (Fe-25Mn-1.5Al-0.5C강의 고온 산화 거동과 표면 결함)

  • Park, Shin Hwa;Hong, Soon Taik;Kim, Tai Wung;Chung, In-Sang
    • Journal of the Korean Society for Heat Treatment
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    • v.13 no.3
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    • pp.158-162
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    • 2000
  • The high temperature oxidation behavior and the surface defect in Fe-25Mn-1.5A1-0.5C steel was investigated by XRD (X-ray Diffractin) and electron microscopy. The intra- and inter-granular oxides were formed by the selective oxidation of manganese and aluminum, which were identified to MnAl2O4 phase. Aluminum nitride (AlN) was formed in front of these oxides. The ${\gamma}$-matrix was transformed to ${\alpha}$- and ${\varepsilon}$- phases by the selective oxidation of manganese. The surface defect, micro-scab was induced by the difference of the high temperature ductility between the matrix and the inter-granular oxide.

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Phase Transformation Behavior on Aging Treatment in CuAINi Shape Memory Alloy (CuAINi 형상기억합금의 시효처리에 따른 상변태 거동)

  • Yang, G.S.;Kang, J.W.
    • Journal of the Korean Society for Heat Treatment
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    • v.6 no.4
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    • pp.213-222
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    • 1993
  • This research was performed to investigate the transformation behavior and shape memory effect of Cu-13.5Al-4.5Ni(wt%) alloy with various aging temperature and time. The results obtained in this study are as follows: Transformation temperature was very increased when aging temperature is at $250^{\circ}C$. The variation of transformation temperature in first reverse transformation cycle and second was very significant, but there was little difference in case of 2nd and 3rd. Transformation temperature at various aging temperature was increased with increasing of aging temperature and time. Microvickers hardness was increased with increasing of aging temperature and time. It was found that ${\alpha}$ and ${\gamma}_2$ phase were created by aging of long time at high temperature.

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Methods for Determining the Quality of Magnetic Fluids

  • Chioran, Viorica;Chioran, Marius
    • Journal of Magnetics
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    • v.18 no.2
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    • pp.197-201
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    • 2013
  • This paper presents the conversion parameter values of the magnetic properties of magnetic fluids. These values were determined for three magnetic fluid samples containing particles with diameters between 30 ${\AA}$ and 170 ${\AA}$. The factors that may affect the value of this parameter (size of particle, magnetic properties, the presence of clusters and aggregates) are also studied. The determined values for the conversion parameter (${\gamma}$) are between 0.25 and 0.76 and the determined limit value is 0.8. Because many applications require magnetic fluids with the saturation magnetization as high as possible and the viscosity as low as possible [1], it has been considered necessary to determine this parameter which describes the quality of magnetic fluids.

The Effects of Alloying Elements and Cooling Rates on the Formation of Phosphide Eutectics of Wear Resistance CV Graphite Cast Irons (내마모 CV흑연주철의 공정인화물 형성에 미치는 합금원소 및 냉각속도의 영향)

  • Park, Heung-Il;Kim, Myung-Ho
    • Journal of Korea Foundry Society
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    • v.9 no.4
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    • pp.311-319
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    • 1989
  • The effects of the alloying elements and cooling rates on the formation of phosphide eutectics of compacted vermicular graphite cast irons containing copper, tin, molybdenum for producing pearlitic matrix, and also containing phosphorus and boron for increasing wear resistance, were investigated. The liquidus phosphide eutectic was found to solidify as a pseudo-binary phosphide eutectic, but with increasing of the cooling rate non-equlibrium phosphide eutectic with needle type carbide could be formed. However, the liquidus phosphide eutectic containing both phosphorus and carbide-forming boron was found to solidify always as a non-equlibrium phosphide eutectic with coarse carbide, independent from the cooling rate. It was also confirmed that the tiny isolated phase observed by SEM was gamma iron solid solution with phosphorus, silicon, molybdenum and the matrix containing these tiny islands was phosphide phase containing manganese and molybdenum. The addition of copper was found to decrease the tendency of forming ledeburitic carbides in the phosphide eutectic.

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Synthesis of NiO-doped Al2O3 Powder by Spray Pyrolysis (분무열분해법에 의한 NiO 첨가 Al2O3 분체의 합성)

  • 박정현;조경식;김한태
    • Journal of the Korean Ceramic Society
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    • v.28 no.8
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    • pp.593-602
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    • 1991
  • Al2O3 and NiO-doped Al2O3 powders were prepared from the ethanol solution of Al (NO3)3$.$9H2O and Ni(NO3)2$.$6H2O by spray pylolysis method using two-fluid nozzle. As a result of spraying test with 0.3 mol/{{{{ iota }} concentration starting solution, mean droplet sizes varied with 8.99∼9.69$\mu\textrm{m}$ and those standard deviation were 4.57∼5.12. As-prepared powders which were synthesized at 1000$^{\circ}C$ have spherical shape, sizes of 0.1∼3.0$\mu\textrm{m}$ and specific surface area of 22.34∼24.20㎡/g. Most powders consisted of {{{{ gamma }}-Al2O3 phase and transforned into ${\alpha}$-A;2O3 phase by calcination at 1100$^{\circ}C$ for 1 hr. NiO-doped Al2O3 sintered bodies had better sinterability than those of pure Al2O3 and 0.3 wt% NiO-doped Al2O3 had near theoretical density and dense microstructure.

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MICROSTRUCTURE AND ELECTROCHEMICAL CHARACTERISTICS OF ELECTRODEPOSITED Zn-Ni ALLOY COATINGS

  • Short, N.R.;Hui, Wen-Hua;Dennis, J.K.
    • Journal of Surface Science and Engineering
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    • v.32 no.3
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    • pp.281-288
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    • 1999
  • Electrodeposited Zn-Ni alloy coatings are of particular interest for improving the corrosion resistance of steel in a number of enviornments. Of particular interest is the relationship between composition, structure and corrosion rate. This paper firstly reviews the literature regarding composition-structure relationships of Zn-Ni electrodeposits and compares them with the equilibrium phase diagram. Secondly, research was carried out on a wide range of coatings which were produced in the laboratory and their structure and corrosion rates determined. It was found that unambiguous identification of phases from XRD data can be difficult. Maximum corrosion resistance of deposits is obtained at 12-13% Ni, with a $\gamma$ phase structure and predomination of (600) and (411) reflections. Compatibility is important with regard to chromate conversion coatings.

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