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Highly stabilized microstructure and excellent electrochemical performances of Ni-rich LiNi0.9Co0.05Mn0.05O2 cathode via La modification (La 개질을 통한 Ni-rich LiNi0.9Co0.05Mn0.05O2 양극재의 고도로 안정화된 미세구조 및 우수한 전기화학적 성능)

  • Seung-Hwan, Lee
    • Journal of Industrial Technology
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    • v.42 no.1
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    • pp.1-5
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    • 2022
  • Although the mileage of electric vehicles can be increased based on the excellent energy density of the LiNi0.9Co0.05Mn0.05O2, it is known that the reason for limiting its use is the low lifespan and poor surface stability due to the structural deformation of the LiNi0.9Co0.05Mn0.05O2. To improve the structural stability of LiNi0.9Co0.05Mn0.05O2, electrochemical performance is improved by La coating on the surface. La-modified LiNi0.9Co0.05Mn0.05O2 shows an initial capacity of 210.6 mAh/g, a capacity retention rate of 89.9 % after 50 cycles, and a retention rate of 52.5% at 6.0 C. These are superior performances than the pristine sample, because the structural stability of the LiNi0.9Co0.05Mn0.05O2 cathode is improved by the La coating.

Development of SWIR 3D Lidar System with Low Optical Power Using 1 Channel Single Photon Detector (1채널 단일광자검출기를 이용한 낮은 광출력의 SWIR(Short Wave Infrared) 3D 라이다 시스템 개발)

  • Kwon, Oh-Soung;Lee, Seung-Pil;Shin, Seung-Min;Park, Min-Young;Ban, Chang-Woo
    • Journal of the Korean Society of Industry Convergence
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    • v.25 no.6_3
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    • pp.1147-1154
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    • 2022
  • Now that the development of autonomous driving is progressing, LiDAR has become an indispensable element. However, LiDAR is a device that uses lasers, and laser side effects may occur. One of them is the much-talked-about eye-safety, and developers have been satisfying this through laser characteristics and operation methods. But eye-safety is just one of the problems lasers pose. For example, irradiating a laser with a specific energy level or higher in a dusty environment can cause deterioration of the dust particles, leading to a sudden explosion. For this reason, the dust ignition proof regulations clearly state that "a source with a pulse period of less than 5 seconds is considered a continuous light source, and the average energy does not exceed 5 mJ/mm 2 or 35 mW" [2]. Energy of output optical power is limited by the law. In this way, the manufacturer cannot define the usage environment of the LiDAR, and the development of a LiDAR that can be used in such an environment can increase the ripple effect in terms of use in application fields using the LiDAR. In this paper, we develop a LiDAR with low optical power that can be used in environments where high power lasers can cause problems, evaluate its performance. Also, we discuss and present one of the directions for the development of LiDAR with laser power limited by dust ignition proof regulations.

Shoreline Change Analysis of Haeundae Beach Using Airborne LiDAR Survey (항공 LiDAR 측량을 이용한 해운대 해안의 해안선 변화 분석)

  • Lee, Jae One;Kim, Yong Suk;We, Gwang Jae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.4D
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    • pp.561-567
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    • 2008
  • In this study, shoreline change was analyzed by RTK-GPS and advanced airborne LiDAR survey. For extraction of coastline, first of all, tide correction was conducted at all RTK-GPS points through the comparing with the corresponding tidal height, and cross section providing coastline was produced using Autocad Civil3D program. Comparing with two results of RTK-GPS (first, 29 Aug 2007; second, 6 Oct 2007) surveys, coastline of the first result had been decreased about 21m compare with that of the second. And it was also demonstrated that the length of coastline by the first RTK-GPS was 15m shorter than that by the airborne LiDAR survey (Dec. 2006). In addition, we recoquized that the erosion appeared in the top right-hand (dock area); the sediment in the bottom left-hand (Chosun beach area) of the Haeundae beach. As a result, therefore, it was learned that artificial sand filling for beach open and natural effects such as a typhoon, current drift, wind direction gave cause for area changes and coastline.

evaluation of Performance Characteristic on Triple Effect Absorption Cycle (삼중효용 흡수사이클의 성능특성 평가)

  • 권오경
    • Journal of Advanced Marine Engineering and Technology
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    • v.22 no.6
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    • pp.782-791
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    • 1998
  • This paper presents a computer simulation of five types of triple effect absorption cycles employ-ing the refrigerant absorbent combinations of NH3/LiNO3 low-pressure type NH3/LiNO3+H2O/LiBr binary two-stage type series flow cycle and two types of parallel flow cycle for H2O/LiBr. The absorption systems is investigated through cycle simulation to obtain the system characteristics with the cooling water inlet temperature approach temperature of absorber loss temperature of absorber and chilled water outlet temperature. The most important characteristic temperature of absorber and chilled water outlet temperature. The most important characteristic of NH3/LiNO3 low-pressure type and a NH3/LINO3+H2O/LiBr binary two-stage type is that it obtains a coefficient of performance higher than the sum of the performance coefficients of its part operating independently. As a result of this analysis the optimum designs and operating conditions were determined based on the operating conditions and the coefficient of performance.

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The Structural and Electrochemical Properties of Li[Ni0.6-xBaxCo0.1Mn0.3]O2 (x = 0, 0.01) by Barium Doping (Barium 도핑에 따른 Li[Ni0.6-xBaxCo0.1Mn0.3]O2(x=0, 0.01) 의 구조 분석 및 전기화학적 특성)

  • Jang, Byeong-Chan;Yoo, Gi-Won;Yang, Su-Bin;Min, Song-Gi;Son, Jong-Tae
    • Journal of the Korean Electrochemical Society
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    • v.17 no.4
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    • pp.222-228
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    • 2014
  • Ni-rich system $Li[Ni_{1-x-y}Co_xMn_y]O_2$ of lithium secondary battery cathode material keep a high discharge capacity. However, by the Ni content increases, there is a problem that the electrochemical properties and stability of the structure are reduced. In order to solve these problems, research for positive ion doping is performed. The one of the cathode material, barium-doped $Li[Ni_{0.6-x}Ba_xCo_{0.1}Mn_{0.3}]O_2$ (x=0.01), was synthesized by the precursor, $Ni_{0.6}Co_{0.1}Mn_{0.3}(OH)_2$, from the co-precipitation method. The barium doped materials have studied the structural and electrochemical properties. The analysis of structural properties, results of X-ray diffraction analysis, and those results confirmed the change of the lattice from the binding energy in the structure by barium doping. Increased stability of the layered structure was observed by $I_{(006)}+I_{(102)}/I_{(101)}$(R-factor) ratio decrease. we expected that the electrochemical characteristics are improved. 23 mAh/g discharge capacity of barium-doped $Li[Ni_{0.6-x}Ba_xCo_{0.1}Mn_{0.3}]O_2$ (x=0.01) electrode is higher than discharge capacity of $Li[Ni_{0.6}Co_{0.1}Mn_{0.3}]O_2$ due to decrease overvoltage. And, through the structural stability was confirmed that improved the cycle characteristics. We caused a reduction in charge transfer resistance between the electrolyte and the electrode was confirmed that the C-rate characteristics are improved.

The properties of a low expansion glass ceramics of $Li_{2}O-Al_{2}O_{3}-SiO_{2}$ system ($Li_{2}O-Al_{2}O_{3}-SiO_{2}$계 저팽창 결정화 유리의 특성)

  • Kim, Bok-Hee;Ko, Jung-Hoon;Nam, O-Jung;Kang, Woo-Jin;Lee, Chang-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.2
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    • pp.79-83
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    • 2009
  • The glass-ceramic of the $Li_{2}O-Al_{2}O_{3}-SiO_{2}$ system was investigated to develop the low thermal expansion materials. The glass of this system was heat treated at $775^{\circ}C$ for 2 h for nucleation and subsequently at $825{\sim}900^{\circ}C$ for 2 h for crystallization. The crystal structure of the glass-ceramic of this system was a single phase of $\beta$-quartz solid solution($Li_{x}Al_{x}Si_{1-x}O_{2}$). The thermal expansion of the glass-ceramic showed $4.40{\times}10^{-7}{\sim}1.33{\times}10^{-6}K^{-1}$ between $25{\sim}300^{\circ}C$ and $1.56{\times}10^{-6}{\sim}2.53{\times}10^{-6}K^{-1}$ between $25{\sim}800^{\circ}C$, higher than lower temperature range. The mechanical strength remained almost same at around high 110 MPa with heating temperature changes.

Studies on Crystallographic and Mossbauer Spectra of the LiFe0.9Mn0.1PO4 (LiFe0.9Mn0.1PO4 물질의 결정구조 및 뫼스바우어 분광 연구)

  • Kwon, Woo-Jun;Lee, In-Kyu;Rhee, Chan-Hyuk;Kim, Sam-Jin;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.22 no.1
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    • pp.15-18
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    • 2012
  • The olivine structured $LiFe_{0.9}Mn_{0.1}PO_4$ material was prepared by solid state method, and was analyzed by x-ray diffractometer (XRD), superconducting quantum interference devices (SQUID) and Mossbauer spectroscopy. The crystal structure of $LiFe_{0.9}Mn_{0.1}PO_4$ was determined to be orthorhombic (space group: Pnma) by Rietveld refinement method. The value of N$\acute{e}$el temperature ($T_N$) for $LiFe_{0.9}Mn_{0.1}PO_4$ was determined 50 K. The temperature dependence of the magnetization curves showed magnetic phase transition from paramagnetic to antiferromagnetic at $T_N$ by SQUID measurement. M$\ddot{o}$ssbauer spectra of $LiFe_{0.9}Mn_{0.1}PO_4$ showed 2 absorption lines at temperatures above $T_N$ and showed asymmetric 8 absorption lines at temperatures below $T_N$. These spectra occurred due to the magnetic dipole and electric quardrupole interaction caused by strong crystalline field at asymmetric $FeO_6$ octahedral sites.

Electrochemical Properties of Boron-doped Cathode Materials (LiNi0.90Co0.05Ti0.05O2) for Lithium-ion Batteries (붕소가 도핑된 리튬이온전지용 양극 활물질(LiNi0.90Co0.05Ti0.05O2)의 전기화학적 특성)

  • Kim, Geun Joong;Park, Hyun Woo;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.57 no.6
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    • pp.832-840
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    • 2019
  • To improve the electrochemical performances of the cathode materials, boron-doped $LiNi_{0.90}Co_{0.05}Ti_{0.05}O_2$ were synthesized by using concentration gradient precursor. The characteristics of the prepared cathode materials were analyzed by XRD, SEM, EDS, PSA, ICP-OES and electrical conductivity measurement. The electrochemical performances were investigated by initial charge/discharge capacity, cycle stability, C-rate, cyclic voltammetry and electrochemical impedance spectroscopy. The cathode material with 0.5 mol% boron exhibited a capacity of 187 mAh/g (0.5 C) in a voltage range of 2.7~4.3 V(vs. $Li/Li^+$), and an capacity retention of 94.7% after 50 cycles. In the relatively high voltage range of 2.7~4.5 V(vs. $Li/Li^+$), it showed a high capacity of 200 mAh/g and capacity retention of 80.5% after 50 cycles.

Analysis on Displacement Characteristics of Slow-Moving Landslide on a slope near road Using the Topographic Map and Airborne LiDAR (수치지형도와 항공 LiDAR를 이용한 도로인접 사면 땅밀림 발생지 변위 특성 분석)

  • Seo, Jun-Pyo;Kim, Ki-Dae;Woo, Choong-Shik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.5
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    • pp.27-35
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    • 2019
  • The purpose of this study is to analyze the displacement characteristics in slow-moving landslide area using digital elevation model and airborne LiDAR when unpredictable disaster such as slow-moving landslide occurred. We also aimed to provide basic data for establishing a rapid, reasonable and effective restoration plan. In this study, slow-moving landslide occurrence cracks were selected through the airborne LiDAR data, and the topographic changes and the scale of occurrence were quantitatively analyzed. As a result of the analysis, the study area showed horseshoe shape similar to the general form of slow-moving landslide occurrence in Korea, and the direction of movement was in the north direction. The total area of slow-moving landslide damage was estimated to about 2.5ha, length of landsldie scrap 327.3m, average width 19.3m, and average depth 8.6m. The slow-moving landslides did not occur on a large scale but occurred on the adjacent slope where roads were located, caused damage to retaining walls and roads. The field survey of slow-moving landslides was limited by accessibility and safety issues, but there was an advantage that accurate analysis was possible through the airborne LiDAR. However, because airborne LiDAR has costly disadvantages, it has proposed a technique to mount LiDAR on UAV for rapidity, long-term monitoring. In a slow-moving landslide damage area, information such as direction of movement of cracks and change of scale should be acquired continuously to be used in restoration planning and prevention of damage.

Structure Analysis of Mixed Crystals, $LiK_{1-x}Rb_{x}SO_{4}(x=0.1,\;0.2)$ ($LiK_{1-x}Rb_{x}SO_{4}(x=0.1,\;0.2)$의 결정구조 분석)

  • Kim, Jin-Gyu;Kim, Youn-Joong;Kim, Hae-Jin;Suh, Il-Hwan
    • Korean Journal of Crystallography
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    • v.16 no.2
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    • pp.75-80
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    • 2005
  • [ $LiK_{1-x}Rb_{x}SO_{4}(x=0.1,\;0.2)$ ] crystals were grown by means of aqueous solution growth technique at 313 K. Structure analysis of them was carried out with space group $P6_{3}(#173)$ by X-ray diffraction. In these compounds, the Li and $SO_{4}^{2-}$ ions lying on the three-fold axes formed infinite three-dimensional network and K and Rb atoms located on the six-fold axes are coordinated by twelve and fifteen O atoms respectively. The most suitable stabilization was achieved when the occupancy factors of K and Rb atoms are (0.91 : 0.09), (0.77 : 0.23) respectively.