• 제목/요약/키워드: $^{95}Nb$

검색결과 136건 처리시간 0.025초

습식방법에 의한 $SnO_2$ 반도체 가스센사 제조 (Preparation of $SnO_2$ Semiconducting Gas Sensor by Wet Process)

  • 전병식;김홍대;최병현;최성근
    • 한국세라믹학회지
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    • 제23권3호
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    • pp.53-61
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    • 1986
  • A gas sensor which has been made by wet process had fabricated by coating each of the mixture on alumina tube and firing at 85$0^{\circ}C$ for 3hrs. A gas concentration such $H_2$, CO, $C_3H_8$, $C_2H_2$ and $CH_4$ vs its detection voltage characteristics has been in-vestigated on $SnO_2-In_2O_3-MgO$ system doped with PdO, $La_2O_3$, $ThO_2$, NiO and $Nb_2O_5$ The optimum sensitivity composition for various gases were 90w/o $SnO_2$-9w/o $In_2O_3$-1w/o MgO for $H_2$, $C_2H_2$ CO and $C_3H_8$ and 95w/o $SnO_2$-4w/o $In_2O_3$-1w/o MgO for $CH_4$. The sample which has been made by wet process than dry process had predominated sensitivity for each gases and particle size of the sample coprecipitated with PH=9 was 0.1${\mu}{\textrm}{m}$ The $SnO_2$-In2_O_3-MgO$ system doped with 2w/o $Nb_2O_5$ and NiO was the most sensitive for $H_2$ and $C_2H_2$ gas. In $SnO_2$-In2_O_3-MgO$ system doped with $ThO_2$ the sensitivity of $H_2$ gas was decreased but CO gas was in-creased when dopant con was increased.

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디스크형 압전변압기의 전극비에 따른 전기적 특성 (A Electrical Characteristics of Disk-type Piezotransformer with Electrode Ratio of Driving and Generating Part)

  • 이종필;채홍인;정수현;홍진웅
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제52권10호
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    • pp.458-463
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    • 2003
  • In order to develope piezoelectric transformer for the ballast of fluorescent lamp, a new shape and electrode pattern of piezoelectric transformer has been investigated in this work. The composition of piezoelectric ceramics was 0.95Pb(Zr$_{0.51}$Ti$_{0.49}$)O$_3$+0.03Pb(Mn$_{1}$3/Nb$_{2}$3/)O$_3$+0.02Pb(Sb$_{1}$2/Nb$_{1}$2/)O$_3$. The sample prepared by this composition system showed the characteristics which has about 1200 of relative dielecric constant, 1100 of the mechanical quality factor, 0.53 of the electromechanical coupling coefficient, 320 pC/N of the piezoelectric constant d$_{33}$, 0.3 % of the dissipation factor. Diameter and thickness of disk-type piezoelectric transformer was 45 mm and 4 mm, respectively. The driving and generating electrode with their gap of 1mm were fabricated on the top surface. But the common electrode was fabricated on the whole bottom surface. The electrode surface ratio of driving and generating part on the top surface ranges from 1.4:1 to 3:1. We investigated the electrical characteristics with the variation of the electrode surface ratio of driving and generating part in the range of load resistance of 100 $\Omega$~70 k$\Omega$. The set-up voltage ratio of this piezoelectric transformer increases with increasing both the electrode surface of driving part and the load resistance. The set-up voltage ratio at no load resistance was more than 60 times. On the other hand, the efficiency decreases with increasing the electrode surface of driving part. In the case of the electrode surface of both 1.4:1 and 2:1, maximum efficiency showed above 97 % at load resistance of 2 k$\Omega$. However, in the case of the electrode surface of 3:1, maximum efficiency showed about 94 % at load resistance of 3 k$\Omega$.>.>.>.

PCFN-PZW계의 마이크로파 유전 특성에 미치는 Pb계 Flux의 영향 (Effect of Pb based flux on the Microwave Dielectric Properties of PCFN-PZW System)

  • 강동헌;설충의;차훈주;김영호;길상근;조봉희
    • 한국전기전자재료학회논문지
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    • 제15권12호
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    • pp.1027-1032
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    • 2002
  • (Pb$\_$0.4/Ca$\_$0.6/)(Fe$\_$1/2/Nb$\_$1/2/)O$_3$ system was modified by 10 mol% Pb(Zn$\_$1/2/W$\_$1/2/)O$_3$ addition and their sinterability and microwave properties were investigated as a function of the amount of flux (0.975PbO-0.025SnO$_2$). With increasing flux content, single perovskite phase was maintained up to 3 wt% flux addition and further addition led to the presence of Pb-rich second phase which was confirmed by EDS analysis. The apparent densities of PCFN-PZW specimen increased and showed maximum values at 2.5 wt% flux addition for the Ts=1000$^{\circ}C$ and 2.0wt% flux addition for the Ts=1050$^{\circ}C$, respectively. The dielectric constant and Q$.$f values strongly depended on the variation of density and microstructure, where the optimum values of $\varepsilon$$\_$r/ = 91.95, Q$.$f = 5938GHz, TCF = +8.15ppm/$^{\circ}C$ were obtained for the 2.5wt% flux added PCFN-PZW specimen sintered at 1000$^{\circ}C$ for 4h.

The Piezoelectric Properties of (Na0.5K0.5)NbO3-K5.4Cu1.3Ta10O29 Ceramics with Various K5.4Cu1.3Ta10O29 Doping and Sintering Temperatures

  • Yoon, Jung Rag;Lee, Chang-Bae;Lee, Serk Won;Lee, Heun-Young
    • Transactions on Electrical and Electronic Materials
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    • 제13권6호
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    • pp.283-286
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    • 2012
  • (1-X)$(Na_{0.5}K_{0.5})NbO_3-XK_{5.4}Cu_{1.3}Ta_{10}O_{29}$ (NKN-KCT) lead-free piezoelectric ceramics have been synthesized by the conventional solid state sintering method, and their sinterability and piezoelectric properties were investigated. Typically, this material is sintered between 1,025 and $1,100^{\circ}C$ for 2 hours to achieve the required densification. Crystalline structures and Microstructures were analyzed by X-ray diffraction and scanning electron microscope. The density, dielectric constant (${\varepsilon}_r$), piezoelectric constant $d_{33}$, electromechanical coupling factor $k_p$ and mechanical quality factor $Q_m$ value of the NKN ceramics depended upon the KCT content and the sintering temperature. In particular, the KCT addition to NKN greatly improved the mechanical quality factor $Q_m$ value. The ceramic with X = 1.0 mol% sintered at $1,050^{\circ}C$ exhibited optimum properties (${\varepsilon}_r$=246, $d_{33}$=95, $k_p$=0.38 and $Q_m$=1,826). These results indicate that the ceramic is a promising candidate material for applications in lead free piezoelectric transformer and filter materials.

PLD법으로 제작된 xPb(Al0.5Nb0.5)O3-(1-x)Pb(Zr0.52Ti0.48)O3박막의 유전 및 압전 특성 (Dielectric and Piezoelectric Properties of xPb(Al0.5Nb0.5)O3-(1-x)Pb(Zr0.52Ti0.48)O3 Thin films Prepared by PLD)

  • 김민철;박용욱;최지원;강종윤;안병국;김현재;윤석진
    • 한국전기전자재료학회논문지
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    • 제16권9호
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    • pp.795-800
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    • 2003
  • The dielectric and piezoelectric properties of the xPb(A $l_{0.5}$N $b_{0.5}$) $O_3$-(1-x)Pb(Z $r_{0.52}$ $Ti_{0.48}$) $O_3$ [xPAN-(1-x)PZT] thin films by pulsed laser deposition (PLD) were investigated as a function of PAN contents. The effect of texture on dielectric and piezoelectric properties of the 0.05PAN-0.95PZT thin films having the highest piezoelectric constant( $d_{33}$) was studied more precisely. For 0$\leq$x$\leq$0.15 compositions in xPAN-(1-x)PZT thin films, the well-developed perovskite phase with (111) preferred orientation was obtained at the deposition temperature of 50$0^{\circ}C$. With increasing PAN content, remanent polarization and coercive field decreased. The dielectric constant increased with an increase of PAN content until it reached 1450 at $\chi$= 0.05, and then decreased for higher PAN content. The maximum points of dielectric constant coincides with the maximum points of the piezoelectric constant $d_{33}$.33/.33/././.

국내 희토류자원의 수급, 부존현황 및 자원잠재성 (Situation of the Supply-demand and Potentiality of REE Resources in South Korea)

  • 고상모
    • 한국광물학회지
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    • 제22권4호
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    • pp.417-422
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    • 2009
  • 국내에는 충주 어래산 광화대와 홍천 광화대에 대한 탐사 결과 약 4,600,000 톤의 자원량을 확보하였으나 시추량의 제한에 따른 자원량의 부족과 낮은 가격으로 인해 경제성이 없는 것으로 잠정적으로 판단된 바 있다. 그러나 최근 희토류 가격이 2000년대 초에 비해 2~3배까지 상승하였으며 최저개발 품위가 REO 2%대로 낮아짐으로써 두 광화대에 대한 체계적인 정밀탐사를 통하여 보다 정확한 자원평가가 요구된다. 이 두 지역은 REE 뿐만 아니라 Fe, Sr 등이 수반됨으로써 그 잠재적인 가치를 높일 수 있을 것으로 판단된다. 하동 광화대는 Ti외 REE와 Li의 추출이 가능하여 경제성을 상승시킬 수 있을 것으로 판단된다. 양양 광화대는 Zr-Nb-REE 광화대로 알려져 있으나 체계적 탐사가 수행되지 않아 자원량의 산정은 수행되지 않았으나 REE 외 희유금속인 Nb을 수반하여 그 잠재적인 가치가 높다고 판단된다. 국내 REE 자원탐사는 체계적이고 계획적인 탐사가 진행 된 적이 없어 단일 광상에 대해 정확한 매장량 산정이나 경제성 분석 등이 이루어지지 않아 그 가치 판단이 모호함으로써 개발에 제한을 가지고 있다. 세계적인 수요량이 현재 REO 100,000톤에서 2013년에는 거의 200,000톤으로의 증가가 전망되고, Eu의 가격은 2000년 중반에 비해 최근 2배 상승하였으며, Dy의 가격은 3배 이상 급상승 추세에 있어 대부분 희토류 산화물 가격은 점차 증가될 것으로 전망한다. 전 세계 희토류 생산의 95%를 중국이 독점하고 있어 자원이 1개국에 편재된 극히 좋지 않은 자원환경으로 세계 각국에서 희토류 탐사에 전념하고 있는 실정이다. 아울러 하이브리드 카 생산이 증대되면 중국만이 생산하는 중희토류의 수요가 급증하여 가격 상승과 함께 수급에 차질이 있을 것으로 추측된다. 따라서 국내 희토류 자원에 대한 체계적이고 단계적인 중장기적 탐사를 통하여 REE 자원을 확보하여 개발한다면 국내 REE 자원의 수급을 원활히 할 수 있을 것으로 기대된다.

Pb($Zn_{1/3}Nb_{2/3}$)$O_3$-Pb($Zr_{x}Ti_{1-x}$)$O_3$ 세라믹의 구조적, 초전 특성 (Structure and Pyroelectrical Properties of Pb($Zn_{1/3}Nb_{2/3}$)$O_3$-Pb($Zr_{x}Ti_{1-x}$)$O_3$Compound Ceramics)

  • 조현무;이성갑;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 추계학술대회 논문집
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    • pp.543-546
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    • 2000
  • Ferroeleclric 0.05PZN-xPZT(90/10)-(0.95-x)PZT(10/90) (x=0.65, 0.85) specimens were fabricated by the mixed-oxide method and cold-pressing method using sol-gel derived PZT(90/10) and PZT(10/90) powders. All specimens show a uniform ferroelectric grain without the presence of the pyrocholre phase. Average grain size increased with an increase in sintering temperature, the value for the x=0.65 specimen sintered at 125$0^{\circ}C$ was 14.4$\mu$m. The dielectric constant and dielectric loss of the x=0.65 specimen sintered at 125$0^{\circ}C$ were 1247, 2.06%, respectively. All specimens showed fairly good temperature and frequency stability of dielectric constant with the range from -2$0^{\circ}C$ to 6$0^{\circ}C$ and 100Hz to 10MHz. The coercive field and the remanent polarization of x = 0.65 specimen sintered at 125$0^{\circ}C$ were 8.5 kV/cm and 13 $\mu$C/cm$^2$, respectively. The pyroelectric coefficient of the x=0.65 specimen sintered at 125$0^{\circ}C$ was 5.64$\times$10$^{-8}$ C/cm$^2$K, respectively.

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Traffic-Oriented Stream Scheduling for 5G-based D2D Streaming Services

  • Lee, Chong-Deuk
    • 한국컴퓨터정보학회논문지
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    • 제27권10호
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    • pp.95-103
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    • 2022
  • 5G 이동통신 서비스가 점차 확대되어감에 따라 P2P 또는 D2D 응용에서 유튜부 비디오 스트리밍과 같은 트래픽 지향의 스트림 제어가 중요한 기술로 떠오르고 있다. 특히 D2D 통신에서 사용자들이 가장 많이 전송하는 데이터 스트림의 타입은 비디오 스트림이며, 이것은 대용량의 전송 스트림의 특징을 가지고 있다. D2D 통신환경에서 이런 종류의 스트림은 트래픽 혼잡의 원인을 제공할 뿐만 아니라 또한 DUE들 간의 서비스 품질을 저하시킨다. 본 논문에서는 비디오 스트림과 같은 동적 미디어 스트림의 끊김현상을 최소화하고 스트리밍 서비스 품질을 최적화하기 위해 TOSS 기법을 제안한다. 제안된 기법은 5G gNB 환경하의 3.5GHz와 28GHz의 대역폭상에서 미디어 스트림의 특성과 트래픽 타입을 분석하여 미디어 스트림을 스케줄링한다. 우리는 시뮬레이션을 통하여 제안된 기법의 성능을 알아보며, 시뮬레이션 결과는 제안된 기법이 다른 비교 기법들에 비해서 성능이 보다 우수함을 보인다.

X-선과 중성자 회절을 이용한 강유전체 단결정 $LiN(D_xH_{1-x}){_4}SO_4$의 결정구조 연구 (Crystal Structure Analysis of $LiN(D_xH_{1-x}){_4}SO_4$ by X-ray and Neutron Diffraction)

  • 김신애;김성훈;소지용;이정수;이창희
    • 한국광물학회지
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    • 제20권4호
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    • pp.351-356
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    • 2007
  • 수소원자를 포함한 강유전체 $Li(NH_4)SO_4$의 중수소 치환형인 $Li(ND_4)SO_4$ 단결정에 대해 X-선과 중성자 회절법으로 결정구조를 연구하였다. 이 결정은 상온에서 사방정계이고 공간군은 $P2_1nb$이다. 격자상수는 $a=5.2773(5)\;{\AA},\;b=9.1244(23)\;{\AA},\;c=8.7719(11)\;{\AA}$이며 Z=4이다. 한국원자력연구원의 연구용 원자로인 하나로에 설치된 중성자 4축 단결정 회절장치로 중성자데이터를 수집하였으며, X-선 회절데이터는 일본 동북대학교 물리학과에서 측정하였다. X-선 회절법으로 수집한 1450개의 독립 회절반점에 대하여 최소자승법으로 정밀화하여 최종 신뢰도값 R=0.070을 얻었으며, 중성자 회절법으로는 745개의 회절반점에 대하여 R=0.049을 얻었다. X-선 회절데이터 분석 결과 결정구조 내의 수소원자 중 1개의 위치만을 얻었으나, 중성자 회절법으로는 $NH_4$ 사면체의 수소/중수소원자의 위치는 물론 H를 치환해서 들어간 D의 점유율을 정련하여 측정시료의 평균화학식이 $LiND_{3.05}H_{0.95}SO_4$임을 밝혔다.

사향소합원(麝香蘇合元)이 정서반응성(情緖反應性)과 Alzheimer's disease 모델 백서(白鼠)의 학습(學習)에 미치는 영향(影響) (The Effects of Sahyangsohapwon on the Affective Reactivity and the Acquisition of Two-way avoidance in AD Model Rats)

  • 홍대성;김종우;황의완
    • 동의신경정신과학회지
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    • 제10권1호
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    • pp.17-38
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    • 1999
  • The effects of Sahyangsohapwon on the affective reactivity of rats were studied with open-field behavior. Sample group was treated with the medicine for 8 weeks, whereas control group was treated with the vehicle. The effects of Sahyangsohapwon on the enhancement of learning and memory of AD model rats were studied with two-way avoidance task. Sample group electrically lesioned on nbM(nucleus basalis of Meynert) was treated with the medicine for 8 weeks, whereas control group with nbM lesion and sham group with the sham operation were treated with the vehicle. 1. In the open-field behavior task, the start latency from start box was measured $27.08{\pm}7.51sec$ in control group, $23.15{\pm}5.98sec$ in sample group. Rats in sample group showed a tendency of shortened latency going out to a strange place compared with those in control group, but with no statistical significance(p>0.05). 2. In the open-field behavior task, the number of locomotion crossing the grid lines was measured $84.54{\pm}3.55$ in control group, $116.93{\pm}6.41$ in sample group. There was an increased locomotion in sample group compared with control group with statistical significance(p<0.01). This can be interpreted as rats in sample group showed lowerd anxiety under a strange environment. 3. In the open-field behavior task, the rearing number was measured $7.46{\pm}0.57$ in control group, $10.13{\pm}0.95$ in sample group. There was an increased rearing in sample group compared with control group with statistical significance(p<0.05). This can also be interpreted as rats in sample group showed lowerd anxiety under a strange environment. 4. In the open-field behavior task, the number of crossing behavior was measured $5.54{\pm}1.50$ in control group, $9.20{\pm}1.67$ in sample group. There was a increasing tendency of crossing behavior in sample group compared with control group, but with no statistical significance(p<0.05). 5. In the open-field behavior task, the total activity was measured $97.54{\pm}4.70$ in control group, $136.27{\pm}792$ in sample group. There was an increased total activity in sample group compared with control group with statistical significance(p<0.01). This can also be interpreted as rats in sample group showed lowerd anxiety under a strange environment. 6. In the analysis of effects on the learning and memory in AD model rats with two-way avoidance task, the response latency was measured $6717{\pm}134msec$ in the 1st session, $5416{\pm}160msec$ in the 2nd session, $5252{\pm}148msec$ in the 3rd session in control group. It was measured $6724{\pm}155msec$ in the 1st session, $4642{\pm}139msec$ in the 2nd session, $4914{\pm}148msec$ in the 3rd session in sample group and $4357{\pm}144msec$ in the 1st session, $3125{\pm}115msec$ in the 2nd session, $3091{\pm}98msec$ in the 3rd session in sham group. There were differences between sham group and nbM lesioned groups with statistical significance in post hoc analysis(p<0.000). And in the 2nd session, there was a reduction of latency in sample group compared with control group with statistical significance (p<0.000). This showed that sample group had better learning capacity than control group. 7. In the analysis of effects on the learning and memory in AD model rats with two-way avoidance task, the number of avoidance response was measured $5.85{\pm}1.41$ in the 1st session, $14.23{\pm}2.89$ in the 2nd session, $15.69{\pm}2.56$ in the 3rd session in control group. It was measured $7.92{\pm}1.94$ in the 1st session, $16.83{\pm}2.29$ in the 2nd session, $15.42{\pm}2.81$ in the 3rd session in sample group and $14.38{\pm}1.62$ in the 1st session, $22.88{\pm}0.89$ in the 2nd session, $23.88{\pm}1.64$ in the 3rd session in sham group. There were differences between sham group and nbM lesioned groups with statistical significance in post hoc analysis(p<0.001). But between control and sample group, there was no significant difference. With the experimental results above, Sahyangsohapwon can be supposed to have the enhancing effects on the affect reactivity and learning with memory of AD model rats induced by electrolyte injury of nbM.

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