• 제목/요약/키워드: $^6Li\

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Study of molecular motion by 1H NMR relaxation in ferroelectric LiH3(SeO3)2, Li2SO4·H2O, and LiN2H5SO4 single crystals

  • Park, Sung Soo
    • Journal of the Korean Magnetic Resonance Society
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    • v.20 no.1
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    • pp.1-6
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    • 2016
  • The proton NMR line widths and spin-lattice relaxation rates, $T_1^{-1}$, of ferroelectric $LiH_3(SeO_3)_2$, $Li_2SO_4{\cdot}H_2O$, and $LiN_2H_5SO_4$ single crystals were measured as a function of temperature. The line width measurements reveal rigid lattice behavior of all the crystals at low temperatures and line narrowing due to molecular motion at higher temperatures. The temperature dependences of the proton $T_1^{-1}$ for these crystals exhibit maxima, which are attributed to the effects of molecular motion by the Bloembergen - Purcell - Pound theory. The activation energies for the molecular motions of $^1H$ in these crystals were obtained. From these analysis, $^1H$ in $LiH_3(SeO_3)_2$ undergoes molecular motion more easily than $^1H$ in $LiN_2H_5SO_4$ and $Li_2SO_4{\cdot}H_2O$ crystals.

Electrochemical Properties of $LiMnO_2$ Cathode as a Function of Addition of Electric Active Materials for Lithium Polymer Batteries (리튬 폴리머 전지용 $LiMnO_2$정극의 도전재에 따른 전기 화학적 특성)

  • 조영재;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.474-477
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    • 2001
  • The properties of LiMnO$_2$ was studied as a cathode active material for lithium polymer batteries. LiMnO$_2$ cathode active materials were synthesized by the reaction of LiOH . $H_2O$ and Mn$_2$O$_3$at various temperature under argon atmosphere. For lithium polymer battery applications, the LiMnO$_2$cell was characterized electrochemically by charge-discharge experiments and a.c. impedance spectroscopy. And the relationship between the characteristics of powders and electrochemical properties was studied in this research. A maximum discharge capacity of 160-170 mAh/g for ο-LiMnO$_2$ cell was achieved. Used that SP270 as electric active material in LiMnO$_2$, it is excellent than property of electric active material used Acetylene black or KS6 at charge/discharge capacity.

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Crystallinity and Battery Properties of Lithium Manganese Oxide Spinel with Lithium Titanium Oxide Spinel Coating Layer on Its Surface

  • Ji, Mi-Jung;Kim, Eun-Kyung;Ahn, Yong-Tae;Choi, Byung-Hyun
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.633-637
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    • 2010
  • In this study, lithium manganese oxide spinel ($LiMn_{1.9}Fe_{0.1}Nb_{0.0005}O_4$) as a cathode material of lithium ion secondary batteries is synthesized with spray drying, and in order to increase its crystallinity and electrochemical properties, the granulated $LiMn_{1.9}Fe_{0.1}Nb_{0.0005}O_4$ particle surface is coated with lithium titanium oxide spinel ($Li_4Ti_5O_{12}$) through a sol-gel method. The granulated particles present a higher tap density and lower specific surface area. The crystallinity and discharge capacity of the $Li_4Ti_5O_{12}$ coated material is relatively higher than uncoated material. With the coating layer, the discharge capacity and cycling stability are increased and the capacity fading is suppressed successfully.

The Effects of Lithium Chloride on the Light-sensitivity and Circadian activity of Goldhamster. (LiCl이 Goldhamster의 빛 민감성과 활동주기에 미치는 영향)

  • 한상진
    • The Korean Journal of Zoology
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    • v.35 no.4
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    • pp.509-517
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    • 1992
  • LiCl (0.047 M)은 Goldhamster의 활동주기 (T)를 평균 1.6시간 연장시키고, 동물 중 20%엑서 단축되는 것으로도 관찰되었다. 1시간 통안의 빛자극(75 Lux)에 의해 주기현상 시점 변화가 나타나는 데 LICI에 의해서 0.3 h 더욱 delav되었고 advance 현상은 1.5 h 감소되었으며 delay엔h advance 전환시기는 1시간 늦게 나타났다. 반면에 7 Lux의 빛 자극에서는 delay가 2.4시간으로 더 증가되었으며 advance 현상은 2.6시간으로 저하되었고, 30분 늦게 delay에서 advance로 전환되었다. subjective day 동안에는 빛자극에 의한 LiCl 효과가 전혀 보이지 않았다. Phase-Response-Curve(PRC)는 Circadian Time에서 delay-advance로 전환되는 mid-subjective night에 점진적으로 변화되는 weak phase curve로 형성되었다. 이 PRC에서 Li이 빛에 대한 민감성을 둔화시키는 효과를 볼 수 있다.

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Chromatographic Separation of Lithum Isotopes by Hydrous Managanese(Ⅳ) Oxide (가수된 산화 망간(Ⅳ)에 의한 리튬 동위원소의 크로마토그래피적 분리)

  • Kim, Dong Won
    • Journal of the Korean Chemical Society
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    • v.45 no.3
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    • pp.219-222
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    • 2001
  • Separation of lithium isotopes was investigated by chemical ion exchange with a hydrous manganese(IV) oxide ion exchanger using an elution chromatography. The capacity of manganese(IV) oxide ion exchanger was 0.5 meq/g. The heavier lithium isotope was enriched in the solution phase, while the lighter isotope was enriched in the ion exchanger phase. The separation factor was determined according to the method of Glueckauf from the elution curve and isotopic assays. The separation factor of $^6Li^+$-$^7Li^+$ isotope pair fractionation was 1.018.

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Growth and Characteristic Infrared Raman Spectra of Potassium Lithium Niobate Single Crystals

  • Youbao Wan;Yoo, Sang-Im
    • Proceedings of the Korea Crystallographic Association Conference
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    • 2002.11a
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    • pp.15-15
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    • 2002
  • Homogeneous and crack-free potassium lithium niobate (K₃Li/sub 2-x/Nb/sub 5+x/O/sub 15/, 0<x<0.5, KLN) single crystals were successfully grown by the Czochralski technique. The KLN single crystals of several different compositions were employed for the investigation of the lattice vibration spectra using infrared Raman spectroscopy. The characteristic Raman spectra of the [NbO/sub 6/]/sup 7-/ octahedral ions were strikingly influenced by the Li ion content. The symmetric stretch vibrational modes V₁, V₂ are broadened, and the symmetric bend vibration mode V/sub 5/ is broadened and even split into three peaks with increasing the Li content, supporting that the bend vibration modes of the [NbO/sub 6/]/sup 7-/ octahedrons are obviously perturbed by Li ions in the C site. Enhanced Raman peak intensities after the post annealing at 900℃ and for 24 h evidenced that a residual stress in as-grown crystals was negligible and only a defect concentration might be reduced.

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Development of Pointcloud Data Integration Technology in Construction Sites via Drone Photogrammetry and MMS LiDAR (드론 및 MMS를 활용한 건설현장 점군 데이터 통합 기술 개발)

  • Jae-Woo Park;Dong-Jun Yeom
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.6_2
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    • pp.1145-1153
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    • 2023
  • This study presents the development of pointcloud data integration technology in construction sites via drone photogrammetry and MMS LiDAR. The integration of pointcloud data from drones and MMS technology can provide precise and accurate 3D digital maps of construction sites, which can benefit the development of smart construction and BIM. The advantages of using both drones and MMS technology for pointcloud data acquisition in construction sites are discussed, along with the limitations and challenges of using drone photogrammetry and MMS LiDAR for pointcloud data integration. The results of this study can contribute to the advancement of pointcloud data integration technology in construction sites and improve the efficiency and accuracy of construction projects.

Electrochemical Properties of Ionic Liquid Composite Poly(ethylene oxide)(PEO) Solid Polymer Electrolyte (이온성 액체 복합 Poly(ethylene oxide)(PEO) 고체 고분자 전해질의 전기화학적 특성)

  • Park, Ji-Hyun;Kim, Jae-Kwang
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.101-106
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    • 2016
  • In this study, we prepared an ionic liquid composite solid polymer electrolyte (PEO-LiTFSI-$Pyr_{14}TFSI$) with poly(ethylen oxide), lithium bis(trifluoromethanesulfonyl)imide, N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide by blending-cross linking process. Although the PEO-LiTFSI-$Pyr_{14}TFSI$ composite solid polymer electrolyte displayed a small peak at 4.4 V, it had high electrochemical oxidation stability up to 5.7 V. Ionic conductivity of the PEO-LiTFSI-$Pyr_{14}TFSI$ composite solid polymer electrolyte increased with increasing temperature from $10^{-6}S\;cm^{-1}$ at $30^{\circ}C$ to $10^{-4}S\;cm^{-1}$ at $70^{\circ}C$. To investigate the electrochemical properties, the PEO-LiTFSI-$Pyr_{14}TFSI$ composite solid polymer electrolyte assembled with $LiFePO_4$ cathode and Li-metal anode. At 0.1 C-rate, the cell delivered $40mAh\;g^{-1}$ for $30^{\circ}C$, $69.8mAh\;g^{-1}$ for $40^{\circ}C$ and $113mAh\;g^{-1}$ for $50^{\circ}C$, respectively. The PEO-LiTFSI-$Pyr_{14}TFSI$ solid polymer electrolyte exhibited good charge-discharge performance in Li/SPE/$LiFePO_4$ cells at $50^{\circ}C$.

Efficient method for acquirement of geospatial information using drone equipment in stream (드론을 이용한 하천공간정보 획득의 효율적 방안)

  • Lee, Jong-Seok;Kim, Si-Chul
    • Journal of Korea Water Resources Association
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    • v.55 no.2
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    • pp.135-145
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    • 2022
  • This study aims to verify the Drone utilization and the accuracy of the global navigation satellite system (GNSS), Drone RGB (Photogrammetry) (D-RGB), and Drone LiDAR (D-LiDAR) surveying performance in the downstream reaches of the local stream. The results of the measurement of Ground Control Point (GCP) and Check Point (CP) coordinates confirmed the excellence. This study was carried out by comparing GNSS, D-RGB, and D-LiDAR with the values which the hydraulic characteristics calculated using HEC-RAS model. The accuracy of three survey methods was compared in the area of the study which is the ownership station, to 6 GCP and 3 CP were installed. The comparison results showed that the D-LiDAR survey was excellent. The 100-year frequency design flood discharge was applied in the channel sections of the small stream. As a result of D-RGB surveying 2.30 m and D-LiDAR 1.80 m in the average bed elevation, and D-RGB surveying 4.73 m and D-LiDAR 4.25 m in the average flood condition. It is recommended that the performance of D-LiDAR surveying is efficient method and useful as the surveying technique of the geospatial information using the drone equipment in stream channel.

Large-area High-speed Single Photodetector Based on the Static Unitary Detector Technique for High-performance Wide-field-of-view 3D Scanning LiDAR (고성능 광각 3차원 스캐닝 라이다를 위한 스터드 기술 기반의 대면적 고속 단일 광 검출기)

  • Munhyun Han;Bongki Mheen
    • Korean Journal of Optics and Photonics
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    • v.34 no.4
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    • pp.139-150
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    • 2023
  • Despite various light detection and ranging (LiDAR) architectures, it is very difficult to achieve long-range detection and high resolution in both vertical and horizontal directions with a wide field of view (FOV). The scanning architecture is advantageous for high-performance LiDAR that can attain long-range detection and high resolution for vertical and horizontal directions. However, a large-area photodetector (PD), which is disadvantageous for detection speed, is essentially required to secure the wide FOV. Thus we propose a PD based on the static unitary detector (STUD) technique that can operate multiple small-area PDs as a single large-area PD at a high speed. The InP/InGaAs STUD PIN-PD proposed in this paper is fabricated in various types, ranging from 1,256 ㎛×949 ㎛ using 32 small-area PDs of 1,256 ㎛×19 ㎛. In addition, we measure and analyze the noise and signal characteristics of the LiDAR receiving board, as well as the performance and sensitivity of various types of STUD PDs. Finally, the LiDAR receiving board utilizing the STUD PD is applied to a 3D scanning LiDAR prototype that uses a 1.5-㎛ master oscillator power amplifier laser. This LiDAR precisely detects long-range objects over 50 m away, and acquires high-resolution 3D images of 320 pixels×240 pixels with a diagonal FOV of 32.6 degrees simultaneously.