• 제목/요약/키워드: ${\Sigma}3$ boundary

검색결과 40건 처리시간 0.025초

Proton Conduction in Nonstoichiometric Σ3 BaZrO3 (210)[001] Tilt Grain Boundary Using Density Functional Theory

  • Kim, Ji-Su;Kim, Yeong-Cheol
    • 한국세라믹학회지
    • /
    • 제53권3호
    • /
    • pp.301-305
    • /
    • 2016
  • We investigate proton conduction in a nonstoichiometric ${\Sigma}3$ $BaZrO_3$ (210)[001] tilt grain boundary using density functional theory (DFT). We employ the space charge layer (SCL) and structural disorder (SD) models with the introduction of protons and oxygen vacancies into the system. The segregation energies of proton and oxygen vacancy are determined as -0.70 and -0.54 eV, respectively. Based on this data, we obtain a Schottky barrier height of 0.52 V and defect concentrations at 600K, in agreement with the reported experimental values. We calculate the energy barrier for proton migration across the grain boundary core as 0.61 eV, from which we derive proton mobility. We also obtain the proton conductivity from the knowledge of proton concentration and mobility. We find that the calculated conductivity of the nonstoichiometric grain boundary is similar to those of the stoichiometric ones in the literature.

두개의 수직 다공성 벽면을 가진 좁은 간격에서의 유체의 열적 불안정성 (Thermal Instability of Fluid in a Slot between Two Vertical Permeable Walls)

  • 손동연;유정열;이택식
    • 대한설비공학회지:설비저널
    • /
    • 제13권4호
    • /
    • pp.215-222
    • /
    • 1984
  • An analytical study on the thermal instability of fluid in a vertical solt between two permeable walls has been carried out using fast converging power series solution method. For given values of prandtl number Pr and permeability paramter ${\sigma}$, the critical Grashof number $Gr_c$ and the critical wave number ac are found as eigenvalues of the problem formulated by the stability equations and the appropriate boundary conditions which are derived on the basis of linear stability theory. In the case of ${\sigma}\;>\;10^4$, the results approach those of solid boundary case, but in the case of ${\sigma}\;<\;10^3$, the decrease of $Gr_c$ and $a_c$become more prominent. In other words, the permeable walls cause the flow to be more unstable than the solid walls. This is considered to be due to the slip of the fluid on the wail, which decrease the friction force.

  • PDF

ROLLING STONES WITH NONCONVEX SIDES II: ALL TIME REGULARITY OF INTERFACE AND SURFACE

  • Lee, Ki-Ahm;Rhee, Eun-Jai
    • 대한수학회지
    • /
    • 제49권3호
    • /
    • pp.585-604
    • /
    • 2012
  • In this paper we consider the evolution of the rolling stone with a rotationally symmetric nonconvex compact initial surface ${\Sigma}_0$ under the Gauss curvature flow. Let $X:S^n{\times}[0,\;{\infty}){\rightarrow}\mathbb{R}^{n+1}$ be the embeddings of the sphere in $\mathbb{R}^{n+1}$ such that $\Sigma(t)=X(S^n,t)$ is the surface at time t and ${\Sigma}(0)={\Sigma}_0$. As a consequence the parabolic equation describing the motion of the hypersurface becomes degenerate on the interface separating the nonconvex part from the strictly convex side, since one of the curvature will be zero on the interface. By expressing the strictly convex part of the surface near the interface as a graph of a function $z=f(r,t)$ and the non-convex part of the surface near the interface as a graph of a function $z={\varphi}(r)$, we show that if at time $t=0$, $g=\frac{1}{n}f^{n-1}_{r}$ vanishes linearly at the interface, the $g(r,t)$ will become smooth up to the interface for long time before focusing.

COMPACT OPERATOR RELATED WITH POISSON-SZEGö INTEGRAL

  • Yang, Gye Tak;Choi, Ki Seong
    • 충청수학회지
    • /
    • 제20권3호
    • /
    • pp.333-342
    • /
    • 2007
  • Suppose that ${\mu}$ is a finite positive Borel measure on the unit ball $B{\subset}C^n$. The boundary of B is the unit sphere $S=\{z:{\mid}z{\mid}=1\}$. Let ${\sigma}$ be the rotation-invariant measure on S such that ${\sigma}(S)=1$. In this paper, we will show that if $sup_{{\zeta}{\in}S}\;{\int}_{B}\;P(z,{\zeta})d{\mu}(z)$<${\infty}$ where $P(z,{\zeta})$ is the Poission-Szeg$\ddot{o}$ kernel for B, then ${\mu}$ is a Carleson measure. We will also show that if $sup_{{\zeta}{\in}S}\;{\int}_{B}\;P(z,{\zeta})d{\mu}(z)$<${\infty}$, then the operator T such that T(f) = P[f] is compact as a mapping from $L^p(\sigma)$ into $L^p(B,d{\mu})$.

  • PDF

부유체하부의 3차원 흐름해석을 위한 Rigid lid 경계조건의 적용 (Application of Rigid Lid Boundary Condition for Three Dimensional Flow Analysis beneath Floating Structure)

  • 홍남식
    • 한국해양공학회지
    • /
    • 제26권5호
    • /
    • pp.55-62
    • /
    • 2012
  • In this paper, the rigid lid boundary condition is applied to simulate the influence of floating structures such as ships or pontoons, and the pressure term in both the momentum equations and continuity equation are modified. The pressure of a floating structure under the free surface is dependent on the draft of the structure, generally called a ship. If the free surface is covered by a floating structure, the free surface cannot move freely. The water level should be fixed, using a rigid lid boundary condition. This boundary condition is implemented by reducing the storage area of the grid cell with a factor between zero and one. The numerical model developed by Hong (2009) is verified through a comparison with experimental results, and the influence of the reduction factor is investigated using the verified numerical model.

압연강판(壓延鋼板)의 피로균열(被虜龜裂) 전파거동(傳播擧動)에 대(對)한 연구(硏究) (A Study on the Propagation Behaviour of the Fatigue Cracks in Rolled Steel Plates)

  • 강창수
    • 대한조선학회지
    • /
    • 제12권2호
    • /
    • pp.43-58
    • /
    • 1975
  • There are many reports on fatigue crack of metallic materials but most of them relate crack propagation rate to stress intensity factor. The problem of crack propagation is not yet clarified, especially the bridge between micro and macro phenomena In this experiment rotating bending fatigue tests have been carried out with smoothed specimen of rolled steel plates including 0.2% carbon under application of three stress conditions to investigate the slip band and the crack propagation behaviour. The results obtained are as follows; 1) The length of cracks which have grown at initial crack tips can be expressed as follows; $l=Ae^{BNr}$(A,B: constant, $N_r$: cycle ratio) $\frac{dl}{dN}=\frac{AB}{N_f}{\cdot}e^{BNr}$($N_f$:fatigue life) 2) The ratio of slipped grain number to total grain number is $S_f=7{\sigma}-5.6$-5.6{\sigma}_c$($\sigma$: stress amplitude) (${\sigma}_c$: fatigue limit) 3) When the fatigue process transfers from Stage I to Stage II, the crack which propagates into specimen changes its direction from that of the maximum shear stress to the direction of perpendicular to principal stress and this is same in the circumferential direction of specimen. the crack propagation behaviors of both sides of a crack are different each other when they approach to the grain boundary.

  • PDF

가공된 층상조직의 구상화 속도의 해석 (Analysis of Rate Equation for Spherodization of Cold Rolled Lamellar Pearlite Structure)

  • 위명용
    • 열처리공학회지
    • /
    • 제4권2호
    • /
    • pp.1-8
    • /
    • 1991
  • The spheroidization of cold rolled lamellar pearlite in annealing at the temperatures between 600 and $700^{\circ}C$ has been studied by quantitative micrography. It was foud that the spheroidization proceeded as two stageh. The first stage was the stage of relieving the stored energy by cold work, the second was the stage of reducing the interface energy between ferrite and cementite. The spheroidization rate combining the spheroidization rate of each stages is described by the following equation : $$d(1/S)/dt=k_3{\cdot}D/_{(1/s)}\{{\sigma}V/_{(1/s)}+k_4{\cdot}{\exp}(-bt)\}$$ Where, S is the total area of the interface between ferrite and cementite per unit volume, D is the diffusion coefficient, ${\sigma}$ is the boundary energy, V is the volume fraction of the cementite, and $k_3$, $k_4$, b are constants.

  • PDF

NOTE ON CONTACT STRUCTURE AND SYMPLECTIC STRUCTURE

  • Cho, Mi-Sung;Cho, Yong-Seung
    • 대한수학회보
    • /
    • 제37권1호
    • /
    • pp.181-189
    • /
    • 2000
  • Let (X, J) be a closed, connected almost complex four-manifold. Let $X_1$ be the complement of an open disc in X and let ${\varepsilon}_1$be the contact structure on the boundary ${\varepsilon}X_1$ which is compatible with a symplectic structure on $X_1$, Then we show that (X, J) is symplectic if and only if the contact structure ${\varepsilon}_1$ on ${\varepsilon}X_1$ is isomorphic to the standard contact structure on the 3-sphere $S^3$ and ${\varepsilon}X_1$is J-concave. Also we show that there is a contact structure ${\varepsilon}_0\ on\ S^2\times\ S^1$which is not strongly symplectically fillable but symplectically fillable, and that $(S^2{\times}S^1,\;{\varepsilon})$ has infinitely many non-diffeomorphic minimal fillings whose restrictions on$\S^2\times\ S^1$are ${\sigma}$ where ${\sigma}$ is the restriction of the standard symplectic structure on $S^2{\times}D^2$.

  • PDF

사각 평판에서 타원의 형상 변화에 따른 응력집중계수에 관한 연구 (A Study on the Stress Concentration Coefficient due to the Change of Ellipse on a Square Plate)

  • 박정호;김형준;박기훈;조우석;제승봉;김현수
    • 한국정밀공학회:학술대회논문집
    • /
    • 한국정밀공학회 2003년도 춘계학술대회 논문집
    • /
    • pp.1434-1437
    • /
    • 2003
  • Sometimes open holes are required for the function and the weight reduction of structure and machinery. However, the serious stress concentration occurs because of the geometric discontinuity caused by the holes and cutting section. In this study, it is attempted to obtain the stress concentration coefficients of the inner surface of the hole boundary by changing the position and the shape of holes on the homogeneous isotropic plate. And the effects on the plate are investigated. The results show that the stress level becomes low and the distribution area widens the position of stress concentration changes as the ratio a/b increases and change to a circle. And as the ratio a/l decreases, the stress concentration reduces. As the plate with three holes. the stress $\sigma$$\_$x/ and $\tau$$\_$xy/ of hole 1,3 becomes high, especially $\sigma$$\_$x/ dominant and high.

  • PDF