• Title/Summary/Keyword: $\beta$-expansion

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The formation of $\beta$-quartz solid silution in lithiu alumino silicate glasses (Lithium Alumino Silicate계 유리에서 알카리 토류 첨가에 따른 $\beta$-quartz고용체의 형성에 관한 연구)

  • Kim, Byeong-Il;Gang, Won-Ho
    • Korean Journal of Materials Research
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    • v.4 no.6
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    • pp.611-619
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    • 1994
  • The formation of , $\beta$-quartz solid solution in the $LiO_2-Al_2O_3-SiO_2$glasses containing $TiO_{2}$ and $ZrO_{2}$ as nucleating agents was investigated for various temperatures and times. Linear thermal expansion coefficients of base glasses and crystallized glasses were $45\sim 55 \times 10^{-7} \textrm{cm}/^{\circ}C$ and $ -8\sim +8 \times 10^{-7}\textrm{cm}/^{\circ}C$ ($25^{\circ}C \sim 525^{\circ}C$), respectively. The crystal phase formed by heat-treatment below $900^{\circ}C$was , $\beta$--quartz solid solution, and the crystal sizes were less than 0.21m. On the other hand, the crystal size of the base glasses containing 3.5 wt% MgO is relatively uniform and is independent with temperature. The specimen containing 3.5 wt% ZnO shows a minimum crystal size(O.l8$\mu \textrm{m}$), and it strongly depends on temperature of heat-treatment.

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Mechanical Properties of the System PbO-B$_2$O$_3$-V$_2$O $_5$Low Melting Glass during Crystallization by Heat-treatment (PbO-B$_2$O$_3$-V$_2$O$_5$계 저융점유리의 열처리에의한 결정화에 따른 기계적 성질)

  • 정창주
    • Journal of the Korean Ceramic Society
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    • v.11 no.3
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    • pp.19-26
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    • 1974
  • Mechanical properties of the system PbO-B2O3-V2O5 low melting glass during crystallization by heat-treatment were investigated. Wettability of the system PbO-B2O3-V2O5 was excellent and appropriate for commercial sealing as a low melting solder glass. Crystals, during heat-treated at 30$0^{\circ}C$ of the system PbO-B2O3-V2O5 were $\beta$-4PbO.B2O3, 5PbO.4B2O3, and Pb2V2O7 mainly. The percent of crystallinity was 82$\pm$5%. Mechanical properties of the system PbO-B2O3-V2O5 were influenced not only by the differences of density and coefficient of thermal expansion and the stress induced from the difference in the density and coefficient of thermal expansion between glass phase and crystals but also crystallization conditions.

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The Crystallization Characteristics Change in $Li_2O$.$Al_2O_3$.$SiO_2$ System Glass-Ceramics when Varying of RO Ratio and Increasing $R_2O_3$ ($Li_2O$.$Al_2O_3$.$SiO_2$ 계 유리에서 RO치환 및 $R_2O_3$ 첨가에 따른 결정화 특성)

  • 이종민;김무경;최병현;양중식
    • Journal of the Korean Ceramic Society
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    • v.22 no.2
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    • pp.3-10
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    • 1985
  • In the study the characteristics change of crystallized $Li_2O$.$Al_2O_3$.$SiO_2$ glass-ceramics when varying RO ratio and increasing Al2O3 were investigated to produce a glass-ceramics with high mechanical strength and low thermal expansion. Parent glass was obtained by melting at 1,350~1,40$0^{\circ}C$ for 3 hours and annealing at 45$0^{\circ}C$ and the various physical characteristics were measured. Results were as follows; 1. When ZnO was replaced by MgO thermal expansion coefficient was lowered when increasing ZnO content. 2. Major crystal phase was $\beta$-spodumene the crystal growth mophology was the three dimensional sphere and the activation energy for crystallization was 54.6 Kcal/mol. 3. Parent glass heat-treated at 95$0^{\circ}C$ for 10 hours had ; a) thermal expansion coeff. of $23.2{\times}10^{-7}$/$^{\circ}C$ b)whiteness of 76 c) microhardness of 1,089kg/$mm^2$

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Biochemical Properties and Physiological Functions of Plant β-D-fructofuranosidase (식물 β-D-fructofuranosidase의 화학적 성질과 생리적 기능)

  • Kim, Donggiun
    • Journal of Life Science
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    • v.27 no.7
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    • pp.849-856
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    • 2017
  • The ${\beta}$-D-fructofuranosidase (EC 3.2.1.26) is an important enzyme from a historical point of view, discovered by French biologist Berthelot in 1860 and was first used to study enzymology. ${\beta}$-D-fructosfuranosidase catalyzes the hydrolysis of sucrose into D-glucose and D-fructose. Four biochemical subgroups of ${\beta}$-D-fructofuranosidase have been investigated in plants. There are vacuolar (soluble acid), cytoplasmic (soluble alkaline), membrane-bound (insoluble alkaline), and cell wall-bound (insoluble acid) ${\beta}$-D-fructofuranosidase by purification. Their biochemical characteristics are distinct. It suggested that those enzymes might be different gene products. The contribution of each of these enzymes to sucrose management in the plant is likely to be correlated with their localization. Common localization in developing cells in tissues from a range of developmental stages and plant parts suggests that all of the isoforms may be closely involved in nutrient transport. The ${\beta}$-D-fructofuranosidases were most commonly found associated with maturing tissues in developing fruits, leaves, and roots. The ${\beta}$-D-fructofuranosidase activity varies in the relationship between growth and expansion through cell division, development of storage organs and tissues, and the relationship of plant defense responses. It is necessary to summarize more researches in order to know the definite physiological function.

A Study on the Large Scale Systems Simplification for computer processing (컴퓨터 처리를 위한 대규모 시스템의 간략법에 관한 연구)

  • 황형수;권오신;이창구
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.36 no.4
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    • pp.280-286
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    • 1987
  • A new method is presented for obtaining redced-order model for time-invariant systems. This method does not require the calculation of the reciprocal transformation, the alpha table, the beta-table and the alpha-beta expansion which should be calculated in Routh approximation method, hence it is computationally very attractive better than Routh approximation method, furthemore the stability of the reduced-order model is guaranted if the original system is stable. This method starts with the continued fraction espansion of auxiliary denominator polynomial give for the denominator polynomial of the reduced-order model. The coefficients of the numerator polynomial are then obtained by equating moment of the original and the reduced-order medel.

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Conversion of 1,3-Thiazolidines to Dihydro-1,4-thiazine by Chlorinolysis

  • Lee, Wha-Suk;Mah, He-Duck;Nam, Kee-Dal;Kang, Soon-Bang
    • Bulletin of the Korean Chemical Society
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    • v.13 no.1
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    • pp.83-87
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    • 1992
  • The ring expansion of 1,3-thiazolidines 4 derived from ${\beta}$-ketoacid derivatives to the corresponding dihydro-1,4-thiazines 1 by using the action of chlorine on 4 has been achieved. In the chlorinolysis unisolable sulfenyl chlorides 5 may be formed from chlorosulfonium ions 11 by ${\beta}$-elimination involving carbonyl activated methylene hydrogens. Addition of sulfenyl chloride to the internal double bond appears to form probable thiiranium ions 14, which in turn gave 1 with loss of acidic proton. Imminium ions 15 could be hydrolyzed easily to give enol 8. As a side reaction, dihydrothiazine that was formed was further chlorinated to produce dichlorides 16 which were rearranged readily to the chloromethyl compounds 10.

A Study on the Crystallization of Grain-Boundary Phases in Si3N4-Y2O3-Al2O3 System (Si3N4-Y2O3-Al2O3계의 입계상 결정화에 관한 연구)

  • 박정현;황종희
    • Journal of the Korean Ceramic Society
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    • v.26 no.1
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    • pp.13-20
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    • 1989
  • After sintering Si3N4 containing 20wt% of variable composition ratio of Y2O3 and Al2O3 at 1$600^{\circ}C$, the specimens were annealed at 125$0^{\circ}C$ and 135$0^{\circ}C$ for 5, 10, 15 hours in order to crystallize the remanining oxynitride glass phases. The main grain-boundary crystalline phases in the Si3N4-Y2O3-Al2O3 system were melilite and YAG. By annealing 15hrs. at 125$0^{\circ}C$, almost all of the glasses were crystallized. During the growth of melilite, lattice volyume of $\beta$-Si3N4 was increased as Al3+ and O2- ions in the oxynitride glass diffuse into $\beta$-Si3N4 lattice, but during the growth of YAG, lattice volume of $\beta$-Si3N4 was decreased by reverse diffusion of Al3+ and O2- ions. In case of crystallization of glass phase to melilite, thermal expansion of sample was decreased, but in case of crystallization to YAG, inverse phenomen on was observed.

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The Relationship Socio-Demographic Characteristic and Campus Life Satisfaction of the Dental Hygiene Students (일부 치위생(학)과 학생들의 인구사회학적 특성과 대학생활 만족도의 관련성)

  • Ryu, Hae-Gyum;Ku, In-Young
    • Journal of Korean Clinical Health Science
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    • v.4 no.3
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    • pp.615-621
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    • 2016
  • Purpose. This study was conducted for provide basic data to improve satisfaction of campus life that investigated survey on the socio-demographic characteristic and campus life stisfaction of the dental hygiene students in Gyeongnam and Busan region. Methods. The research subjects are the total 220 and it was analyzed with structured questionnaires. The collected data was analyzed by IBM SPSS ver. 20.0, a statistical program (IBM Co., Armonk, NY, USA) for the frequency and percentage, ANOVA, Hierachical regression. The result is as following. Results. It was investigated to affected campus life satisfaction by in case of female student(${\beta}=-0.232$), in case of employment preparation(${\beta}=-0.193$), in case of household economical poor status(${\beta}=-0.188$). Conclusions. As the results of the research, it is considered necessary the expansion of the systemized, in order to increase the campus life satisfaction, improvement to the university administration and welfare for the emotion of girl, development program for interview skill and smooth interpersonal relationship, support major costs and living expenses.

The properties of a low expansion glass ceramics of $Li_{2}O-Al_{2}O_{3}-SiO_{2}$ system ($Li_{2}O-Al_{2}O_{3}-SiO_{2}$계 저팽창 결정화 유리의 특성)

  • Kim, Bok-Hee;Ko, Jung-Hoon;Nam, O-Jung;Kang, Woo-Jin;Lee, Chang-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.2
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    • pp.79-83
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    • 2009
  • The glass-ceramic of the $Li_{2}O-Al_{2}O_{3}-SiO_{2}$ system was investigated to develop the low thermal expansion materials. The glass of this system was heat treated at $775^{\circ}C$ for 2 h for nucleation and subsequently at $825{\sim}900^{\circ}C$ for 2 h for crystallization. The crystal structure of the glass-ceramic of this system was a single phase of $\beta$-quartz solid solution($Li_{x}Al_{x}Si_{1-x}O_{2}$). The thermal expansion of the glass-ceramic showed $4.40{\times}10^{-7}{\sim}1.33{\times}10^{-6}K^{-1}$ between $25{\sim}300^{\circ}C$ and $1.56{\times}10^{-6}{\sim}2.53{\times}10^{-6}K^{-1}$ between $25{\sim}800^{\circ}C$, higher than lower temperature range. The mechanical strength remained almost same at around high 110 MPa with heating temperature changes.

Dynamic response of functionally gradient austenitic-ferritic steel composite panels under thermo-mechanical loadings

  • Isavand, S.;Bodaghi, M.;Shakeri, M.;Mohandesi, J. Aghazadeh
    • Steel and Composite Structures
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    • v.18 no.1
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    • pp.1-28
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    • 2015
  • In this paper, the dynamic response of functionally gradient steel (FGS) composite cylindrical panels in steady-state thermal environments subjected to impulsive loads is investigated for the first time. FGSs composed of graded ferritic and austenitic regions together with bainite and martensite intermediate layers are analyzed. Thermo-mechanical material properties of FGS composites are predicted according to the microhardness profile of FGS composites and approximated with appropriate functions. Based on the three-dimensional theory of thermo-elasticity, the governing equations of motionare derived in spatial and time domains. These equations are solved using the hybrid Fourier series expansion-Galerkin finite element method-Newmark approach for simply supported boundary conditions. The present solution is then applied to the thermo-elastic dynamic analysis of cylindrical panels with three different arrangements of material compositions of FGSs including ${\alpha}{\beta}{\gamma}M{\gamma}$, ${\alpha}{\beta}{\gamma}{\beta}{\alpha}$ and ${\gamma}{\beta}{\alpha}{\beta}{\gamma}$ composites. Benchmark results on the displacement and stress time-histories of FGS cylindrical panels in thermal environments under various pulse loads are presented and discussed in detail. Due to the absence of similar results in the specialized literature, this paper is likely to fill a gap in the state of the art of this problem, and provide pertinent results that are instrumental in the design of FGS structures under time-dependent mechanical loadings.