• Title/Summary/Keyword: ${\gamma}$-phase

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A study on the manufacture and dielectric of the polyvinylidene fluoride thin films through vapor deposition method (진공증착법을 이용한 PVDF박막의 제작과 유전 특성에 관한 연구)

  • Park, S.H.;Im, U.C.;Cho, K.S.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1995.11a
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    • pp.420-422
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    • 1995
  • PVDF (polyvinylidene fluoride) has at least from known crystalline structure ( ; they are referred to as the $\alpha$, $\beta$, $\gamma$ and $\alpha_p$ phase or forms II, I, III and $IV_p$). In this study, the manufactured PVDF thin films through vapor deposition method had for II ( ; the substrate temperature at 30$^{\circ}C$). The dielectric behavior of poly(vinylidene fluoride) is affected by orientation and crystal modification. The very high value of the dielectric constant for high temperature conditioned film is believed to be due to the orientation effect. The loss peak caused by molecular motion of the molecules in crystalline regions.

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Dielectric Properties of Epoxy-Nano Composites for Surface Modified Nano Alumina (표면개질된 나노 알루미나의 에폭시-나노 콤포지트 유전 특성)

  • Park, Jae-Jun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.10
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    • pp.613-619
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    • 2016
  • The aim of this study is to improve of dielectric properties using epoxy/nano alumina composites with adding glycerol diglycidyl ether (GDE:1,2 g). This paper deals with the effects of dielectric properties(${\epsilon}^{\prime}_r$ and $tan{\delta}$) for epoxy/nano alumina contents (1,3 phr) and GDE addition (1,2 g)composites. 5 kinds specimen were prepared with containing epoxy resins, epoxy nano alumina composites. Average particle size of nano used were 30 nm. The nano alumina used were gamma phase particles of spherical shape. The suppression of epoxy chain motion by addition of nano alumina+GDE decreased dielectric loss and relative permittivity magnitude.

The Effect of the Gas Ration on the Characteristics of Plasma Nitrided SCM440 Steel (SCM440강의 플라즈마 질화특성에 미치는 가스비율의 영향)

  • 김무길
    • Journal of Advanced Marine Engineering and Technology
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    • v.22 no.5
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    • pp.712-720
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    • 1998
  • The effect of H2:N2 gas ratio on the case thickness hardness and nitrides formation in the sur-face of SCM440 machine structural steel have been studied by micro-pulse plasma process. The thickness of compound layer increased with the increase of nitrogen content in the gas com-position. The maximum thickness of compound layer the maximum case depth and the maximum surface hardness were about 15.8${\mu}m$, 400${\mu}m$ and Hv765 respectively in the nitriding condition of 250Pa and 70% nitrogen content at $520^{\circ}C$ for 7hrs. Generally only nitride phases such as ${\'{\gamma}}$($Fe_4N$)$\varepsilon(Fe_2}{_3N}$ phases were detected in compound and diffusion layer by XRD analysis. The amount of $\varepsilon(Fe_2}{_3N}$ phase increased with the increase of nitrogen content. The relative amounts and kind of phases formed in the nitrided case changed with the change of nitrogen content in the gas composition.

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Amylase Production by Continuous Cultures of Aspergillus oryzae and its Mutants (Aspergllus oryza와 그 변이주의 연적배양에 의한 amylase 생성에 관한 연구)

  • Han, Hong-Eui
    • Korean Journal of Microbiology
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    • v.15 no.2
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    • pp.63-76
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    • 1977
  • Irradiation with high doses of gamma rays induced the reduction of mycelial weight and anaylase activity, and increased relative amylase activity in surface cultures. Biphase in growth curves was shown in aeration-agitation cultures but the behavior of the first phase of growth could be eliminated by replacing the amylasehydrolysed starch substrates, so that enzyme production was shortened ca. 40 hours and relative amylase activity was increased about 3 times higher before onset of autolysis. In the effect of gibberellin on amylase production, the positive stimulation was appeared to only surface culturs of the liquid medium and the negative effect to shake-cultures in a mutant. Trials of various continuous culture were resulted not only the approalch to the value of amylase activity in surface cultures of liquid medium, but also higher productivity than in batch cultures. The culture-degeneration was observed in two-stage continuous culture, but did not appear in continuous elevation culture.

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A Study on the Stimulus Reaction of PBLG (Poly-${\gamma}$-Benzyl $_L$-Glutamate의 자격반응에 관한 연구)

  • Kim, Beyung-Geun;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2002.07c
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    • pp.1413-1415
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    • 2002
  • The Displacement current measurement system used in this experiment because detecting the dynamic behavior of monolayers at the air-water interface is possible. It basically consists of a film balance, a pair of electrodes connected to each other through a sensitive ammeter. Here, one electrode is suspended in air and the other electrode is placed in the water. PBLG phase transformation measured by Maxwell-displacement-current-measurement method in surface of the water. Measured (surfacc pressure, displacement current and dipole moment) of monolayers of PBLG on the water surface. We measured displacement current that occur when changed temperature(15, 20, 25$^{\circ}$ ) and the compression speed(30, 40, 50(mm/min)). From the result, it is known that curren generated in the range of high surface pressur compression velocity and temperature become faste.

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Fraction Analysis of ε and γ'-iron Nitride in Compound Layer Using X-ray Diffraction (X-선 회절법에 의한 철-질소 화합물층의 ε과 γ'상 분율 해석)

  • Kim, Yoon-Kee
    • Korean Journal of Materials Research
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    • v.16 no.2
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    • pp.85-91
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    • 2006
  • The fraction of $\varepsilon\;and\;\gamma$'-iron nitride in compound layer is predicted by x-ray diffraction using direct comparison method. The validity of formulation models was checked by comparing calculated results with metallographic analysis of iron nitride compound layer grown on steel S45C by gas nitriding. The fraction of $\varepsilon$ calculated by the three phase model, porous-$Fe_3N$/ dense-$Fe_3N$/ mixed layer with $Fe_3N\;and\;Fe_4N$, is 80 percent of that analyzed by etching technique. The $\varepsilon$ fraction predicted by mixed layer model is 122 percent of that measured by microscope.

A Study on Spectrophotometric Determination of Oleic Acid by Basic Dye Methylen Bblue (염기성색소(鹽基性色素) Methylen Blue에 의(依)한 Oleic Acid의 흡광광도정량(吸光光度定量))

  • Lee, Sook-Yun
    • Journal of Pharmaceutical Investigation
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    • v.4 no.1_2
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    • pp.46-54
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    • 1974
  • A new spectrophotemetric method was estalished for the determination of oleic acid. This method is based on the 1,2-dichloroe-thane extraction of the ion-pair formed between methylene blue and oleic acid. But the absorbance of an ion-pair in the 1,2-dichloroe-thane layer was variable with the temperature, the ion-pair was extracted back into a diluted hydrochloric acid solution. The maximum absorbance of the acid extract observed at $660m{\mu}$ and a lineal relationship was observed from the initial amount over the range of $50-800{\gamma}/ml$ of oleic acid in the aqueous phase. The composition ratio of the ion-pair formed between methylene blue and oleic acid was determined to be 2 : 1 by both the mole ratio and continuous variation methods.

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Sensing Properties of Au Nanoparticle-Functionalized ZnO Nanowires by γ-Ray Radiolysis

  • Katoch, Akash;Choi, Sun-Woo;Byun, Joon-Hyuk;Kim, Sang-Sub
    • Journal of Sensor Science and Technology
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    • v.21 no.3
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    • pp.180-185
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    • 2012
  • ${\gamma}$-ray radiolysis was used to functionalize networked ZnO nanowires with Au nanoparticles. The networked ZnO nanowires were prepared through a vapor phase selective growth method. The sensing performances of the Au-functionalized ZnO nanowires were investigated in terms of $NO_2$, CO and benzene gases. The Au-funtionalized ZnO nanowire sensors showed an applicable, reliable capability to detect the gases, indicating their potential in chemical gas sensors.

The Magnetic Properties of Rapidly Quenched Yttrium-Palladium-Borocarbides Ribbon

  • Kim, K.S;Yu, S.C;Moon, Y.M;Baek, J, S;Lim, W.Y
    • Journal of Magnetics
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    • v.1 no.1
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    • pp.42-45
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    • 1996
  • We have studied the superconductivity of rapidly quenched $YPd_2B_2C$ ribbons. The superconductivity in bulk $YPd_2B_2C$ is completely suppressed by annealing as-cast ingots at hihger temperature, suggesting that the superconducting phase is metastable. The rapidly quenched sample, in the as-quenched state, shows the superconducting transition temperature of about 21 K. Form our magnetic data, the value for the upper critical field $H_c2$ (0) is estimated to be 10 T. The critical current density and the expected specific heat discontinuity $({\Delta}C/{\gamma}{T_c})$ were obtained to be about$10^8A/m^2$ at 10 Oe and 1.55, respectively.

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AISI D2 Steel의 이온질화시 Multilayer의 생성에 의한 표면강화

  • Jo, Gyun-Taek;Son, Seok-Won;Lee, Yeong-Guk;Lee, Won-Beom
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.302-302
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    • 2013
  • 본 연구는 이온질화시 self-sputtering에 의한 AISI D2 소재의 표면경화에 대한 연구를 진행하였다. 이를 위해 이온질화시 질소가스와 아르곤 가스를 이용해 이온질화를 수행하였다. 이에 대한 결과는 optical micrograph (OM), scanning electron microscopy (SEM), X-ray diffraction(XRD), transmission electron microscopy (TEM)를 이용해 분석하였다. 실험결과, 소재의 경도는 570 HV에서 약 1470 HV까지 상승하였다. 극표면에 CrN-enriched layer의 형성 및 극표면 아래층에서 질소의 과포된 화합물층을 관찰할 수 있었다. 표면경화는, 극표면에 CrN-enriched layer의 형성과, 아래 N의 과포화에 의한 ${\gamma}$?autenite) phase, 그리고 diffusion layer의 형성에 의한 multi-layer의 형성으로 표면에 강화에 기여한것으로 사료된다.

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