• Title/Summary/Keyword: ${\beta}$-phase

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Nanotube Morphology Change of Ti-6Al-4V Alloys by Heat Treatment

  • Kim, Sung-Hwan;Choe, Han-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2013.05a
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    • pp.194-194
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    • 2013
  • In order to investigate nanotube morphology change of Ti-6Al-4V alloys by heat treatments, the Ti-6Al-4V alloys were used in this study. In non-treated Ti-6Al-4V alloy case, nanotubes only exhibited at ${\alpha}$ phase region with dissolved V-oxide area of ${\beta}$ phase. However, in Ti-6Al-4V alloy at $800^{\circ}C$ WQ case, nanotubes exhibited at both ${\alpha}$ and ${\beta}$ phase region. Electrochemical corrosion studies showed that the nanotubular alloy at $800^{\circ}C$WQ possesses slightly higher corrosion resistance than non-treated nanotubular alloy.

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Solid-phase Synthesis and Preliminary Evaluation of 1,6,8-Trisubstituted Tetrahydro-2H-pyrazino[1,2-a]pyrimidine-4,7-diones as a NF-kB Inhibitor

  • Kim, Jin-Woong;Cho, Jung-Hyuck;Han, Tae-hee;Lee, Jong-Baek;Oh, Chang-Hyun
    • Bulletin of the Korean Chemical Society
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    • v.27 no.4
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    • pp.484-488
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    • 2006
  • The solid-phase synthesis of new series of 1,6,8-trisubstituted tetrahydro-2H-pyrazino[1,2-a]pyrimidine-4,7-diones as bicyclic $\beta$-turn mimetics is described. Their NF-kB inhibition activities were tested and the effect of substituents on bicyclic ring was investigated. Among the prepared compounds, the fluorobenzyl and methoxybenzyl group substituted compounds 26 and 27 at C-1 and C-8 position showed more inhibitory activities than the others. Tested at a concentration of 10 uM, these two compounds showed a 60% inhibition against the target NF kB 549.

The Study of Sintering Characteristics in LAS(Li2O.Al2O3.SiO2) System (LAS($Li_2O.Al_2O_3.SiO_2$)계 소지의 소결특성에 관한 연구)

  • Lee, Eung-Sang;Park, Hyun;Kim, Dong-Hwan
    • Journal of the Korean Ceramic Society
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    • v.29 no.2
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    • pp.127-135
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    • 1992
  • It has been reported that natural petalite showed a low negative thermal coefficient and wide coefficient and wide coexisting region with liquid phase in Li2O-Al2O3-SiO2 system. Therefore, we investigated variation of microstructure and thermal and mechanical properties when the amount of SiO2 content in petalite compound and MgO addition to it compound were changed. As SiO2 content exceeded 80 wt%, crystal phases of $\beta$-cristobalite and $\beta$-spondumene solid solution were formed. Generally, the densification and bending strength were increased by the addition of MgO, but the positive thermal coefficient was found in the case of MgO 10 wt% addition because of second phase and glassy phase.

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The Microstructure and the Prerred Orientation of Pb-Sn-Alloy Electrodeposits in Pulse Plating (파형점류전해에 의한 Pb-Sn 합금의 현미경조직 및 우선배향)

  • 예길촌;김용응
    • Journal of the Korean institute of surface engineering
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    • v.22 no.4
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    • pp.207-214
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    • 1989
  • The surface morphology and the proferred orientation of the Pb-Sn alloy electrodeposite were investated by the change of electrolysis conditions in pulse current electroplating. The preferred orientation of Pb-phase in alloy deposits was changed in the sequence of (110)longrightarrow(100)or(100)+(111)longrightarrow(111) with increasing peak current density, while that of $\beta$-Sn phase changed from (321)+(301)to(301)+(111) mixed orientation. The surface morphology was closely related to the preferred orientation of alloy electrodeposits. The alloy deposits, which had (100)or(111) for pb-phase and (321)or(100)(301)for $\beta$-Sn sespectively, showed the surface structure of granular crystallites. The alloy deposits whih mixed orientations for both phases had microstructure of closely the closely stacked crysrallites, which was inclined to the surface.

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Microstructural evolution and mechanical properties of $Al_{71.6}Ge_{28.4}$ eutectic alloy ($Al_{71.6}Ge_{28.4}$ 공정합금의 미세구조 및 기계적 성질의 평가)

  • Park, Jin-Man;Yook, Wan;Kim, Do-Hyang
    • Journal of Korea Foundry Society
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    • v.27 no.4
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    • pp.167-172
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    • 2007
  • In the present study, the microstructural evolution and mechanical properties of $Al_{71.6}Ge_{28.4}$ eutectic alloy have been investigated. Stable (fcc ${\alpha}$-Al and diamond cubic ${\beta}$-Ge) and various metastable crystalline (monoclinic, rhombohedral) phases were produced by competitive phase selection during non-equilibrium processing methods i.e. melt spinning and injection casting. The as-injection casted samples containing metastable-equilibrium eutectic (${\alpha}$-Al + monoclinic) structure showed much higher strength than samples with equilibrium eutectic (${\alpha}-Al+{\beta}-Ge$) structure but plasticity disappointingly diminished. In order to endow the enhanced ductility without significant strength drop, the alloys was heat-treated at transition temperature from metastable phase to stable phase. The annealed specimen displayed the phase transformed microstructural evolution and enhanced macroscopic plasticity.

Mechanical, Electrical Properties and Manufacture of the $\beta$-SiC-$ZrB_2$ Electroconductive Ceramic Composites by Pressureless Sintering (무가압소결한 $\beta$-SiC-$ZrB_2$계 도전성 복합체의 제조 및 기계적, 전기적 특성)

  • Shin, Yong-Deok;Kwon, Ju-Sung
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.2
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    • pp.98-103
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    • 1999
  • The effect of $Al_2O_3$ additives to $\beta-SiC+39vol.%ZrB_2$ electroconductive ceramic composites by pressureless sintering on microstructural, mechanical and electrical properties were investigated. The $\beta-SiC+39vol.%ZrB_2$ ceramic composites were pressureless sintered by adding 4, 8, 12wt.% $Al_2O_3$ powder as a liquid forming additives at $1950^{\cire}C$ for 1h. Phase analysis of composites by XRD revealed mostly of $\alpha-SiC(6H), ZrB_2$ and weakly $\alpha-SiC(4H), \beta-SiC (15R)$ phase. The relative density of composites was lowered by gaseous products of the result of reaction between \beta-SiC and Al_2O_3$, therefore, porosity was increased with increasing $Al_2O_3$ contents, and showed the maximum value of 1.4197MPa.$m^{1/2}$ for composite with 4wt.% $Al_2O_3$ additives. The electrical resistivity of $\beta-SiC+39vol.%ZrB_2$ electroconductive ceramic composite was increased with increasing $Al_2O_3$ contents, and showed positive temperature coefficient resistance (PTCR) in the temperature range of $25^{\cire}C$ to $700^{\cire}C$.

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Effect of Porosity on the Fracture Toughness and Electrical Conductivity of Pressureless Sintered ${\beta}-SiC-ZrB_2$ Composites (무가압소결(無加壓燒結)한 ${\beta}-SiC-ZrB_2$ 복합체(複合體)의 파괴인성(破壞忍性)과 전기전도성(電氣傳導性)에 미치는 기공(氣孔)의 영향)

  • Shin, Yong-Deok;Kwon, Ju-Sung
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.847-849
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    • 1998
  • The effect of $Al_{2}O_{3}$ additives on the microstructure, mechanical and electrical properties of ${\beta}$-SiC+39vol.%$ZrB_2$ electroconductive ceramic composites by pressureless sintering were investigated. The ${\beta}$-SiC+39vol.%$ZrB_2$ ceramic composites were pressureless sintered by adding 4, 8, 12wt.% $Al_{2}O_{3}$ powder as a liquid forming additives at $1950^{\circ}C$ for 1h. Phase analysis of composites by XRD revealed mostly of $\alpha$-SiC(6H), $ZrB_2$ and weakly $\alpha$-SiC(4H), $\beta$-SiC(15R) phase. The relative density of composites was lowered by gaseous products of the result of reaction between $\beta$-SiC and $Al_{2}O_{3}$ therefore, porosity was increased with increased $Al_{2}O_{3}$ contents. The fracture toughness of composites was decreased with increased $Al_{2}O_{3}$ contents, and showed the maximum value of $1.4197MPa{\cdot}m^{1/2}$ for composite added with 4wt.% $Al_{2}O_{3}$ additives. The electrical resistivity of ${\beta}$-SiC+39vol.%$ZrB_2$ electroconductive ceramic composite was increased with increased $Al_{2}O_{3}$ contents, and showed positive temperature coefficient resistance (PTCR) in the temperature from $25^{\circ}C$ to $700^{\circ}C$.

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Basic Study on P(VDF-TrFE) Smart Sensor for Monitoring Composite Structure Behaviors (복합재료구조물 거동 관찰을 위한 P(VDF-TrFE) 스마트센서의 기초연구)

  • Bae, Ji-Hun;Chang, Seung-Hwan
    • Composites Research
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    • v.28 no.3
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    • pp.75-80
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    • 2015
  • Poly(vinylidene fluoride-trifluoroethylene; P(VDF-TrFE)) is one of the most promising electroactive polymers with numerous application potentials in many fields of industry. Because of its good electro-mechanical properties P(VDF-TrFE) has been used for a number of sensors and actuators and also can be used for monitoring composite structure behaviors as a sensor. Three different ways (Electrical poling, annealing-cooling, and pressing) to enhance ${\beta}$-phase of P(VDF-TrFE) film were carried out. A microscopic analysis was conducted using X-ray diffraction to investigate the effect of such treatments on piezoelectric properties of P(VDF-TrFE) film. From the results, poling, annealing-cooling, and pressing were all effective to enhance ${\beta}$ crystallinity of P(VDF-TrFE) film and the maximum increase rate was 62.80% from 45.29% of the control group.

Characterization of a New Antidementia $\beta$-Secretase Inhibitory Peptide from Rubus coreanus

  • Lee, Dae-Hyoung;Lee, Dae-Hyung;Lee, Jong-Soo
    • Food Science and Biotechnology
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    • v.17 no.3
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    • pp.489-494
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    • 2008
  • In order to develop a potent antidementia $\beta$-secretase inhibitor from phytochemicals, $\beta$-secretase inhibitory activities of extracts from many medicinal plants and herbs were determined. Water extracts from Rubus coreanus showed the highest $\beta$-secretase inhibitory activity of 84.5%. After purification of the $\beta$-secretase inhibitor from R. coreanus using systematic solvent extraction, ultrafiltration, Sephadex G-10 column chromatography, and reverse-phase high performance liquid chromatography (HPLC), a purified $\beta$-secretase inhibitor with $IC_{50}$ inhibitory activity of $6.3{\times}10^3\;ng/mL$ ($1.56{\times}10^{-6}\;M)$ was obtained with a 0.08% solid yield. The molecular mass of the purified $\beta$-secretase inhibitor was estimated to be 576 Da by liquid chromatography-mass spectrometry (LC-MS) and $\beta$-secretase inhibitor also is a new tetrapeptide with the sequence Gly-Trp-Trp-Glu. The purified $\beta$-secretase inhibitory peptide inhibited $\beta$-secretase non-competitively and also show less inhibition on trypsin, however no inhibition on other proteases such as $\alpha$-secretase, chymotrypsin, and elastase.

VARIATIONS OF THE SOLAR FLARE ENERGY SPECTRUM OVER TWO ACTIVITY CYCLES (1972 - 1995)

  • KASINSKY V. V.;SOTNIKOVA R. T.
    • Journal of The Korean Astronomical Society
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    • v.29 no.spc1
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    • pp.315-316
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    • 1996
  • Based on X-ray (1-8 ${\AA}$) flux data for 1972-1995 the integral spectra of solar flare energy were computed. It has been shown that the spectral index $\beta$ of the integral energy spectrum (IES) vanes systematically with the 11-year cycle phase. The interval of $\beta$-variations (0.47 <$\beta$<1) is characteristic of UV-Cet stars. The maximum energy of the X-ray flares does not exceed $10^{32}$ erg.

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