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Mechanism of Crack Formation in Pulse Nd YAG Laser Spot Welding of Al Alloys (Al합금 펄스 Nd:YAG 레이저 점 용접부의 균열 발생기구)

  • Ha, Yong Su;Jo, Chang Hyeon;Gang, Jeong Yun;Kim, Jong Do;Park, Hwa Sun
    • Journal of Welding and Joining
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    • v.18 no.2
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    • pp.213-213
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    • 2000
  • This study was performed to investigate types and formation mechanism of cracks in two Al alloy welds, A5083 and A7NO1 spot-welded by pulse Nd: YAG laser, using SEM, EPMA and Micro-XRD. In the weld zone, three types of crack were observed: center line crack($C_{C}$), diagonal crack($C_{D}$), and U shape crack($C_{U}$). Also, HAZ crack($C_{H}$), was observed in the HAZ region, furthermore, mixing crack($C_{M}$), consisting of diagonal crack and HAZ crack was observed.White film was formed at the hot crack region in the fractured surface after it was immersed to 10%NaOH water. In the case of A5083 alloy, white films in C crack and $C_D crack region were composed of low melting phases, Fe₂Si$Al_8$ and eutectic phases, Mg₂Al₃ and Mg₂Si. Such films observed near HAZ crack were also consist of eutectic Mg₂Al₃. In the case of A7N01 alloy, eutectic phases of CuAl₂, $Mg_{32}$ (Al,Zn) ₃, MgZn₂, Al₂CuMg and Mg₂Si were observed in the whitely etched films near $C_{C}$ crack and $C_{D}$ crack regions. The formation of liquid films was due to the segregation of Mg, Si, Fe in the case of A5083 alloy and Zn, Mg, Cu, Si in the case of A7N01 aooly, respectively.The $C_{D}$ and $C_{C}$ cracks were regarded as a result of the occurrence of tensile strain during the welding process. The formation of $C_{M}$ crack is likely to be due to the presence of liquid film at the grain boundary near the fusion line in the base metal as well as in the weld fusion zone during solidification. The $C_{U}$ crack is considered a result of the collapsed keyhole through incomplete closure during rapid solidification. (Received October 7, 1999)

Study on the Characteristics of Gray Water from an Apartment Complex for Reuse (재이용을 위한 공동주택 Gray Water의 특성 연구)

  • Park, Su Jeong;Kwon, Oh Sang;Tanaka, Hiroaki;Kim, Chang Soo;Kim, Eun Seok;Kim, Ji Hye;Jang, Seok Jea;Ahn, Kyung Hee
    • Journal of Korean Society on Water Environment
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    • v.29 no.6
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    • pp.847-851
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    • 2013
  • This study describes the results of an investigation conducted in order to characterize the quantity and quality of individual gray water streams. The highest pollutants concentrations were found in gray water originating from kitchen and laundry with $BOD_5$ concentrations in the order of several hundreds $mgl^{-1}$. In contrast to this, bathroom was regarded as a major contributor of Escherichia coli. Laundry gray water has higher pH, sodium, sulfate, anionic surfactants. Individual gray water types had different contribution to the overall daily discharge and relative pollutants loads. Kitchen, although accounting for only 13% of the total volume, was identified as a major source of microorganisms with Total coliforms, Escherichia coli, Fecal streptococcus taking up 82%, 74% and 54% of their relative daily load, respectively. The laundry gray water, although being responsible for 36% of the total daily discharge, was established as a significant contributor of sodium, sulfate, anionic surfactants and TOC (70%, 72%, 84% and 52%, respectively). But the laundry gray water was a minor source of microorganisms. Bathroom was found to be a major gray water producer, making up 51% of the flow, but constituted less than 50% of the relative daily load in most cases.

Interaction between Light and other Factors Affecting Germination of Oenothera lamarckiana Ser. Seed. (큰달맞이꽃 종자발아(種子發芽)에 영향하는 요인(要因)과 광간(光間)의 상호작용(相互作用))

  • Kim, J.S.;Hwang, I.T.;Koo, S.J.;Cho, K.Y.
    • Korean Journal of Weed Science
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    • v.8 no.1
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    • pp.15-22
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    • 1988
  • In this experiment, interactions between light and other factors such as chilling, alternating temperature, moisture, content, oxygen, and seed coat which affect germination of Oenothera lamarckiana Ser. seed were investigated to study the physiological effects of light on the germination. Light induced the initial stage of seed germination before radical protrusion by affecting embryo rather than seed coat even under anaerobic condition or low water potential (-18 bars). This light effect on germinability of seed was suppressed by blue light irradiation and the effect was increased with increment of blue light intensity and irradiation time. However, the blue light effect was reversible. Chilling, alternating temperature, softening of seed coat and light showed promotive interaction in the induction of seed germination. Irradiation of filtered light (monochrome), however, reduced chilling effect on germination. Hydrogen-ion concentration and gibberellic acid treatment had no effect on light or dark germination.

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Effect of bentazon and propanil application on the photosynthesis of the rice plants, Monochoria vaginalis and Cyperus serotinus (Bentazon 및 Propanil 처리(處理)가 수도(水稻), 물달개비 및 너도방동산이의 광합성(光合成)에 미치는 영향(影響))

  • Ku, Y.C.;Park, S.H.;Park, R.K.;Joug, S.K.
    • Korean Journal of Weed Science
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    • v.7 no.2
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    • pp.139-143
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    • 1987
  • This experiment was conducted to investigate the effect of herbicide on the photosynthetic activity of the weed and rice plant. Two rice cultivars "Nongbaeg" and "Taebaegbyeo" were tested with butachlor, Molis-M, and perfluidone at 5 days after transplanting. Bentazone and propanil were sprayed at 25 days after transplanting. Photosynthetic activity was varied with herbicide and varieties. Generally, application of herbicide resulted in decreased photosynthetic activity. Indica ${\times}$ Japonica variety showed more sensitive to herbicide than Japonica variety. Recovery of the photosynthetic activity was faster in the bentazon than the propanil.

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Establishment of Control System of Weedy Rice(Oryza sativa) and Barnyardgrass(Echinochloa crus-galli) in Direct-seeded Rice - I. Effect of Oxadiazon, Molinate, Thiobencarb on Control of Red Rice and Barnyardgrass in Water-seeded Rice (벼 직파재배에 있어서 잡초성벼 및 피 방제체계 확립에 관한 연구 - I. 담수표면산파 재배시 앵미와 피에 대한 oxadiazon, molinate, thiobencarb의 파종전 처리 효과)

  • Ryang, H.S.;Kim, J.K.;Kyoung, E.S.;Kim, J.S.;Ma, S.Y.
    • Korean Journal of Weed Science
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    • v.18 no.2
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    • pp.106-115
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    • 1998
  • This study was conducted to investigate the effect of oxadiazon, molinate, thiobencarb before seeding on control of red rice and barnyardgrass in water-seeded rice. High application rate plot among oxadiazon treatment plots could observe phytotoxicity symptoms depending on field conditions, but these injury recovered gradually with time. Molinate and thiobencarb application plots at the concentration of 225~400, 210~420g ai/l0a respectively were not observed phytotoxicity. Control of red rice was different according to kinds of herbicides and application rates. Oxadiazon showed higher control performance at the concentration of more than 60g ai/10a. Control effect of molinate and thiobencarb against red rice was enhanced with the increase of application rate, and both herbicides showed satisfactory effect at more than 300g ai/10a. Control of barnyardgrass showed up to 90~100% in all tested herbicides. There was no significant yield reduction by oxadiazon, molinate, and thiobencarb application before seeding in all tested field. In the pot experiment, crop injury, seedling stand, and early growth were more advantageous at time of drainge after one day after seeding than flooding until rooting.

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Allelopathic Activity and Determination of Allelochemicals from Sunflower (Helianthus annuus L.) Root Exudates II. Elucidation of Allelochemicals from Sunflower Root Exudates (해바라기(Helianthus annuus L.) 근분비물질(根分泌物質)의 타감작용(他感作用) 및 타감물질(他感物質)의 동정(同定) II. 타감성(他感性) 해바라기 근분비물질(根分泌物質)의 동정(同定))

  • Park, K.H.;Moody, K.;Kim, S.C.;Kim, K.U.
    • Korean Journal of Weed Science
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    • v.12 no.2
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    • pp.173-182
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    • 1992
  • Regardless of the test species, germination was adversely affected by the different concentrations of the acidic and neutral fractions of sunflower root exudates while the basic and aqueous fractions had no effect on germination. In both test species, root lengths were inhibited slightly more than shoot lengths. Significant reduction in fresh weights of the test species was observed when the test species were treated with the acidic and neutral fractions but not with the basic and aqueous fractions. Six compounds, hydroquinone, ${\beta}$-resorcyclic acid, vanillic acid, caffeic acid, salicylic acid, and quercetin, were characterized from the acidic fraction. Seven compounds, hydroquinone, gentisic acid, ${\beta}$-resorcyclic acid, vanillic acid, caffeic acid, ferulic acid, and quercetin, were elucidated from the neutral fraction.

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Difference in sensitivity of Eleocharis kuroguwai tubers to bensulfuron-methyl at different burial depths (Bensulfuron-methyl에 대(對한) 올방개 괴경(塊莖) 이식(移植) 심도별(深度別) 감수성(感受性) 차이(差異))

  • Shin, H.S.;Chun, J.C.
    • Korean Journal of Weed Science
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    • v.13 no.1
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    • pp.55-61
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    • 1993
  • Difference in sensitivity of Eleocharis kuroguwai tubers to bensulfuron- methyl{methyl 2-[[[[[(4, 6-dimethoxy-2-pyrimidinyl) amino] carbonyl] amino] sulfonyl] methyl] benzoate} at different burial depths were determined with respect to tuber emergence, sprouting of lateral buds, carbohydrate consumption of the tuber, and growth and new tuber production of the regrown plants. Days required to regrowth from the growth cessation due to bensulfuron-methyl were shorter in shallow-buried tubers than in deep-buried tubers. With application of bensulfuron-methyl shallow-buried tubers consumed less carbohydrate in the tuber than deep-buried tubers as compared with in deep-buried tubers during the period of growth cessation and greater regrowth also occurred in the former. Fast and great regrowth in shallow-buried tubers resulted in great production of dry matter and new tubers. However, the differences obtained were not due to bensulfuron-methyl, but due mainly to ecological emergence and growth characteristics of tubers buried at different depths.

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Antimelanogenic Effect and Whitening of Anthocyanin Rich Fraction from Seeds of Liriope platyphylla (맥문동 종실 안토시아닌 분획물의 멜라닌 생성 억제 및 미백 효과)

  • Choung, Myoung Gun;Hwang, Young Sun;Kim, Gi Ppeum;Ahn, Kyung Geun;Shim, Hoon Seob;Hong, Seung Beom;Choi, Jae Hoo;Yu, Chang Yeon;Chung, Ill Min;Kim, Seung Hyun;Lim, Jung Dae
    • Korean Journal of Medicinal Crop Science
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    • v.21 no.5
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    • pp.361-371
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    • 2013
  • This study was performed to determine the antimelanogenic effect and tyrosinase inhibitory activities of anthocyanin rich fraction (AN-SLP) from Liriope platyphylla Wang et Tang seeds. Anthocyanins isolated from L. platyphylla seeds revealed the presence of four major anthocyanin components, which were tentatively identified as delphinidin-3-Oglucoside, delphinidin-3-O-rutinoside, petunidin-3-O-rutinoside, and malvidin-3-O-rutinoside using semipreparative HPLC, $^1H$-NMR, $^{13}C$ NMR, FAB-MS and LC/ES-MS. The inhibitory effect of AN-SLP on tyrosinase activity was studied using in vitro (against mushroom tyrosinase) and ex vivo (against B16 melanoma cell tyrosinase) models. Cellular tyrosinase activity was decreased by AN-SLP treatment in B 16 melanoma cells through dose dependent manner, but AN-SLP did not inhibit mushroom tyrosinase and L-DOPA oxidation directly. AN-SLP showed melanin inhibition by 53.2% at 50 ${\mu}g/m{\ell}$ which was 0.7 times more efficient than the antimelanogenic effect of commercial arbutin and kojic acid (36.5%) also did not show cell toxicity. Additionally, AN-SLP inhibited the activity of ${\alpha}$-glucosidase and the glycosylation of tyrosinase in melanoma cell. The resulting unsaturated glycosylation of tyrosinase makes it unstable and disturb correct transportation. From theses results, we conclude that AN-SLP could be used as anti-melanogenic agent for skin whitening.

Changes in Physico-chemical and Microbiological Parameters during Active Composting of Cattle Manure (우분 퇴비화의 주발효과정 중 이화학적 및 미생물학적 파라미터의 변화)

  • Kim, Yoon Seok;Kang, Myoung Kyu;Bae, Kyung Sook;Lee, Kyu Seung;Rhee, Young Ha
    • Korean Journal of Microbiology
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    • v.33 no.4
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    • pp.267-273
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    • 1997
  • Various physico-chemical and microbiological parameters of a composting system were compared with respect to their potential use for the monitoring and evaluation of composting processes for cattle manure. The temperature changed within a range of $30-65^{\circ}C$ during the whole composting process, and the period of active composting (>$40^{\circ}C$) persisted for 16 days. The concentrations of total carbon, total nitrogen, and organic matter decreased by 15% during active composting, but significant changes in C/N ratio were not observed. The decrease of temperature in the latter period of active composting caused a decrease of $NH_4^+-N$ and an increase of $NO_3^--N$ in the composting pile. When temperature exceeded $50^{\circ}C$, the population of thermophiles was higher than that of mesophiles by more than 1 or 2 orders of magnitude. Correlation analyses showed that amylase activity correlated positively with the population of mesophiles and reducing sugar content, but negatively with the population of thermophiles. Amylase activity was higher at the beginning of active composting, whereas cellulase, xylanase and ligninase activities which showed close relationship with each other, increased continually during active cornposting, suggesting the distinction of temporal niches between amylose-degrading and lignocellulose-degrading bacteria in the same habitat.

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Evaluation of Effective Dose and Exposure Level of Radon in Process Handling NORM (인산석고 취급공정에서의 라돈농도 및 유효선량 수준 평가)

  • Chung, Eun Kyo;Jang, Jae Kil;Kim, Jong Kyu;Kim, Joon Beom;Kwon, Jiwoon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.28 no.3
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    • pp.283-291
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    • 2018
  • Objectives: To monitor the radon concentration level in plants that handle phosphorus rock and produce gypsum board and cement, and evaluate the effective dose considering the effect of radon exposure on the human body. Methods: Airborne radon concentrations were measured using alpha-track radon detectors (${\alpha}$-track, Rn-tech Co., Korea) and continuous monitors (Radon Sentinel 1030, Sun Nuclear Co., USA). Radon concentrations in the air were converted to radon doses using the following equation to evaluate the human effects due to radon. H (mSv/yr) = Radon gas concentration x Equilibrium factor x Occupancy factor x Dose conversion factor. The International Commission on Radiological Protection (ICRP) used $8nSv/(Bq{\cdot}hr/m^3)$ as the dose conversion factor in 2010, but raised it by a factor of four to $33nSv/(Bq{\cdot}hr/m^3)$ in 2017. Results: Radon concentrations and effective doses in fertilizer manufacturing process averaged $14.3(2.7)Bq/m^3$ ($2.0-551.3Bq/m^3$), 0.11-0.54 m㏜/yr depending on the advisory authority and recommendation year, respectively. Radon concentrations in the gypsum-board manufacturing process averaged $14.9Bq/m^3$ at material storage, $11.4Bq/m^3$ at burnability, $8.1Bq/m^3$ at mixing, $10.0Bq/m^3$ at forming, $8.9Bq/m^3$ at drying, $14.7Bq/m^3$ at cutting, and $10.5Bq/m^3$ at shipment. It was low because it did not use phosphate gypsum. Radon concentrations and effective doses in the cement manufacturing process were $23.2Bq/m^3$ in the stowage area, $20.2Bq/m^3$ in the hopper, $16.8Bq/m^3$ in the feeder and $11.9Bq/m^3$ in the cement mill, marking 0.12-0.63 m㏜/yr, respectively. Conclusions: Workers handling phosphorous gypsum directly or indirectly can be assessed as exposed to an annual average radon dose of 0.16 to 2.04 mSv or 0.010 to 0.102 WLM (Working Level Month).