• 제목/요약/키워드: $^1H$-relaxation

검색결과 249건 처리시간 0.032초

$LaGaO_3$:$Eu^{3+}$형광체의 합성 및 발광 특성 (Synthesis and Anaiysis of Photohnninescence Properties of $^5D_1$$^7F_1$ Transition in $LaGaO_3$:$Eu^{3+}$ Red Phosphor)

  • 김경화;최윤영;손기선;김창해;박희동;최세영
    • 대한화학회지
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    • 제44권5호
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    • pp.453-459
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    • 2000
  • 최근 정보 표시 소자로 전계 방출 표시 소자(FED),PDP.LCD 등이 주목받고 있다. 음극선 발광 형광체는 FED뿐만 아니라 형광 표시판(VFD) 등이 중요한 핵심 소자이다. 따라서 본 연구에서는 FED에 응용 가능한 새로운 모체 탐색을 시도하였고 $LaGaO_3$모체에 $Eu^{3+}$를 첨가한 적색 형광체를 합성하여 광 특성을 분석하였다. $Eu^{3+}$의 농도에 따른 발광 스펙트럼, 여기 스펙트럼과 잔광 시간 곡선을 통해 $LaGaO_3$: $Eu^{3+}$의PL거동을 규명하였다. 잘 알려진 $Eu^{3+}$ 캐스캐이딩(cascading)과 다중 음향 양자(multiphonon emisson)에 의한 cross-relaxation은 $LaGaO_3$: $Eu^{3+}$ 형광체에서도 확인되었다. 또한, Inokutti-Hirayama식으로 부터 결정된 $Eu^{3+}$ 사이의 다중극자 상호 작용(multipolar interaction)유형은 이중 극자 상호 작용(dipole-dipole interaction)으로 밝혀졌다. 본 연구를 통해 $^5D_0$ 전이의 직접 소광 기구(direct quenching mechanism)를 새롭게 제안하였다. 소광 유형은 농도에 의존하며, 0.2몰 이하에서는 확산 율속 단계에 의한 소광 현상이 우세하다가 0.3몰 이상 부터는 $^5D_0$에서 전하 이동 띠(Charge Transfer Band,CTB)로 전이되는 직접 소광 유형이 지배적이다. 음극선 거동은 800V의 가속 전압하에서 여기시켜 측정하였고, PL거동과 같이 0.125몰일때 가장 큰 615nm의 발광 휘도를 나타내었다.

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Cu55Zr30Ti10Pd5 비정질 합금의 기계적 거동 (Mechanical Properties of a Cu55Zr30Ti10Pd5 Bulk Amorphous Alloy)

  • 최원욱;;김형섭;홍순익
    • 한국재료학회지
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    • 제15권4호
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    • pp.281-284
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    • 2005
  • Room and high temperature deformation behaviors of Cu-Zr-Ti-Pd bulk metallic glasses produced by copper mold casting were investigated. The addition of Pd was shown to enhance the glass forming ability and thermal stability of Cu-Zr-Ti base bulk metallic glass. The compressive strength of $Cu_{55}Zr_{30}Ti_{10}Pd_5$ bulk metallic glass was 2230 MPa with 1.8 plastic strain. The stress overshoot and yield drop phenomenon were observed below $487^{\circ}C$ and a drastic decrease in the flow stress was observed at $487^{\circ}C$. The stress overshoot is thought to be associated with stress-induced structural relaxation.

The bimodal regulation of vascular function by superoxide anion: role of endothelium

  • Demirci, Buket;McKeown, Pascal P.;Bayraktutan DVM, Ulvi
    • BMB Reports
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    • 제41권3호
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    • pp.223-229
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    • 2008
  • Reactive oxygen species (ROS) are implicated in vascular homeostasis. This study investigated whether ${O_2}^{\cdot^-}$, the foundation molecule of all ROS, regulates vasomotor function. Hence, vascular reactivity was measured using rat thoracic aortas exposed to an ${O_2}^{\cdot^-}$ generator (pyrogallol) which dose-dependently regulated both $\alpha$-adrenergic agonist-mediated contractility to phenylephrine and endothelium-dependent relaxations to acetylcholine. Pyrogallol improved and attenuated responses to acetylcholine at its lower (10 nM - 1 ${\mu}M$) and higher (10 - 100 ${\mu}M$) concentrations, respectively while producing the inverse effects with phenylephrine. The endothelial inactivation by L-NAME abolished acetylcholine-induced vasodilatations but increased phenylephrine and KCl-induced vasoconstrictions regardless of the pyrogallol dose used. Relaxant responses to sodium nitroprusside, a nitric oxide donor, were not affected by pyrogallol. Other ROS i.e. peroxynitrite and $H_2O_2$ that may be produced during experiments did not alter vascular functions. These findings suggest that the nature of ${O_2}^{\cdot^-}$-evoked vascular function is determined by its local concentration and the presence of a functional endothelium.

한국산 Arisaema ringens $S_{CHOTT}$의 생약학적 연구 (Pharmacognostical Studies on Korean Arisaema ringens $S_{CHOTT}$)

  • 정명현
    • 생약학회지
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    • 제2권4호
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    • pp.163-172
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    • 1971
  • This paper attempts to observe the histological structure of Korean Arisaema ringens $S_{CHOTT}{'s}$ rhizome, to identify it's constituent and to investigate the pharmacological action with it's alcohol extract. The results are : 1) The inner structure of rhizome on the transverse section is divided into external and internal tissues by the ring of intercellular secretary sac. Raphides of calcium oxalate contained in mucilage cell, collateral vascular bundle, are extremely similar to those contained in Pinellia ternata. 2) The organs of the pistillate Arisaema ringens are larger and more plentiful than those of the staminate Arisaema ringens. The sexual identification is easy in the flowering season. 3) The alkaloid is identified by Meyer reagent as white p.p.t. at pH 2 of sulfuric acid. 4) The saponin is indentified remarkably by means of foaming reaction, Lieberman-Burchard reaction and hemolytic reaction. 5) The effect of alcohol extract on the relaxation of the isolated intestine of the rabbit is remarkably shown at the concentration of $10^{-3}g/ml$. 6) The effect of alcohol extract on the isolated ractus muscle of the frog increases the constructive action of acetylcholine at the concentration of $10^{-3}g/ml$. 7) The effect of alcohol extract on the isolated heart movement of the frog is decreased remarkably at the concentration of $10^{-3}g/ml$. 8) The effect of alcohol extract on the blood pressure of the rabbit is decreased by an interavenous injection of $10^{-3}g/kg$.

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InP Quantum Dot - Organosilicon Nanocomposites

  • Dung, Mai Xuan;Mohapatra, Priyaranjan;Choi, Jin-Kyu;Kim, Jin-Hyeok;Jeong, So-Hee;Jeong, Hyun-Dam
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.191-191
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    • 2012
  • InP quantum dot (QD) - organosilicon nanocomposites were synthesized and their photoluminescence quenching was mainly investigated because of their applicability to white LEDs (light emitting diodes). The as-synthesized InP QDs which were capped with myristic acid (MA) were incompatible with typical silicone encapsulants. Post ligand exchange the MA with a new ligand, 3-aminopropyldimethylsilane (APDMS), resulted in soluble InP QDs bearing Si-H groups on their surface (InP-APDMS) which allow embedding the QDs into vinyl-functionalized silicones through direct chemical bonding, overcoming the phase separation problem. However, the ligand exchange from MA to APDMS caused a significant decrease in the photoluminescent efficiency which is interpreted by ligand induced surface corrosion relying on theoretical calculations. The InP-APDMS QDs were cross-linked by 1,4-divinyltetramethylsilylethane (DVMSE) molecules via hydrosilylation reaction. As the InP-organosilicon nanocomposite grew, its UV-vis absorbance was increased and at the same time, the PL spectrum was red-shifted and, very interestingly, the PL was quenched gradually. Three PL quenching mechanisms are regarded as strong candidates for the PL quenching of the QD nano-composites, namely the scattering effect, Forster resonance energy transfer (FRET) and cross-linker tension preventing the QD's surface relaxation.

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Finite Element Analysis and Measurement on the Release of Residual Stress and Non-linear Behavior in Weldments by Mechanical Loading(I) -Experimental Examination-

  • Jang, K.B.;Yoon, H.S.;Cho, S.M.
    • International Journal of Korean Welding Society
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    • 제2권1호
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    • pp.40-44
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    • 2002
  • Residual stress by welding should be reduced because that decreases the reliability on strength of welded structure. The reason is that the total stiffness of structure decreases by non-linear behavior of weldment under external load. The release of residual stress by mechanical loading and unloading is often performed in the fabrication of box structure for steel bridge. The proper degree of loading and unloading is significant at release method of residual stress by mechanical loading because that degree is changed by material and geometric shape of welded structure. Therefore, the simulation model that could exactly analyze the release of residual stress by mechanical loading is to be necessary. This simulation model should be established on the based of variable and accurate measurement data. In this study, the non-linear behavior of weldments under external loading and unloading, such as the decrease and increase of structure stiffness, was investigated by monitoring of nominal stress and strain. Tensile loading and unloading test under variable load was performed and the proper degree of stress relaxation was measured by sectioning technique using strain gauge.

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자기공명단층촬영장치를 이용한 신경조영영상의 기초연구 (The Feasibility Study of 3-D Magnetic Resonance Neurograms)

  • 문치웅;이수열;임태환
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1993년도 춘계학술대회
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    • pp.28-30
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    • 1993
  • We have investigated the feasibility study, especially for optimal TR, to obtain 3-D MR neurographic imaging (neurograms or nervography) which shows the distribution of peripheral nerve fibers at the human forearm using 4.7 T magnet. To peform a successful formation of MR neurographic imaging, nerve signal should be separated from the other signal comes from surrounding muscle or fat, because nerves are usually embeded in muscle or fat. Generally, it is well known that nerve has shoter T1 value than that of muscle. Thus, repetition time was optimized to maximize the signal intensity defference between the muscel and nerve. We have also used spin-echo(SE) sequence with long echo time($60{\sim}90\;msec$) to enhance the different signal intensity between muscles and pheriperal nerves base on the fact that muscle tissue has longer T2 relaxation lime than that or nerve.

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Ginsenoside Rg1 ameliorates chronic intermittent hypoxia-induced vascular endothelial dysfunction by suppressing the formation of mitochondrial reactive oxygen species through the calpain-1 pathway

  • Fang Zhao;Meili Lu;Hongxin Wang
    • Journal of Ginseng Research
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    • 제47권1호
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    • pp.144-154
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    • 2023
  • Background: As the major pathophysiological feature of obstructive sleep apnea (OSA), chronic intermittent hypoxia (CIH) is vital for the occurrence of cardiovascular complications. The activation of calpain-1 mediates the production of endothelial reactive oxygen species (ROS) and impairs nitric oxide (NO) bioavailability, resulting in vascular endothelial dysfunction (VED). Ginsenoside Rg1 is thought to against endothelial cell dysfunction, but the potential mechanism of CIH-induced VED remains unclear. Methods: C57BL/6 mice and human coronary artery endothelial cells (HCAECs) were exposed to CIH following knockout or overexpression of calpain-1. The effect of ginsenoside Rg1 on VED, oxidative stress, mitochondrial dysfunction, and the expression levels of calpain-1, PP2A and p-eNOS were detected both in vivo and in vitro. Results: CIH promoted VED, oxidative stress and mitochondrial dysfunction accompanied by enhanced levels of calpain-1 and PP2A and reduced levels of p-eNOS in mice and cellular levels. Ginsenoside Rg1, calpain-1 knockout, OKA, NAC and TEMPOL treatment protected against CIH-induced VED, oxidative stress and mitochondrial dysfunction, which is likely concomitant with the downregulated protein expression of calpain-1 and PP2A and the upregulation of p-eNOS in mice and cellular levels. Calpain-1 overexpression increased the expression of PP2A, reduced the level of p-eNOS, and accelerated the occurrence and development of VED, oxidative stress and mitochondrial dysfunction in HCAECs exposed to CIH. Moreover, scavengers of O2·-, H2O2, complex I or mitoKATP abolished CIH-induced impairment in endothelial-dependent relaxation. Conclusion: Ginsenoside Rg1 may alleviate CIH-induced vascular endothelial dysfunction by suppressing the formation of mitochondrial reactive oxygen species through the calpain-1 pathway.

시간지연을 가지는 비선형 상호연결시스템의 견실비약성 $H_{\infty}$ 분산 퍼지모델 제어기법 (Robust and Non-fragile $H_{\infty}$ Decentralized Fuzzy Model Control Method for Nonlinear Interconnected System with Time Delay)

  • 김준기;양승협;권영신;방경호;박홍배
    • 전자공학회논문지SC
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    • 제47권6호
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    • pp.64-72
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    • 2010
  • 본 논문에서는 폴리토프 불확실성과 시간지연, 그리고 제어기 섭동을 가지는 비선형 상호연결시스템의 상태궤환 제어기에 대한 견실비약성 $H_{\infty}$ 분산 퍼지제어기 설계 방법을 다룬다. 먼저 시간지연을 가지는 비선형 상호연결시스템을 Takagi-Sugeno 퍼지모델로 나타내고, 이로부터 지연종속 견실비약성 $H_{\infty}$ 퍼지제어기가 존재하기 위한 충분조건, 제어기 설계방법 및 비약성을 만족하는 제어기의 꽉찬집합(compact set)을 제시한다. 이 때 제시한 조건은 변수치환과 슈어여수(Schur complement)정리를 통해 선형행렬부등식(LMI: Linear Matrix Inequality)의 계수가 꽉찬 집합 내의 파라미터의 함수로 정의되는 파라미터화 선형행렬부등식(PLMIs: Parameterized Linear Matrix Inequalities)으로 표현되며, 이를 완화기법(relaxation technique)를 사용하여 유한개의 선형행렬부등식으로 변환하고, 제어기와 비약성을 만족하는 제어기 영역을 구한다. 마지막으로 예제와 모의실험을 통해 불확실성과 시간지연, 제어기이득 섭동에도 불구하고 제안한 퍼지제어기가 폐루프시스템을 안정화시키고 외란감쇠를 보장함을 확인한다.

침지저장액에 따른 두부의 물성 변화에 관한 연구 (Studies on the physical properties of soybean curd stored in the solution of different salt concentration)

  • 장원영;신동훈;김병용
    • Applied Biological Chemistry
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    • 제38권2호
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    • pp.135-140
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    • 1995
  • 여러 소금농도$(0{\sim}5%)$에 따라 만든 침지액에 침지한 두부를 여러 저장온도$(5{\sim}25^{\circ}C)$에서 저장하는 동안, 침지액의 화학적 변화 및 두부 조직 변화를 측정하였다. $0{\sim}3%$의 소금으로 만든 침지액과 비교하여 볼때 5%의 소금으로 만든 두부 침지액에서 pH의 감소가 뚜렷이 억제되었고 탁도 증가율 및 미생물 증가도 억제되었다. 저온$(5^{\circ}C)$에서 저장시 침지액의 pH 변화는 매우 낮게 나타났으나 고온(15, $25^{\circ}C$)에서 저장시 pH는 초기 급격히 감소하였으나, 24시간 후 다시 증가함을 나타내었다. 또한 $5^{\circ}C$에서 저장시 침지액의 탁도변화는 매우 억제됨을 알 수 있었다. 조직 변화를 나타내는 초기 응력변화$({\sigma}_{/0})$, 탄성성분(E), 점성성분$({\eta})$과 파손강도 등은 침지액의 농도에 상관없이 거의 일정하게 나타났으며, 저장온도에 따라 급격히 조직 변화가 일어났다. 관능시험결과 단단함과 짠맛에 대해서만 시료간에 유의차를 나타냈고, 소금을 침지액에 첨가시 $1{\sim}5%$까지는 짠맛에 대한 시료간에 유의차를 나타내지 않았다.

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