• Title/Summary/Keyword: $^1H-\

Search Result 66,668, Processing Time 0.075 seconds

Effects of Cultivation Conditions on the Growth and Polyamine Composition in Methylobacterium extorquens AM1 Growing on Methanol (Methylobacterium extorquens AM1의 메탄올을 이용한 성장과 세포내 폴리아민 구성에 미치는 배양조건의 영향)

  • 엄치용;박기정;강빈구;김영민
    • Korean Journal of Microbiology
    • /
    • v.29 no.6
    • /
    • pp.387-391
    • /
    • 1991
  • Methylobacterium extorquens AM1 growing on methanol as a sole source of carbon and energy was found to grow most rapidly (t$t_{d}$ =6h) at 30.deg.C in a mineral medium (pH 7.0) containing 0.5% (v/v) methanol which was agitated at 200 rpm (optimal cultivation condition). Cells grown under the optimal cultivation condition contained more spermidine, but less putrescine, than the cells grown on 2.5%(v/v) ( $t_{d}$ =8h ) or at 20.deg.C ( $t_{d}$ =8h ). Cells cultivated under the optimal condition was found to contain more spermidine than the cells grown at pH 6.0 (( $t_{d}$ =7h ) and pH 8.0 ($t_{d}$ =7.3h). the cells growing at the stationary phase under the optimal condition accumulated more spermine or putrescine than the cells growing at the same phase on 2.5%(v/v) methanol or at pH 6.0 and pH 8.0, respectively. M. extorquens AM1 grown in a medium agitated at 100 rpm ( $t_{d}$ =8.8h ) contained less spermidine and spermine than the cells grown under the optimal cultivation condition.

  • PDF

Synthesis of Isopropyldichlorosilane by Direct Process

  • Lim, Weon-Cheol;Cho, Joo-Hyun;Han, Joon-Soo;Yoo, Bok-Ryul
    • Bulletin of the Korean Chemical Society
    • /
    • v.28 no.10
    • /
    • pp.1661-1664
    • /
    • 2007
  • Direct reaction of elemental silicon with a gaseous mixture of isopropyl chloride (1) and hydrogen chloride in the presence of copper catalyst using a stirred bed reactor equipped with a spiral band agitator gave isopropyldichlorosilane having a Si-H bond (2a) as a major product and isopropyltrichlorosilane (2b) along with chlorosilanes, trichlorosilane and tetrachlorosilane. A process for production of 2a was maximized using the 1:0.5 mole ratio of 1 to HCl and smaller size of elemental silicon at a reaction temperature of 220 °C. When a reaction was carried out by feeding a gaseous mixture of 1 [12.9 g/h (0.164 mol/h)] and HCl [2.98 g/h (0.082 mol/h)] to a contact mixture of elemental silicon (360 g) and copper (40 g) under the optimum condition for 45 h, 2a among volatile products kept up about 82 mol % until 35 h and then slowly decreased down 68 mol % in 45 h reaction. Finally 2a was obtained in 38% isolated yield (based on 1 used) with an 85% consumption of elemental silicon in a 45 h reaction. In addition to 2a, 2b was obtained as minor product along with chlorosilanes, trichlorosilane, and tetrachlorosilane. The decomposition of 1 was suppressed and the production of 2a improved by adding HCl to 1.

Effects of simulated acid rain on seed germination of several floricultural crops. (산성(酸性)비가 몇가지 초화류(草花類) 종자(種子)의 발아(發芽)에 미치는 영향(影響))

  • Lee, Jae-Seog;Kim, Jung-Sook
    • Korean Journal of Environmental Agriculture
    • /
    • v.13 no.2
    • /
    • pp.168-174
    • /
    • 1994
  • The experiments were performed to examine the effects of simulated acid rain (pH 1.0${\sim}$5.0) prepared by mixing sulfuric acid and nitric acid at the ratio of 3 : 1 on germination and growth of seedlings of some floricultural crops. Days to germination showed a one to three days' interval among crops, but pH level did not show any effect on germination for each crop. All seeds used in this experiment did not germinate at pH 1.0. At pH 2.0, the flowering cabbage and geranium still did not germinate, and even though the radicles of seeds were germinated, root hairs did not develop. The length of hypocotyls and radicles appeared to be significantly different according to the pH levels.

  • PDF

A genome-wide association study (GWAS) for pH value in the meat of Berkshire pigs

  • Park, Jun;Lee, Sang-Min;Park, Ja-Yeon;Na, Chong-Sam
    • Journal of Animal Science and Technology
    • /
    • v.63 no.1
    • /
    • pp.25-35
    • /
    • 2021
  • The purpose of this study is to estimate the single nucleotide polymorphism (SNP) effect for pH values affecting Berkshire meat quality. A total of 39,603 SNPs from 1,978 heads after quality control and 882 pH values were used estimate SNP effect by single step genomic best linear unbiased prediction (ssGBLUP) method. The average physical distance between adjacent SNP pairs was 61.7kbp and the number and proportion of SNPs whose minor allele frequency was below 10% were 9,573 and 24.2%, respectively. The average of observed heterozygosity and polymorphic information content was 0.32 ± 0.16 and 0.26 ± 0.11, respectively and the estimate for average linkage disequilibrium was 0.40. The heritability of pH45m and pH24h were 0.10 and 0.15 respectively. SNPs with an absolute value more than 4 standard deviations from the mean were selected as threshold markers, among the selected SNPs, protein-coding genes of pH45m and pH24h were detected in 6 and 4 SNPs, respectively. The distribution of coding genes were detected at pH45m and were detected at pH24h.

Studies on the Pulp Bleaching for Reducing AOX(I) - The Pulp Bleaching Method Using A and $D_{(H/L)}$ Treatment - (AOX 감소를 위한 새로운 표백법 (제1보) - A처리 및 $D_{(H/L)}$ 처리를 이용한 표백법 -)

  • 윤병호;김기선;이선호
    • Journal of Korea Technical Association of The Pulp and Paper Industry
    • /
    • v.29 no.1
    • /
    • pp.52-61
    • /
    • 1997
  • This study was aimed to decrease AOX(Adsorbed Organic Halide Compounds) by applying bleaching methods of A(HNO$_3$ + NaNO$_2$) and $D^{(H/L)}$(dual pH chlorine dioxide bleaching) to conventional OCEDED bleaching stages. And so we investigate the effects of NSA treatment and the influence of production rate of ion species in chlorine dioxide and pulp mixtures according to various pH as well as dual pH on pulp bleaching. Finally the effects of AOC_DED^{(H/L)}ED^{(H/L)}$ bleaching stage were investigated by measuring AOX, brightness, kappa number and viscosity of pulps. A stage was treated by using 4% $HNO_3$ and 0.05~2.0% $NaNO_2$ on pulp and $D^{(H/L)}$ stage was like that pulp mixed with chlorine dioxide solution was adjusted at pH 7.0 and reacted in pulp cosistency 3%, S~20min, $70^{\circ}C$, and then successively for 160~175min at pH 4.0. It was found that suitable $NaNO_2$ addition rate was at 0.6% where the brigtness of pulp was most higher and pulp viscosity was not decreased much. Chlorate ($CIO_3$) was decreased according to pH increase but chlorite($CIO_2$) was highly decreased according to pH increase. And chloride was slightly increased with pH increase. The applying of A and D^{(H/L)}$ bleaching stages to some various multiple bleaching stages ($AOC_DED^{(H/L)}/EopD^{(H/L)} etc.$) had good results that brightness was increased more 2~3% ISO than conventional method(OCEDEopD), but viscosity was dropped by only 1~2cps.

  • PDF

The NMR Assignments of Torilin from Torilis japonica

  • Kang, Sam-Sik;Lee, Eun-Bang;Kim, Tae-Hee;Kim, Kyung-Ran;Jung, Jee-Hyung
    • Archives of Pharmacal Research
    • /
    • v.17 no.4
    • /
    • pp.284-286
    • /
    • 1994
  • A guaian type sesquiterpene, torilin, was isolated from the hexane extract of the fruits of Torilis japonica. The $^1H{\;}and{\;}^{13}C-sinals$ of this compound have been fully assigned utilizing $^1H-^1H$ COSY, HMQC, and HMBC experiments.

  • PDF

Status of and Factors Influencing Vaccination against the Pandemic (H1N1) 2009 Virus among University Students from the Fields of Nursing and Allied Health (일 지역 보건계열 대학생의 신종인플루엔자 A (H1N1) 예방접종 실태 및 영향 요인)

  • Kim, Og-Son
    • Journal of Korean Academy of Nursing
    • /
    • v.41 no.3
    • /
    • pp.403-410
    • /
    • 2011
  • Purpose: This study was to identify the current status of vaccination against the pandemic (H1N1) 2009 virus among university students from the fields of nursing and allied health from a local community and verify factors influencing vaccination. Methods: The study included 227 students in the fields of nursing and allied health from a provincial university. Data were obtained from these participants between May 31 and June 11, 2010 by using self-report questionnaires. Results: The rate of vaccination against the pandemic (H1N1) 2009 virus for these participants was 14.5%. No difference was observed in this regard between majors and school year. Factors that influence vaccination against this virus included previous vaccination against seasonal influenza and participants’ attitudes toward general vaccination. Conclusion: The results suggest that for effective pandemic (H1N1) 2009 vaccination of university students from the fields of nursing and allied health, students who have not been vaccinated should be intensively managed. Developing a vaccination program that encourages a positive attitude toward vaccination is recommended.

A Case of Novel Influenza A (H1N1) Virus Pneumonia Complicated Pnemomediastinum and Subcutenous Emphysema

  • Kim, Yu-Jin;Kyung, Sung-Young;Park, Jung-Woong;Jeong, Sung-Hwan;Seo, Yiel-Hea;Lee, Sang-Pyo
    • Tuberculosis and Respiratory Diseases
    • /
    • v.70 no.2
    • /
    • pp.155-159
    • /
    • 2011
  • Recently, a novel influenza A (H1N1) has been recognized as the cause of a worldwide respiratory infection outbreak. Although the symptoms of a novel influenza A (H1N1) are usually mild, the disease can cause severe illness and death. A complication of novel influenza A (H1N1) is pneumomediastinum, a rarely reported condition. We report a case of influenza A (H1N1) complicating pneumomediastinum with subcutaneous emphysema, which had initially presented with blood tinged sputum and chest pain. In addition, we demonstrate bronchoalveolar lavage in influenza A (H1N1).

pH Measurement Using Isosbestic Point of Indicator (지시약의 등흡광점을 이용한 용액의 pH 측정)

  • Won-Hyung Choi;Ho-Jang Hur
    • Journal of the Korean Chemical Society
    • /
    • v.33 no.2
    • /
    • pp.203-207
    • /
    • 1989
  • The methyl red stock solution was added to sample solution and the absorbance values of this solution were measured at the maximum absorption wavelengths of the acidic form, the basic form, and the isosbestic point of the indicator. From the measurements of absorbance, the pH of this solution was calculated. The range of absorbance at the isosbestic point was maintained within 0.1 ${\sim}$ 0.3. The error of pH measurement was within ${\pm}0.08$ pH unit in the pH range of sample solution of $pK_I{\pm}1$.

  • PDF