• 제목/요약/키워드: $\pi-Complex$

검색결과 287건 처리시간 0.025초

Design of Space Search-Optimized Polynomial Neural Networks with the Aid of Ranking Selection and L2-norm Regularization

  • Wang, Dan;Oh, Sung-Kwun;Kim, Eun-Hu
    • Journal of Electrical Engineering and Technology
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    • 제13권4호
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    • pp.1724-1731
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    • 2018
  • The conventional polynomial neural network (PNN) is a classical flexible neural structure and self-organizing network, however it is not free from the limitation of overfitting problem. In this study, we propose a space search-optimized polynomial neural network (ssPNN) structure to alleviate this problem. Ranking selection is realized by means of ranking selection-based performance index (RS_PI) which is combined with conventional performance index (PI) and coefficients based performance index (CPI) (viz. the sum of squared coefficient). Unlike the conventional PNN, L2-norm regularization method for estimating the polynomial coefficients is also used when designing the ssPNN. Furthermore, space search optimization (SSO) is exploited here to optimize the parameters of ssPNN (viz. the number of input variables, which variables will be selected as input variables, and the type of polynomial). Experimental results show that the proposed ranking selection-based polynomial neural network gives rise to better performance in comparison with the neuron fuzzy models reported in the literatures.

The Expanding Significance of Inositol Polyphosphate Multikinase as a Signaling Hub

  • Kim, Eunha;Ahn, Hyoungjoon;Kim, Min Gyu;Lee, Haein;Kim, Seyun
    • Molecules and Cells
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    • 제40권5호
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    • pp.315-321
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    • 2017
  • The inositol polyphosphates are a group of multifunctional signaling metabolites whose synthesis is catalyzed by a family of inositol kinases that are evolutionarily conserved from yeast to humans. Inositol polyphosphate multikinase (IPMK) was first identified as a subunit of the arginine-responsive transcription complex in budding yeast. In addition to its role in the production of inositol tetrakis- and pentakisphosphates ($IP_4$ and $IP_5$), IPMK also exhibits phosphatidylinositol 3-kinase (PI3-kinase) activity. Through its PI3-kinase activity, IPMK activates Akt/PKB and its downstream signaling pathways. IPMK also regulates several protein targets non-catalytically via protein-protein interactions. These non-catalytic targets include cytosolic signaling factors and transcription factors in the nucleus. In this review, we highlight the many known functions of mammalian IPMK in controlling cellular signaling networks and discuss future challenges related to clarifying the unknown roles IPMK plays in physiology and disease.

Dynamic Rapid Synthesis of Bis(2,2'-bipyridine)nitrato Zinc (II) Nitrate Using a Microwave Method and its Application to Dye-Sensitized Solar Cells (DSSC)

  • Kim, Young-Mi;Kim, Su-Jung;Nahm, Kee-Pyung;Kang, Mi-Sook
    • Bulletin of the Korean Chemical Society
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    • 제31권10호
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    • pp.2923-2928
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    • 2010
  • This study examined the synthesis of the crystal structure of bis(2,2'-bipyridine)nitrato zinc (II) nitrate, $[Zn(bipy)_2(NO_3)]^+NO_3^-$ using a microwave treatment at 300 W and 60 Hz for the application to dye-sensitized solar cells. The simulated complex structure of the complex was optimized with the density functional theory calculations for the UV-vis spectrum of the ground state using Gaussian 03 at the B3LYP/LANL2DZ level. The structure of the acquired complex was expected a penta-coordination with four nitrogen atoms of bipyridine and the oxygen bond of the $NO_3^-$ ion. The reflectance UV-vis absorption spectra exhibited two absorptions (L-L transfers) that were assigned to the transfers from the ligand ($\sigma$, $\pi$) of $NO_3$ to the ligand ($\sigma^*$, $\pi^*$) of pyridine at around 200 - 350 nm, and from the non-bonding orbital (n) of O in $NO_3$ to the p-orbital of pyridine at around 450 - 550 nm, respectively. The photoelectric efficiency was approximately 0.397% in the dye-sensitized solar cells with the nanometer-sized $TiO_2$ at an open-circuit voltage (Voc) of 0.39 V, a short-circuit current density (Jsc) of $1.79\;mA/cm^2$, and an incident light intensity of $100\;mW/cm^2$.

Relationship between Spinopelvic Parameters and Hip Function in Patients with Femoroacetabular Impingement at Diagnosis: A Cross-Sectional Study

  • Bernardo Aguilera-Bohorquez;Pablo Corea;Cristina Siguenza;Jochen Gerstner-Saucedo;Alvaro Carvajal;Erika Cantor
    • Hip & pelvis
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    • 제35권1호
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    • pp.6-14
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    • 2023
  • Purpose: The aim of this study was to determine correlation between the spinopelvic parameters in sitting and standing positions (sacral slope [SS], lumbar lordosis [LL], spinopelvic tilt [SPT], pelvic incidence [PI], and pelvic femoral angle [PFA]), with hip function assessed using the modified Harris hip scores (mHHs) in patients with symptomatic femoroacetabular impingement (FAI) at diagnosis. Materials and Methods: A retrospective study of 52 patients diagnosed with symptomatic FAI was conducted. Evaluation of the spinopelvic complex in terms of SS, LL, SPT, PI and PFA was performed using lateral radiographs of the pelvis and lumbosacral spine in standing and sitting positions. Assessment of hip function at diagnosis was performed using the mHHs. Calculation of spinopelvic mobility was based on the difference (Δ) between measurements performed in standing and sitting position. Results: The median time of pain evolution was 11 months (interquartile range [IQR], 5-24 months) with a median mHHs of 66.0 points (IQR, 46.0-73.0) at diagnosis. The mean change of LL, SS, SPT, and PFA was 20.9±11.2°, 14.2±8.6°, 15.5±9.0°, and 70.7±9.5°, respectively. No statistically significant correlation was observed between spinopelvic parameters and the mHHs (P>0.05). Conclusion: Radiological parameters of the spinopelvic complex did not show correlation with hip function at the time of diagnosis in patients with symptomatic FAI. Conduct of further studies will be required in the effort to understand the effect of the spinopelvic complex and its compensatory mechanics, primarily between the hip and spine, in patients with FAI before and after hip arthroscopy.

IMI-O 초박막의 착체농도에 대한 유전 특성 (Dielectric Properties of Complex Cconcentration in IMI-0 Thin Films)

  • 정상범;유승엽;박재철;권영수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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    • pp.345-348
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    • 1999
  • The monolayer behaviors at the air-water interface and the dielectric properties of MI-0 LB films for complex concentration were investigated by the surface pressure-area ($\pi$-A) isotherms and dielectric constant. The molecular area was expanded with increase of metal ions concentration. It is considered that the expansion of molecular area is due to electrostatic repulsion between the polymer chains andhydrophobic increase of ionic strength. In the frequency-dependent complex dielectric constant at room temperature, the real part of dielectric constant($\varepsilon'$) is about 6.0~10.0 in the low-frequency range and is decreasing slowly upto $1O^4$Hz. It decreased abruptly near $1O^5Hz$. It seems to be dielectric dispersion in this frequency range. Also, the imaginary part of dielectric constant ($\varepsilon"$) shows a peak in $1O^5$~$1O^6Hz$. It seems to be dielectric absorption in this frequency range.ange.

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단상 계통 연계형 태양광 인버터에 사용되는 PI 와 PR 전류제어기의 비교 분석 (Comparison of PI and PR Controller Based Current Control Schemes for Single-Phase Grid-Connected PV Inverter)

  • 부우충기엔;성세진
    • 한국산학기술학회논문지
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    • 제11권8호
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    • pp.2968-2974
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    • 2010
  • 태양광 인버터는 계통과 태양광 시스템 사이의 공통 접속점에 고조파, 플리커, 고주파 노이즈가 없는 고품질 전력을 공급하는 핵심적인 역할을 한다. 일반적으로 비례-적분 (PI: Proportional Integral) 제어기는 정상상태 오차와 낮은 외란 제거 능력으로 인하여 교류 계통에서 만족할만한 성과를 얻지 못하나, 현장에서 이득 설정이 용이하므로 일반적으로 전압형 인버터 (VSI)에서 이용된다고 알려져 있다. 이 논문에서는 산업계에서 일반적으로 사용되는 비례-적분 제어기와 교류 계통의 상용주파수에서의 무한대의 이득 값을 가지며, 정상상태 에러 발생을 제거하며, 정지 좌표계에서 구현할 수 있는 비례-이득 (PR: Proportional Resonant) 제어기의 동작 원리, 설계 기법 등을 비교 분석하였다. PI와 PR 제어기의 분석 결과를 시뮬레이션과 실험을 통하여 그 타당성을 증명하였다. 두 제어기는 32-비트 고정소수점 연산을 하는 TMS320F2812 DSP 프로세서를 이용하여 구현하였고, 3kW 실험용 프로토타입 태양광 인버터를 제작하여 그 성능을 확인하였다.

대식세포의 Fc 수용체를 통한 탐식에 미치는 Inositol-phosphatase의 영향 (Effect of Inositol-phosphatase on Fc Receptor-mediated Phagocytosis of Macrophages)

  • 김종현
    • IMMUNE NETWORK
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    • 제5권3호
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    • pp.144-149
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    • 2005
  • Background: Fc receptor-mediated phagocytosis is a complex process involving the activation of kinases and phosphatases. FcgammaRIIB has been known to transduces inhibitory signals through an immunoreceptor tyrosine-based inhibitory motif (ITIM) in cytoplasmic domains. In this study, we examined the involvement of inositol-phosphatase in the Fc receptor-mediated phagocytosis. Methods: J774 cells were infected using vaccinia viral vector containing SH2 domain-containing inositol-phosphatase (SHIP) cDNA and stimulated with the sensitized sheep red blood cells. Results: Stimulation of J774 cells induced the tyrosine phosphorylation of SHIP which was maximal at 5 minutes. Phosphatidylinositol-3 (PI-3) kinase inhibitor (wortmannin) inhibits J774 cell phagocytosis of sensitized sheep red blood cells in a dose-dependent manner. Heterologious expression of SHIP in J774 cells inhibits phagocytosis of sensitized sheep red blood cells in a dose-dependency manner, but catalytically dead mutants of SHIP has no effect on phagocytosis. Conclusion: These results strongly suggest that the active signals mediated by PI-3 kinase are opposed by inhibitory signals through SHIP in the regulation of Fc receptor-mediated phagocytosis.

뉴로-퍼지 제어기 설계 연구 (A Study on a Neuro-Fuzzy Controller Design)

  • 임정홈;정태진
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 하계학술대회 논문집 D
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    • pp.2120-2122
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    • 2002
  • There are several types of control systems that use fuzzy logic controller as a essential system component. The majority of research work on fuzzy PID controller focuses on the conventional two-input PI or PD type controller. However, fuzzy PID controller design is a complex task due to the involvement of a large number of parameters in defining the fuzzy rule base. In this paper we combined conventional PI type and PD type fuzzy controller and set the initial parameters of this controller from the conventional PID controller gains obtained by Ziegler-Nichols tuning or other coarse tuning methods. After that, by replacing some of these parameters with sing1e neurons and making them to be adjusted by back-propagation learning algorithm we designed a neuro-fuzzy controller which showed good performance characteristics in both computer simulation and actual application.

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니코틴의 배치와 형태에 관한 분자궤도론적 연구 (제1보) (MO Studies on Nicotine (I))

  • 이익춘;박동환
    • 대한화학회지
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    • 제22권4호
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    • pp.195-201
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    • 1978
  • 니코틴과 그 양성자 부가물의 배치 및 형태를 분자궤도론으로 EHT와 CNDO/2방법을 써서 연구하였다. 가장 안정한 형태는 피롤리딘 고리가 $280^{\circ}$회전된 꼴임을 알았으며 이것을 콘쥬게이션, 정전기적 및 입체효과로서 설명하였다. 양성자의 부가는 피리딘 고리에 일어나며 일종의 ${\pi}$-착물이 형성됨을 알았다.

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Phenol과 DMA 간의 수소결합 (Intermolecular Hydrogen Bond between Phenol and DMAs)

  • 김복혜;이익춘
    • 대한화학회지
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    • 제10권1호
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    • pp.15-17
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    • 1966
  • Phenol과 각 종 Dimethylaniline(DMA)간의 수소결합을 Infrared Spectrophotometer로 연구하였다. 일반으로 DMA는 n-donor 및 ${\pi}$-donor의 2중 역활을 하나 주로 n-donor로 작용하며 phenol의 O-H stretching frequency의 shift(${\Delta}{\nu}$)는 DMA의 basicity에 비례하였고 (${\Delta}{\nu}$) 와 Hammett의 σcontant사이에는 linearity가 성립함을 알았다.

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