• Title/Summary/Keyword: $^{36}Cl$

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Removal of Alkali Metal Ion and Chlorine Ion Using the Ion Exchange Resin (이온교환수지를 이용한 알칼리 금속 이온 및 염소 이온의 제거)

  • Lee, Kyung-Han;Kil, Bo-Min;Ryu, Cheol-Hwi;Hwang, Gab-Jin
    • Membrane Journal
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    • v.30 no.4
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    • pp.276-281
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    • 2020
  • A research was conducted on the removal of ion from the solution involving the alkali metal ion and chlorine ion using ion exchange resin. The cation exchange resin and anion exchange resin was used for the remove of metal ion (Na+ and K+) and chlorine ion (Cl-), respectively. In the case of solution A (involving 36,633 ppm of Na+ and 57,921 ppm of Cl-), the Na+ ion and Cl- ion were removed over 99% within 20 min. In the case of solution B (involving 1,638 ppm of K+), the K+ ion was removed over 99% within 3 min.

Studies on Gold Balsam (금발삼에 관한 연구)

  • 박용완;김충일
    • Journal of the Korean Ceramic Society
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    • v.11 no.4
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    • pp.31-36
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    • 1974
  • For gold balsam, the suitable sulfur balsam which is made of lavender oil and sulfur is found to be the distillate with the content of 15~19% sulfur. The sulfur balsam is distillated under 20mmHg vaccum at 84~105$^{\circ}C$. The composition of the compound which is produced by reaction between sulfur balsam and gold chloride is recognized as C10H18SAuCl3. This varys to C10H18SAuCl in water. The reaction constants K from C10H18SAuCl3 to C10H18SAuCl at 30, 40, 5$0^{\circ}C$ are as followsr. K1=7.97~9.28$\times$10-2 K2=2.81~3.79$\times$10-1 K3=4.74~6.74$\times$10-1 The plots of T versus log K are linear, which shows pseudo-first order reaction. The lower temperature is, the more stable C10H18SAuCl3 is. The gold balsam with excess sulfur balsam is increased in stability.

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Comparative Assessment on Indicating Factor for Biomineralization by Bacillus Species (Bacillus종의 생광물화에 미치는 영향 인자의 비교 평가)

  • Seok, Hee-Jeong;Kim, Chang-Gyun
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.3
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    • pp.179-191
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    • 2013
  • This study was conducted to comparatively assess quantitative indicating factor for biomineralization characterizing $CO_2$ mineralization on three type of minerals (i.e., $CaCl_2$, $MgCl_2$, $CaCl_2-MgCl_2$) in an aqueous solution amended with Bacillus pasteurii or indigenous microorganisms for a S landfill cover soil. For given three types of minerals, $NH_4{^+}$ (urease activity) was released at the highest of 88 mg/L for $MgCl_2$, then 85 mg/L for $CaCl_2$, and the lowest of 42 mg/L for $CaCl_2-MgCl_2$. $CO_2$ gas in the head space was completely removed after 12, 12, and 24 hr for $CaCl_2$, $MgCl_2$ and $CaCl_2-MgCl_2$, respectively. $Ca^{2+}$ concentration in $CaCl_2$ solution was the quickest and the greatest decreased 92% for 12 hr whereas that in $CaCl_2-MgCl_2$ solution was lower at 85% for 36 hr. $Mg^{2+}$ concentration in $MgCl_2$ was more efficiently decreased at 46% for 48 hr than that of $CaCl_2-MgCl_2$ solution of 38.5% for 72 hr. Regardless of types of minerals or their concentration, pH was changed from 5.5 to 9 by biomineralization being progressed. Microbial activity ($OD_{600}$) was also changed from 0 to 0.6. SEM images indicated that spheroidal and trapezoid shape crystal were formed, which were identified as of $CaCO_3$ (Calcite) and $MgCO_3$ (Magnesite) by X-ray diffraction. In the long run, $NH_4{^+}$ (urease activity), $CO_2$ gas, $OD_{600}$, pH, $Ca^{2+}$ and $Mg^{2+}$ would be suitable for reasonable indicating factor in order to assess the degree of biomineralization efficiency.

Effects of Antioxidant Activity and Changes in Vitamin C during Storage of Lycii folium Extracts Prepared by Different Cooking Methods (조리방법을 달리한 구기엽의 저장기간별 항산화 효과 및 비타민 C 함량의 변화)

  • Kim, Tae-Su;Park, Won-Jeong;Kang, Myung-Hwa
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.36 no.12
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    • pp.1578-1582
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    • 2007
  • Contents in polyphenol and vitamin C and their antioxidant activities during storage of Lycii folium prepared by different treatment methods were investigated. The antioxidant activity of extracts prepared from 80% MeOH was evaluated using DPPH radical scavenging and SOD-liked activities. Total phenolic acid contents were 1.34 mg/mL when dry, but extracts during 15-day storage after NaCl 0% treatment decreased. DPPH radical scavenging activity of extracts was 65.48% when dry and decreased during 15-day storage after dry and NaCl 0% treatment. SOD-liked activity was 98.63% in NaCl 0% during 15-day storage after dry. Contents of vitamin C decreased during 15-day storage after dry and NaCl 0% treatment. Consequently, our results indicate that Lycii folium prepared from dry treatment could be a promising biomaterial for the production of functional food for total phenolic acid and vitamin C.

Synthesis and Characterization of Palladium (IV) Complexes with Guanine, Adenine, and Uracil Base (Guanine, Adenine 및 Uracil 염기를 갖는 팔라듐 (IV) 착물의 합성과 그 성질)

  • Oh Sang Oh;Chung Duck Young;Kim Hee Seon
    • Journal of the Korean Chemical Society
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    • v.36 no.5
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    • pp.679-684
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    • 1992
  • New Pd(IV) complexes have been prepared through the reactions of $trans-[Pd(en)_2Cl_2](ClO_4)_2 $(en = ethylenediamine) with Guanine, Adenine, or Uracil anion as purine and pyrimidine base. We identified the ratio of central metal versus ligands by $C{\cdot}H{\cdot}N$ elemental analysis and proposed the coordinating site of the base by infrared spectrum, $^1H-NMR,\; and\; ^{13}C$-NMR spectrum. Guanine or Adenine ligand coordinated at N7 site and an en ligand exchanged for $ClO_4^-$ counter ions of the starting material . As these results, the complexes showed the formula $[Pd(en)L_2(ClO_4)_2](ClO_4)_2{\cdot}(en)$, (L = Guanine, Adenine). But in the Uracil complex no exchange of the en ligand and $ClO_4^-$ occured and Uracil anion preferred the N1 to N3 as coordinating site, the complex $[Pd(en)_2(Urac)_2](ClO_4)_2(Urac = Uracil anion).$

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Effect on the change of ginsenosides, pH and color by NaCl concentration (NaCl 농도가 인삼의 ginsenoside 함량과 pH 및 색의 변화에 미치는 영향)

  • Park, Myung-Han;Lee, Jong-Won;Lee, Jong-Tae;Kim, Kyo-Chang
    • Applied Biological Chemistry
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    • v.36 no.4
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    • pp.260-264
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    • 1993
  • In order to determine the stability of ginseng components in this salt concentration when used to ginseng as additive ingredient of sauces or seasonings, we study on the content and charactristic of ginsenosides and changes in pH and color, ginseng tail and ginseng extract were treated with various concentration of NaCl solution. In this experiment, extract of ginseng tail were increased in pH as NaCl concentration were increased, but ginseng extract have not changed evidently. The both solution were decreased in color as the salt concentration were increased. Yield of n-butanol extract was decreased in 5% NaCl concentration, while it was increased in the above concentration, and ginseng extract was changed higher than ginseng tail. Ginsenosides content were increased in 5% NaCl concentration, both $ginsenosied-Rb_1$, $-Rb_2$, -Rc, -Rd of diol line and ginsenoside-Re of triol line and increased in above NaCl concentration. Especially ginsenoside-Re showed to sensitive response to the changes of the salt concentration.

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THE EFFECT OF OXYGEN ON PERCHLORATE REDUCTION IN A BIOFILM REACTOR

  • Choi, Hyeok-Sun
    • Environmental Engineering Research
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    • v.12 no.4
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    • pp.148-154
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    • 2007
  • The purpose of this research was to investigate the effects of low concentration of oxygen on reduction of perchlorate, especially low perchlorate influent concentrations in a biofilm reactor, as well as the effect of flow pattern in a biofilm reactor. Dissolved oxygen averaging 1 mg/L did not inhibit reduction of influent perchlorate from 23 to $426\;{\mu}g/L$ in the biofilm reactors when sufficient acetate was added, probably due to limitation of oxygen diffusion into the biofilm. Influent perchlorate ranging from 23 to $426\;{\mu}g/L$ was reduced to below detection level ($4\;{\mu}g/L$) in the presence of 1 mg/L dissolved oxygen (DO). Chloride was produced in a ratio of $0.37gCl^-/g{ClO_4}^-$ and $0.35gCl^-/g{ClO_4}^-$ in plug flow and recirculation biofilm reactor which is similar to stoichiometric amount ($0.36gCl^-/g{ClO_4}^-$) indicating complete perchlorate reduction at $426\;{\mu}g/L$ of ${ClO_4}^-$ feeding. At $23\;{\mu}g/L$L influent perchlorate, total biomass solids were 3.18 g and 2.81 g in the plug flow and recirculation biofilm reactors. The most probable number(MPN) analysis for perchlorate-reducing bacteria showed $10^4$ to $10^5\;cells/cm^2$ in both biofilm reactors throughout the experiments. The effluent perchlorate concentrations were not significantly different in the two different flow regimes, plug flow and recirculation biofilm reactors.

An Efficient Method for Co-purification of Eggshell Matrix Proteins OC-17, OC-116, and OCX-36

  • Zhang, Maojie;Wang, Ning;Xu, Qi;Harlina, Putri Widyanti;Ma, Meihu
    • Food Science of Animal Resources
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    • v.36 no.6
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    • pp.769-778
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    • 2016
  • In this study, we improved the eggshell-membrane separation process by separating the shell and membrane with EDTA solution, evaluating effects of three different extraction solutions (acetic acid, EDTA, and phosphate solution), and co-purifying multiple eggshell proteins with two successive ion-exchange chromatography procedures (CM Sepharose Fast Flow and DEAE Sepharose Fast Flow). The recovery and residual rates of eggshell and membrane separated by the modified method with added EDTA solution were 93.88%, 91.15% and 1.01%, 2.87%, respectively. Ovocleidin-116 (OC-116) and ovocalyxin-36 (OCX-36) were obtained by loading 50 mM Na-Hepes, pH 7.5, 2 mM DTT and 350 mM NaCl buffer onto the DEAE-FF column at a flow rate of 1 mL/min, ovocleidin-17 (OC-17) was obtained by loading 100 mM NaCl, 50 mM Tris, pH 8.0 on the CM-FF column at a flow rate of 0.5 mL/min. The purities of OCX-36, OC-17 and OC-116 were 96.82%, 80.15% and 73.22%, and the recovery rates were 55.27%, 53.38% and 36.34%, respectively. Antibacterial activity test suggested that phosphate solution extract exhibited significantly higher activity against the tested bacterial strains than the acetic acid or EDTA extract, probably due to more types of proteins in the extract. These results demonstrate that this separation method is feasible and efficient.

A Study on pH and Soluble Reactive Phosphorus (SRP) from Litter Using Various Poultry Litter Amendments During Short-Term: A Laboratory Experiment (다양한 깔짚 첨가제 이용이 단 기간 깔짚내 pH와 수용성 인에 미치는 영향에 관한 연구)

  • Choi, In-Hag;Yi, Seong-Joon;Kim, Chang-Mann
    • Journal of Environmental Science International
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    • v.17 no.2
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    • pp.233-237
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    • 2008
  • The objective of this study was conducted to evaluate the effects of poultry litter amendments on pH and soluble reactive phosphorus (SRP) in poultry litter. Two laboratory studies were conducted for 42 d in Exp. 1 and for 10 d in Exp. 2, respectively. The poultry litter was treated with various amendments which included 4 g fly ash and 4 g $AlCl_3\;(AlCl_36H_2O)/100g$ litter in Exp. 1 and 4 g alum$(Al_2(SO_4){_3}\;14H_2O)$, 8 g alum, 8.66 g liquid alum, and 17.3 g liquid alum/100 g litter in Exp. 2; untreated litter served as controls. There were no differences in pH between control and T1(4 g fly ash) and SRP contents between T1(4 g fly ash) and T2(4 g $AlCl_3$) in Exp. 1. A significant difference in pH and SRP contents in Exp. 2 was observed among all treatments(P< 0.05). In experiment 1, T1(4 g fly ash) and T2(4 g $AlCl_3$) at 42 d decreased SRP in litter by 47.1% and 62.6% of that from litter alone, respectively. In experiment 2, T1(4 g alum), T2(8.66 g liquid alum), T3(8 g alum), and T4(17.3 g liquid alum) treatments at 10 days reduced SRP contents by up to 36.2%, 62.9%, 87.0%, and 83.9%, respectively, when compared with the controls. Decrease in SRP contents was chiefly associated with reduction in litter pH. These results indicate that use of various litter amendments to limit P solubility has potential and should be pursued as a means of reducing soluble reative phosphorus during short term.

DNA recombinase Rad51 is regulated with UV-induced DNA damage and the DNA mismatch repair inhibitor CdCl2 in HC11 cells

  • You, Hyeong-Ju;Kim, Ga-Yeon;Kim, Seung-Yeon;Kang, Man-Jong
    • Journal of Animal Reproduction and Biotechnology
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    • v.36 no.3
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    • pp.121-128
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    • 2021
  • Increasing the efficiency of HR (homologous recombination) is important for a successful knock-in. Rad51 is mainly involved in homologous recombination and is associated with strand invasion. The HR-related mismatch repair system maintains HR fidelity by heteroduplex rejection and repair. Therefore, the purpose of this study is to control Rad51, which plays a critical role in HR, through UV-induced DNA damage. It is also to confirm the effect on the expression of MMR related genes (Msh2, Msh3, Msh6, Mlh1, Pms2) and HR-related genes closely related to HR through treatment with the MMR inhibitor CdCl2. The mRNA expression of Rad51 gene was confirmed in both HC11 cells and mouse testes, but the mRNA expression of Dmc1 gene was confirmed only in mouse testes. The protein expression of Rad51 and Dmc1 gene increased in UV-irradiated HC11 cells. After 72 hours of treatment with 1 ㎛ of CdCl2, the mRNA expression level of Msh3, Pms2, and Rad51 decreased, but the mRNA expression level of Msh6 and Mlh1 increased in HC11 cells. There was no significant difference in Msh2 mRNA expression between CdCl2 untreated-group and the 72 hours treated group. In conclusion, HR-related gene (Rad51) was increased by UV-induced DNA damage. Treatment of the MMR inhibitor CdCl2 in HC11 cells decreased the mRNA expression of Rad51.