• Title/Summary/Keyword: ${\alpha}-F_2O_3$

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Effects of Composition on Soft Magnetic Properties and Microstructures of Fe-Hf-O Thin Films (Fe - Hf - O계 박막에서 조성이 미세구조 및 연자기 특성에 미치는 효과)

  • 박진영;김종열;김광윤;한석희;김희중
    • Journal of the Korean Magnetics Society
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    • v.7 no.5
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    • pp.237-242
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    • 1997
  • The microstructure and soft magnetic properties of as-deposited Fe-Hf-O thin film alloys, which are produced at $P_{O2}=10%$ by rf magnetron sputtering method in $Ar+O_2$ mixed gas atmosphere, is investigated. Newly developed $Fe_{82}Hf_{3.4}O_{14.6}$ film exhibits good soft magnetic properties with $4{\pi}M_s=17.7$ kG, $H_c=0.7$ Oe and ${\mu}_{eff}$(0.5~100MHz)=2,500, respectively. The Fe-Hf-O films are composed of $\alpha$-Fe nanograins and amorphous phase with larger amounts of Hf and O elements which chemically combine each other. With increasing Hf area fraction, Hf and O contents increased proportionally. It was considered that O content in films was determined by Hf contents, because O was chemically combined with Hf. It results from decreasing the $\alpha$-Fe grain size by precipitates (Hf and O), high electrical resistivity. The $Fe_{82}Hf_{3.4}O_{14.6}$ film exhibits the quality factor (Q=$\mu$'/$\mu$") of 25 at 20 MHz. These good frequency characteristics are considered to be superior to other films already reported.o other films already reported.

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Preparation and Luminescent Property of Eu3+-doped A3Al1-zInzO4F (A = Ca, Sr, Ba, z = 0, 0.1) Phosphors (Eu3+-doped A3Al1-zInzO4F (A = Ca, Sr, Ba, z = 0, 0.1)의 합성과 형광특성)

  • Kim, Yeo-Jin;Park, Sang-Moon
    • Korean Journal of Materials Research
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    • v.21 no.12
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    • pp.644-649
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    • 2011
  • [ $A_{3-2x/3}Al_{1-z}In_{z}O_4F:Eu_x^{3+}$ ](A = Ca, Sr, Ba, x = -0.15, z = 0, 0.1) oxyfluoride phosphors were simply prepared by the solid-state method at $1050^{\circ}C$ in air. The phosphors had the bright red photoluminescence (PL) spectra of an $A_{3-2x/3}Al_{1-z}In_{z}O_4F$ for $Eu^{3+}$ activator. X-ray diffraction (XRD) patterns of the obtained red phosphors were exhibited for indexing peak positions and calculating unit-cell parameters. Dynamic excitation and emission spectra of $Eu^{3+}$ activated red oxyfluoride phosphors were clearly monitored. Red and blue shifts gradually occurred in the emission spectra of $Eu^{3+}$ activated $A_3AlO_4F$ oxyfluoride phosphors when $Sr^{2+}$ by $Ca^{2+}$ and $Ba^{2+}$ ions were substituted, respectively. The concentration quenching as a function of $Eu^{3+}$ contents in $A_{3-2x/3}AlO_4F:Eu^{3+}$ (A = Ca, Sr, Ba) was measured. The interesting behaviors of defect-induced $A_{3-2x/3}Al_{1-z}In_{z}O_{4-{\alpha}}F_{1-{\delta}}$ phosphors with $Eu^{3+}$ activator are discussed based on PL spectra and CIE coordinates. Substituting $In^{3+}$ into the $Al^{3+}$ position in the $A_{3-2x/3}AlO_4F:Eu^{3+}$ oxyfluorides resulted in the relative intensity of the red emitted phosphors noticeably increasing by seven times.

The Effect of Acupuncture Treatment at the GB37 on the Electroencephalogram(EEG) (광명(GB37) 자침이 뇌파변화에 미치는 영향)

  • Yu, Ik-Han;Lee, Sang-Lyoung
    • Korean Journal of Acupuncture
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    • v.28 no.3
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    • pp.85-98
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    • 2011
  • Objectives : The aim of this thesis is to examine the effect of acupuncture treatment at the GB37 on normal humans by using the power spectral analysis of the EEG. Methods : EEG (Electroencephalogram) power spectrum exhibits site-specific and state-related differences in specific frequency bands. In this thesis, the power spectrum was measured by the complexity. the 32 channels EEG study was carried out in the 13 subjects (12 males ; age=22.58 years old, 1 females ; 22 years old). Results : In the ${\alpha}$ (alpha) band, the power values at F7, F3, F4, F8, FTC2, C4, T4, CP1, CP2, TCP2, TT2, Pz, P4, Po1, Po2, O1, Oz, O2 channels (p<0.05) during the GB37-acupoint treatment were significantly changed. And in many channels were decreased. In the ${\beta}$ (beta) band, the power values at Cz, C4, T4, Tcp1, T6, Po1, O1, Oz, O2 channels (p<0.05) during the GB37-acupoint treatment were significantly changed. And in many channels were decreased. In the ${\delta}$(delta) band, the power values at Fp1, TT2 channels (p<0.05) during the GB37-acupoint treatment were significantly changed. And in many channels were decreased. In the $\theta$ (theta) band, the power values at Fp1, F8, FTC2, Pz channels (p<0.05) during the GB37-acupoint treatment were significantly changed. And in many channels were decreased. Conclusions : This results suggest that the acupuncture treatment at the GB37 significantly mostly change the power spectrum value on the alpha (18 channels), beta (9 channels) bands.

An Acoustic Analysis and Perceptual Study of Korean Vowels Produced by Transgenders and Noraml Adults (성전환자와 정상인이 발성한 모음의 음향분석과 지각실험)

  • Jo, Sung-Mi;Jeong, Ok-Ran
    • Speech Sciences
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    • v.10 no.3
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    • pp.145-155
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    • 2003
  • This study compared $F_{0}$ and the first three formants of eight Korean monophthongs produced by nine transgenders (male to female) to those of eighteen normal adults. Voice analysis was done by Praat (version 4.049). A one-way ANOVA with Tukey HSD post hoc tests were performed to determine statistical differences in $F_{0}$ and formant values obtained from transgenders, and normal male and female subjects. Results indicated that there was no significant difference in $F_{1}$ of /u/, /$\Lambda$/, and /o/, $F_{2}$ of /u/, /$\Lambda$/, and /i/ and $F_{3}$ of /u/ among the 3 groups (transgenders, normal males and normal females). However, in the comparison of transgenders vs. males, a significant difference was observed in $F_{0}$ of /o/, and $F_{2}$ of /i/, /a/, /e/, and /${\ae}$/ and $F_{3}$ of /e/. Furthermore, in the comparison of transgenders vs. females, a significant difference was also observed in $F_{0}$ of all vowels, $F_{1}$ of /i/, /$\alpha$/, /e/, /${\ae}$/, and /i/. $F_{2}$ of /i/, and /${\ae}$/, and $F_{3}$ of /i/, /$\alpha$/, /$\Lambda$/, /e/, /${\ae}$/, /i/, and /o/. Also, perceptual judgment of the transgenders' voice came out somewhat correlated strongly with their $F_{0}$ values but not much with the formant values. It was concluded that the transgenders' acoustic parameters are placed in between those of the normal males and females in. terms of fundamental and formant frequency analyses of vowels. Thus, it was assumed that those differences might stem from the transgenders' original big resonating cavities.

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Small Molecular Organic Nonvolatile Memory Cells Fabricated with in Situ O2 Plasma Oxidation

  • Seo, Sung-Ho;Nam, Woo-Sik;Park, Jea-Gun
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.8 no.1
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    • pp.40-45
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    • 2008
  • We developed small molecular organic nonvolatile $4F^2$ memory cells using metal layer evaporation followed by $O_2$ plasma oxidation. Our memory cells sandwich an upper ${\alpha}$-NPD layer, Al nanocrystals surrounded by $Al_2O_3$, and a bottom ${\alpha}$-NPD layer between top and bottom electrodes. Their nonvolatile memory characteristics are excellent: the $V_{th},\;V_p$ (program), $V_e$ (erase), memory margin ($I_{on}/I_{off}$), data retention time, and erase and program endurance were 2.6 V, 5.3 V, 8.5 V, ${\approx}1.5{\times}10^2,\;1{\times}10^5s$, and $1{\times}10^3$ cycles, respectively. They also demonstrated symmetrical current versus voltage characteristics and a reversible erase and program process, indicating potential for terabit-level nonvolatile memory.

A New Steroidal Glycoside from Allium macrostemon Bunge

  • Kim, Yun Sik;Cha, Joon Min;Kim, Dong Hyun;Lee, Tae Hyun;Lee, Kang Ro
    • Natural Product Sciences
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    • v.24 no.1
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    • pp.54-58
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    • 2018
  • A phytochemical investigation of Allium macrostemon Bunge (Liliaceae) afforded the new pregnane steroidal glycoside, named allimacroside F (1), along with three known glycosides, benzyl-O-${\alpha}-{\text\tiny{L}}$-rhamnopyranosyl-($1{\rightarrow}6$)-${\beta}-{\text\tiny{D}}$-glucopyranoside (2), phenylethyl-O-${\alpha}-{\text\tiny{L}}$-rhamnopyranosyl-($1{\rightarrow}6$)-${\beta}-{\text\tiny{D}}$-glucopyranoside (3), (Z)-3-hexenyl-O-${\alpha}-{\text\tiny{L}}$-rhamnopyranosyl-($1{\rightarrow}6$)-${\beta}-{\text\tiny{D}}$-glucopyranoside (4). The identification and structural elucidation of a new compound (1) was carried out based on spectral data analyses ($^1H-NMR$, $^{13}C-NMR$, $^1H-^1H$ COSY, HSQC, HMBC, and NOESY) and HR-FAB-MS.

Characterization of Sandwiched MIM Capacitors Under DC and AC Stresses: Al2O3-HfO2-Al2O3 Versus SiO2-HfO2-SiO2 (Al2O3-HfO2-Al2O3와 SiO2-HfO2-SiO2 샌드위치 구조 MIM 캐패시터의 DC, AC Stress에 따른 특성 분석)

  • Kwak, Ho-Young;Kwon, Hyuk-Min;Kwon, Sung-Kyu;Jang, Jae-Hyung;Lee, Hwan-Hee;Lee, Song-Jae;Go, Sung-Yong;Lee, Weon-Mook;Lee, Hi-Deok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.12
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    • pp.939-943
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    • 2011
  • In this paper, reliability of the two sandwiched MIM capacitors of $Al_2O_3-HfO_2-Al_2O_3$ (AHA) and $SiO_2-HfO_2-SiO_2$ (SHS) with hafnium-based dielectrics was analyzed using two kinds of voltage stress; DC and AC voltage stresses. Two MIM capacitors have high capacitance density (8.1 fF/${\mu}m^2$ and 5.2 fF/${\mu}m^2$) over the entire frequency range and low leakage current density of ~1 nA/$cm^2$ at room temperature and 1 V. The charge trapping in the dielectric shows that the relative variation of capacitance (${\Delta}C/C_0$) increases and the variation of voltage linearity (${\alpha}$/${\alpha}_0$) gradually decreases with stress-time under two types of voltage stress. It is also shown that DC voltage stress induced greater variation of capacitance density and voltage linearity than AC voltage stress.

Crystallographic and Magnetic Properties of $NdFe_{10.7}Ti_{1.3}$ ($NdFe_{10.7}Ti_{1.3}$의 결정학적 및 자기적 성질 연구)

  • 이승화;이용종;안성용;김철성;김윤배;김창석
    • Journal of the Korean Magnetics Society
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    • v.6 no.6
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    • pp.361-366
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    • 1996
  • $NdFe_{10.7}Ti_{1.3}$ has been studied with X-ray diffraction, Mossbauer spectroscopy and vibrating sample magnet-ometer(VSM). The alloys were prepared by arc-melting under an argon atmosphere. The $NdFe_{10.7}Ti_{1.3}$ contains some $\alpha-Fe$, from X-ray and Mossbauer measurements. The $NdFe_{10.7}Ti_{1.3}$ has the $ThMn_{12}$-type tetragonal struc-ture with $a_{0}=8.607{\AA}\;and\;c_{0}=4.790{\AA}$. The Curie temperature ($T_c$) of the $NdFe_{10.7}Ti_{1.3}$ is 590 K from $M\"{o}ssbauer$ spectroscopy performed at various temperatures ranging from 13 to 800 K. Each spectrum below $T_c$ was fitted with six subspectra of Fe sites in the structure$(8i_{1},\;8i_{2},\;8j_{2},\;8j_{1},\;8f\;and\;{\alpha}-Fe)$. The area fractions of the subspectra at room temperature are 13.8%, 15.4%, 17%, 16.4%, 34.1% and 3.3%, respectively. Magenetic hyperfine fields for the Fe sites decrease in the order, $H_{hf}(8i)>H_{hf}(8j)>H_{hf}(8f)$. The abrupt changes in the magnetic hyperfine field, isomer shift and magnetic moment observed at about 180 K in $NdFe_{10.7}Ti_{1.3}$ are attributed to spin reorientation.

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Degradation Mechanism of the ZnO-Varistor Fabricated with the content of a 3-Composition Seed grain (3-성분 종입자법으로 제조된 ZnO-Varistor의 열화기구)

  • 장경욱;박춘배;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1992.05a
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    • pp.97-100
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    • 1992
  • The Degradation mechanism of the ZnO-varistor fabricated with the content of a 3-Composition seed grain is discussed using the method of Thermally Stimulated Current (TSC). The spectra of TSC is measured in the temperature range of -130~270$^{\circ}C$ with a various forming electric fields E$\sub$f/, temperature T$\sub$f/ time tf, and a various rising rate of temperature. It is observed that there are appeared the peaks of ${\alpha}$, ${\alpha}$$_2$, ${\beta}$ and ${\gamma}$from high temperature in a TSC spectrum. It seems that ${\alpha}$$_1$ peak is due to thermal depolarization of donor ions forming the space charge in the depletion layer, and ${\alpha}$$_2$peak is due to the detrapping of trapped electrons in deep trap level of intergranular layer, and ${\beta}$ peak is due to the thermal exciting of carrier existing in the donor level of grain itself, and ${\gamma}$ peak is due to the thermal exciting of trapped carrier in all shallow trap site randomly distributed in the inner of sample and/or a intrinsic impurity existing in it.

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Crystal Structure of Hexapotassium Undecahydrogen Tetratungsto Hexaantimonate(Ⅴ) Tetrahydrate (Hexapotassium Undecahydrogen Tetratungsto Hexaantimonate(Ⅴ) Tetraphydrate의 결정 구조)

  • Park, Gi Min;Yoshiki Ozawa;Lee, Uk;Lee, Uk
    • Journal of the Korean Chemical Society
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    • v.38 no.5
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    • pp.359-365
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    • 1994
  • The crystal stucture of hexapotassium undecahydrogen tetratungsto hexaantimonate(V) tetrahydrate has been determined from single crystal X-ray diffraction data. Crystal data are as follows: $K_6H_{12}[Sb_6W_4O_{36}]{\cdot}4H_2O$, Fw = 2360.62, tetragonal, I$4_1$/a, a = 10.799(1) ${\AA}$, c = 35.244(5) ${\AA}$, V = 4110.1(7) ${\AA}^3$, Z = 4, $D_x$ = 3.82 g$cm^{-3}$, $\mu(MoK\alpha)$ = 160.15 $cm^{-1}$, T = 293 K, final R = 0.0356 for 2400($F_0 > 3\sigma(F_0))$ independent reflections. The $[H_{12}Sb_6W_4O_{36}]^{-6}$ polyanion independently consists of one tungsten, two antimony, and nine oxygen atoms and belongs to the $\bar4(S_4)$ point group. This polyanion is formed by two open octahedra five membered ring of Sb(3)$O_6-W(1)O_6-Sb(2)O_6-W(1)O_6-Sb(3)O_6$ which is connected at right angle. The Sb-W, Sb-O, and W-O bond distances range from 3.2304(9) to 3.2403(5) $\AA$, 1.745(8) to 2.334(6) $\AA$, and 1.914(7) to 2.039(7) $\AA$, respectively.

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