• Title/Summary/Keyword: ${\alpha}$-Method

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Isoconversional Cure Kinetics of Modified Urea-Formaldehyde Resins with Additives

  • Park, Byung-Dae
    • Current Research on Agriculture and Life Sciences
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    • v.30 no.1
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    • pp.41-50
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    • 2012
  • As a part of abating formaldehyde emission of urea-formaldehyde resin, this study was conducted to investigate the rmalcure kinetics of both neat and modified urea-formaldehyde resins using differential scanning calorimetry. Neat urea-formaldehyde resins with three different formaldehyde/urea mol ratios (1.4, 1.2 and 1.0) were modified by adding three different additives (sodium bisulfite, sodium hydrosulfite and acrylamide) at two different levels (1 and 3wt%). An isoconversional method at four different heating rates was employed to characterize thermal cure kinetics of these urea-formaldehyde resins to obtain activation energy ($E{\alpha}$) dependent on the degree of conversion (${\alpha}$). The $E{\alpha}$ values of neat urea-formaldehyde resins (formaldehyde/urea = 1.4 and 1.2) consistently changed as the ${\alpha}$ increased. Neat and modified urea-formaldehyde resins of these two F/U mol ratios did show a decrease of the $E{\alpha}$ at the final stage of the conversion while the $E{\alpha}$ of neat urea-formaldehyde resin (formaldehyde/urea = 1.0) increased as the ${\alpha}$ increased, indicating the presence of incomplete cure. However, the change of the $E{\alpha}$ values of all urea-formaldehyde resins was consistent to that of the Ea values. The isoconversional method indicated that thermal cure kinetics of neat and modified urea-formaldehyde resins showed a strong dependence on the resin viscosity as well as diffusion control reaction at the final stage of the conversion.

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Preliminary Results of Polarimetric Characteristics for C-band Quad-Polarization GB-SAR Images Using H/A/$\alpha$ Polarimetric Decomposition Theorem

  • Kang, Moon-Kyung;Kim, Kwang-Eun;Lee, Hoon-Yol;Cho, Seong-Jun;Lee, Jae-Hee
    • Korean Journal of Remote Sensing
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    • v.25 no.6
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    • pp.531-546
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    • 2009
  • The main objective of this study is to analyse the polarimetric characteristics of the various terrain targets by ground-based polarimetric SAR system and to confirm the compatible and effective polarimetric analysis method to reveal the polarization properties of different terrain targets by the GB-SAR. The fully polarimetric GB-SAR data with HH, HV, VH, and VV components were focused using the Deramp-FFT (DF) algorithm. The focused GB-SAR images were processed by the H/A/$\alpha$ polarimetric decomposition and the combined H/$\alpha$ or H/A/$\alpha$ and Wishart classification method. The segmented image and distribution graphs in H/$\alpha$ plane using Cloude and Pottier's method showed a reliable result that this quad-polarization GB-SAR data could be useful to classified corresponding scattering mechanism. The H/$\alpha$-Wishart and H/A/$\alpha$-Wishart classification results showed that a natural media and an artificial target were discriminated by the combined classification, in particular, after applying multi-looking and the Lee refined speckle filter.

Probabilistic Safety Assessment of Nuclear Power Plants Using Alpha Factor Method for Common Cause Failure (알파모수 공통원인고장 평가 기법을 활용한 원자력발전소 안전성 평가)

  • Hwang, Seok-Won
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.10 no.1
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    • pp.51-55
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    • 2014
  • Based on the results of Probabilistic Safety Assessment(PSA) for a Nuclear Power Plant (NPP), Common Cause Failure(CCF) events have been recognized as one of the main contributors to the risk. Also, the CCF data and estimation method used in domestic PSA models have been pointed out as an issue with respect to the quality. The existing method of MGL and non-staggered testing even widely used were considered conservative in estimating the safety and had a limited capability in uncertainty analyses. Therefore, this paper presents the CCF estimation using a new generic data source and Alpha factor method. The analyses showed that Alpha factor and staggered method are effective in estimating the CCF contribution and risk insights of reference plant. This method will be a common bases for the optimization of new design for the construction plants as well as for the updating of safety assessment on the operating nuclear power plants.

A Fuzzy Resoning for Servo System by $\alpha$-Level Set Decomposition and Hardware Implementation ($\alpha$-레벨집합 분해에 의한 서보시스템용 퍼지추론과 하드웨어)

  • 안영주
    • Proceedings of the KIPE Conference
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    • 2000.07a
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    • pp.38-40
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    • 2000
  • In this paper we propose a calculation method for fuzzy control based on quantized $\alpha$-cut decomposition of fuzzy sets. This method is easy to be implemented in analog hardware. The effect of quantization levels on defuzzified fuzzy inference results is investigated. A few quantization levels are sufficient for fuzzy control. The hardware implementation of this calculation method and the defuzzification by gravity center method by PWM are also presented.

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Synthesis of $(\pm)-\alpha-Hydroxy-\alpha$-(p-Chlorobiphenyl)Acetic Acid and its Resolution ($(\pm)-\alpha-Hydroxy-\alpha$-(p-Chlorobiphenyl)acetic acid 합성과 분할)

  • 권순경
    • YAKHAK HOEJI
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    • v.39 no.4
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    • pp.433-437
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    • 1995
  • Optically pure(-)-and (+)-$\alpha$-hydroxy-$\alpha$-(p-chlorobiphenyl)acetic acids were prepared. The racemate was synthesized through three steps. By condensation of p-cnorobiphenyl with diethyl ketomalonate in the presence of SnCl$_{4}$, diethyl $\alpha$-hydroxy-$\alpha$-(p-chlorobiphenyl)malonate (1) was formed and subsequently ($\pm$)-$\alpha$-hydroxy-$\alpha$-(p-chlorobiphenyl)acetic acid (3) was obtained through hydrolysis and decarboxylation. For the separation of the racemate the classical resolution method, derivatization of a racemate by reaction with an optically pure compound was employed. In this case the optically pure compound were [R]-(+)-$\alpha$-methylbenzylamine and [S]-(-)-$\alpha$-methylbenzylamine. Diastereomeric salts between acids and bases could be easily separated by crystallization in absolute ethanol.

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Fuzzy $\alpha-\beta$ filter for vehicle tracking (차량 추적 성능 향상을 위한 퍼지 $\alpha-\beta$ 필터)

  • 정태진;김인택;한승수
    • Proceedings of the IEEK Conference
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    • 2000.06e
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    • pp.43-46
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    • 2000
  • In this paper, we present a method for vehicle tracking systems using $\alpha$-$\beta$ filter based on fuzzy logic. The $\alpha$-$\beta$ filter estimates the future target positions using fixed $\alpha$.$\beta$ coefficients. We utilize the fuzzy logic to make $\alpha$ and $\beta$ coefficients very with the position. Comparisons of tracking performance made for three different schemes: the $\alpha$-$\beta$ filter, $\alpha$-$\beta$filter using fuzzy logic, and the kalman filter.

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Colorimetric Determination of ${\alpha}-Cyclodextrin$ by Using the Decoloration of Starch-iodine Complex (Starch-iodine Complex의 변색반응을 이용한 ${\alpha}-Cyclodextrin$의 정량)

  • Suh, In-Yeong;Huh, Chul-Sung;Hwang, In-Kyu
    • Korean Journal of Food Science and Technology
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    • v.22 no.7
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    • pp.802-804
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    • 1990
  • A new colorimetric method to analyze ${\alpha}-Cyclodextrin({\alpha}-CD)$ by using a property of ${\alpha}-CD$ to decolor the starch-iodine complex, was presented. ${\alpha}-CD$ was quantitatively determined as follows. The ${\alpha}-CD$ standard solutions at concentrations up to 2 mg/ml were prepared. To 1ml of starch-iodine complex solution which contained starch(1%) and iodine (0.02% $I_2$, 0.2% KI) equivalently in distilled water, $200\;{\mu}l$ of ${\alpha}-CD$ standard solutions and 3 ml of distilled water were added and the absorbance was measured at 570 nm. Using this mothod ${\alpha}-CD$ concentration range at $0{\sim}2\;mg/ml$ could be determined and their absorbance patterns at 570 nm showed a good linearity. ${\beta}(CD)$ and glucose had no interference in this method for ${\alpha}-CD$ determination.

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Comparison of Phytoplankton Chlorophyll-$\alpha$ Extracted with Different Solvents

  • Lee, Yun-Kyoung;Shin, Myoung-Sun;Jung, Yu-Kyong;Jang, Chang-Won;Kim, Bom-Chul
    • Korean Journal of Ecology and Environment
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    • v.41 no.4
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    • pp.485-489
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    • 2008
  • Algal chlorophyll-$\alpha$ is commonly determined by spectro-photometric method using 90% acetone as solvents. However, acetone has low extraction efficiency without grinding filters, and DMF (dimethyl formamide) was tested for the compatibility with acetone. Chlorophyll-$\alpha$ concentration was determined for samples from 5 reservoirs of different trophic states and phytoplankton composition, using acetone extraction with grinding and DMF without grinding. Chlorophyll-$\alpha$ measured by DMF and Acetone did not show a significant difference when using trichromatic method of UNESCO and Lorenzen, and therefore, DMF can substitute acetone. But when acidification method was applied, they showed significant difference of 8%. It can be concluded that DMF can extract chlorophylls more effectively without grinding and it can be a better alternative for the standard extraction solvent.

Applicability of the mα-tangent Method to Estimate Plastic Limit Loads of Elbows and Branch Junctions (선형탄성해석과 mα-tangent방법을 이용한 배관 한계하중 평가 적용성)

  • Gim, Jae-Min;Kim, Sang-Hyun;Bae, Kyung-Dong;Kim, Yun-Jae;Kim, Jong-Sung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.41 no.6
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    • pp.499-505
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    • 2017
  • In this study, the limit loads calculated by the $m_{\alpha}-tangent$ method based on the linear finite element analysis are compared with the closed form solutions that are proposed by various authors. The objects of the analysis is to select the elbow and the branch pipe which are representative structure of piping system. The applicability of the $m_{\alpha}-tangent$ method are investigated by applying it to cases with various geometries. The internal pressure and the in-plane bending moment are considered and the $m_{\alpha}-tangent$ method is in good agreement with the existing solutions in case of elbows. However, the limit loads calculated by the $m_{\alpha}-tangent$ method for branch junctions do not agree well with the existing solutions and do not show any tendency. The reason is a biased result due to the stress concentration of the discontinuous parts.

Synthesis of Tiaprofenic Acid (Tiaprofenic Acid의 합성)

  • Choi, Hong-Dae
    • YAKHAK HOEJI
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    • v.33 no.4
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    • pp.237-240
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    • 1989
  • A new synthetic method for tiaprofenic acid, which is a potent anti-inflammatory agent, was described. Friedel-Crafts reaction of thiophene with ethyl ${\alpha}-chloro-{\alpha}-(methylthio)$ acetate (1) gave ethyl ${\alpha}-methylthio-2-thiopheneacetate$ (3). Ethyl ${\alpha}-methyl-2-thiopheneacetate$ (5) was prepared by treatment of (3) with NaH and MeI, followed by desulfurization with zinc dust-acetic acid of the resultant ethyl ${\alpha}-methyl-{\alpha}-methylthio-2-thiopheneacetate$ (4). Tiaprofenic acid (7) could be easily synthesized by benzoylation of (5) and hydrolysis of the resultant ethyl $5-benzoyl-{\alpha}-methyl-2-thiopheneacetate$ (6).

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