• Journal of Electrochemical Science and Technology
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• 제5권1호
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• pp.32-36
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• 2014

The $0.3Li_2MnO_3{\cdot}0.7LiMn_{0.55}Ni_{0.30}Co_{0.15}O_2$ cathode material was prepared via a co-precipitation method. The vapor grown carbon fiber (VGCF) was used as a conductive material and its effects on electrochemical properties of the $0.3Li_2MnO_3{\cdot}0.7LiMn_{0.55}Ni_{0.30}Co_{0.15}O_2$ cathode material were investigated. From the XRD pattern, the typical complex layered structure was confirmed and a solid solution between $Li_2MnO_3$ and $LiMO_2$ (M = Ni, Co and Mn) was formed without any secondary phases. The VGCF was properly distributed between cathode materials and conductive sources by a FE-SEM. In voltage profiles, the electrode with VGCF showed higher discharge capacity than the pristine electrode. At a 5C rate, 146 mAh/g was obtained compared with 232 mAh/g at initial discharge in the electrode with VGCF. Furthermore, the impedance of the electrode with VGCF did not changed much around $9-10{\Omega}$ while the pristine electrode increased from 21.5${\Omega}$ to $46.3{\Omega}$ after the $30^{th}$ charge/discharge cycling.

• Journal of Electrochemical Science and Technology
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• 제7권4호
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• pp.245-250
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• 2016

The layered $Na_{0.6}Li_{0.6}[Mn_{0.72}Ni_{0.18}Co_{0.10}]O_2$ composite with well crystalized and high specific capacity is prepared by molten-salt method and using the substitution of Na for Li-ion battery. The effects of annealing temperature, time, Na contents, and electrochemical performance are investigated. In XRD analysis, the substitution of Na-ion resulted in the P2-$Na_{2/3}MO_2$ structure ($Na_{0.70}MO_{2.05}$), which co-exists in the $Na_{0.6}Li_{0.6}[Mn_{0.72}Ni_{0.18}Co_{0.10}]O_2$ composites. The discharge capacities of cathode materials exhibited $284mAhg^{-1}$ with higher initial coulombic efficiency.

• Bulletin of the Korean Chemical Society
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• 제16권3호
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• pp.265-269
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• 1995

Complexation of ortho-xylyl-17-crown-5 (X17C5) with alkali metal ions in acetonitrile was studied by 7Li and 23Na NMR spectroscopy. The complex formation constants of X17C5 with LiI, LiSCN, NaI, and NaSCN were determined by investigating the changes in the chemical shifts as a function of the concentration ratio of X17C5 to metal ion. It was found that X17C5 forms 1:1 complex with Li+ and Na+ ions and the log Kf's for the complexation with LiI, LiSCN, NaI, and NaSCN were determined to be 2.88, 2.43, 2.53, and 2.30, respectively. In particular, the kinetics of complexation of X17C5 with Na+ was investigated by the method of 23Na NMR lineshape analysis. Activation energies were determined from Arrhenius plot of the resultant rate constant data to be 25.4 kJ/mol for NaI and 15.1 kJ/mol for NaSCN. Other kinetic parameters were also calculated by employing the Eyring equation. The decomplexation rates measured were 1.82 × 104 M-1s-1 for NaI and 1.50 × 104 M-1s-1 for NaSCN. It is concluded that the decomplexation mechanism is predominantly a bimolecular cation exchange for both cases.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 추계학술대회 초록집
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• pp.137.2-137.2
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• 2011

Poly (sodium 4-styrenesulfonate) (PSS) is ionomer based on polystyrene that is electrical conductivity and isoviscosity. LiFePO4 has been a promising electrode material however its poor conductivity limits practical application. To enhance the electronic conductivity of LiFePO4, in this study we prepared LiFePO4- PSS composite by the hydrothermal method. LiFePO4 was heated at $170^{\circ}C$ for 12h and then different wt% PSS (0%, 2.91%, 4.75%, 7.36%, 10%) are added to LiFePO4 and milled at 300rpm for 10h. And then the obtained powders were subsequently heated at $500^{\circ}C$ for 1h under argon flow. The cathode electrode were made from mixtures of LiFePO4-PSS: SP-270- PVDF in a weighting ratio 75%: 25%:5%. The electrochemical properties of LiFePO4- PSS/Li batteries were analyzed by cyclic voltammetry and charge/discharge tests. LiFePO4-C/Li battery with 4.75 wt% PSS displays discharge capacity of 128 mAh g-1 at room temperature that is considerably higher than pure LiFePO4/Li battery ( 113.48 mAhg-1).

• 한국세라믹학회지
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• 제41권1호
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• pp.92-95
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• 2004

Micro-Pulling Down (${\mu}$-PD) 법을 이용하여 $MnO_2$와 $Tb_4O_7$를 첨가하여 crack. 열 strain 등의 결함이 없는 화학양론조성의 $LiNbO_3$ 단결정을 c-축으로 직경 1.0mm, 길이 25-30mm의 크기로 성장시켰다. Electron Probe Micro Analysis (EPMA)를 이용하여 결정 내에 $MnO_2$와 $Tb_4O_7$이 균일하게 분포되어 있음을 확인하였다. 또한 Fourier Transform-Infrared Spectrophotometer (FT-IR)을 사용하여 OH 흡수밴드를 관찰하였고, 성장된 결정의 $MnO_2$와 $Tb_4O_7$ 첨가에 따른 형광특성의 변화를 측정하였다.

• 한국전자파학회논문지
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• 제14권6호
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• pp.558-566
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• 2003

Li$_2$CO$_3$가 첨가된 BiNbO$_4$ 세라믹스를 이용하여 후막 모노폴 안테나를 제작하였다. 그 결과 Li 이온이 Bi, Nb 이온과 결합하여 이온간의 거리를 증가시켰다. 이에 따라 이온 분극량이 증가하여 유전율은 증가하였지만 세라믹 내 격자구조의 왜곡이 심해져 유전손실이 증가하였다. 안테나 특성에 있어서는 유전율 보다는 품질계수(Q)의 영향을 직접적으로 받았다. 대역폭을 측정한 결과 Li$_2$CO$_3$ 첨가에 따른 급격한 품질계수의 저하와 함께 37 %에서 81.7 %까지 증가한 반면 안테나 이득은 -5.5 dBi 에서 -10.03 dBi까지 급격히 감소하였다. 이로 인해 방사패턴은 Li$_2$CO$_3$ 미(未)첨가 시 보다 낮은 dBi 값을 보여 주었다. 특히 무 지향성을 보여야될 x-y면 방사패턴의 경우 격자구조의 왜곡으로 인한 파장의 산란과 공기와 유전체의 경계면에서 높은 유전율 차이로 굴절이 일어나 심하게 왜곡되어 있었다. 그러나 낮은 품질계수(Q)로 인하여 모든 조성 범위에서 1 GHz 이상의 우수한 -10 dB 대역폭 특성을 보여주었다.

• Journal of Magnetics
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• 제15권1호
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• pp.25-28
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• 2010

This study examined the crystallographic and magnetic properties of vanadium-substituted lithium cobalt titanium ferrite, $Li_{0.7}Co_{0.2}Ti_{0.2}V_{0.2}Fe_{1.7}O_4$. Ferrite was synthesized using a conventional ceramic method. The samples annealed below $1040^{\circ}C$ showed X-ray diffraction peaks for spinel and other phases. However, the sample annealed above $1040^{\circ}C$ showed a single spinel phase. The lattice constant of the sample was $8.351\;{\AA}$, which was relatively unaffected by vanadium-substitution. The average grain size after vanadium-substitution was $13.90\;{\mu}m$, as determined by scanning electron microscopy. The M$\ddot{o}$ssbauer spectrum could be fitted to two Zeeman sextets, which is the typical spinel ferrite spectra of $Fe^{3+}$ with A and B sites, and one doublet. From the absorption area ratio of the M$\ddot{o}$ssbauer spectrum, the cation distribution was found to be ($Co_{0.2}V_{0.2}Fe_{0.6})[Li_{0.7}Ti_{0.2}Fe_{1.1}]O_4$. Vibrating sample magnetometry revealed a saturation magnetization and coercivity of 36.9 emu/g and 88.6 Oe, respectively, which were decreased by vanadium-substitution.

• Bulletin of the Korean Chemical Society
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• 제23권5호
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• pp.679-682
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• 2002

Layered Na0.7[Ni0.05Mn0.95]O2 compounds have been synthesized by a sol-gel method, using glycolic acid as a chelating agent. Na0.7[Ni0.05Mn0.95]O2 precursors w ere used to prepare layered lithium manganese oxides by ion exchange for Na by Li, using LiBr in hexanol. Powder X-ray diffraction shows the layered Na0.7[Ni0.05Mn0.95]O2 has an O3 type structure, which exhibits a large reversible capacity of approximately 190 mA h g-1 in the 2.4-4.5 V range. Na0.7[Ni0.05Mn0.95]O2 powders undergo transformation to spinel during cycling.

• 대한기계학회논문집B
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• 제39권7호
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• pp.591-598
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• 2015

본 연구에서는 핀 핏치와 핀 높이가 다른 7종류의 낮은 핀관에 대하여 LiBr 농도 0%.~50%, 열유속 $20kW/m^2{\sim}40kW/m^2$, 포화압력 7.38kPa~101.3kPa에서 풀 비등 실험을 수행하였다. 실험 범위에서 최적 낮은 핀관 형상은 핀 핏치 26fpi, 핀 높이 1.8mm로 나타났다. 핀 핏치가 너무 넓으면 전열 면적이 감소하고 핀 핏치가 너무 좁으면 기포의 성장 및 이탈이 원활하지 못하게 되어 최적 핀 핏치가 존재한다. 포화압력이 낮아질수록, LiBr 농도가 증가할수록 열전달계수는 감소하였다. 이는 포화압력이 낮아질수록 기포의 이탈직경은 증가하고 이탈 빈도는 감소하기 때문이다. 또한 LiBr 농도가 증가하면 포화온도는 증가하고 물질확산율은 감소하는데 이에 따라 기포의 성장속도가 감소하고 따라서 열전달계수가 감소하게 된다. 낮은 핀관의 열전달계수는 모든 포화압력과 농도에서 평활관의 열전달계수보다 크게 나타났다. 본 실험자료를 기반으로 상관식을 제시하였다.

• 고무기술
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• 제6권2호
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• pp.91-98
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• 2005

Nano-sized cathode materials for high power lithium ion polymer battery are easily and economically prepared using united eutectic self-mixing method without any artificial mixing procedures of reactants and ultra-miniaturization of products. While the micro-sized $LiNi_{0.7}Co_{0.3}O_2$ exhibits the discharge capacities of 167.8 mAh/g at 0.1C and 142.5 mAh/g at 3.0C, those of the nano-sized $LiNi_{0.7}Co_{0.3}O_2$ are 170.8 mAh/g at 0.1C and 159.3 mAh/g at 3.0C. In the case of $LiCoO_2$, the micro-sized $LiCoO_2$ exhibits the discharge capacities of 134.8 mAh/g at 0.1C and 118.6 mAh/g at 5.0C. Differently, the nano-sized $LiCoO_2$ exhibits the discharge capacities of 137.2 mAh/g at 0.1C and 131.7 mAh/g at 5.0C.