• Title/Summary/Keyword: $\alpha$-$Fe_{2}O_{3}$

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Specualr spin valve with nano-oxide layer (나노 oxide 층을 가진 스펙큘라 스핀밸브)

  • Kim, K.Y.;Kim, H.J.;Jang, S.H.;Kang, T.
    • Proceedings of the Korean Magnestics Society Conference
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    • 2002.12a
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    • pp.30-31
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    • 2002
  • 100 Gbit/in$^2$ 이상의 자기기록밀도를 달성하기 위해서는 재생헤드로 사용되고 있는 스핀밸브의 자기저항비가 10% 이상을 가지면서 열적 특성이 우수해야 한다. 현재까지 연구되어진 스핀밸브 구조 중 NiO([,2,3], $\alpha$-Fe$_2$O$_3$[4]등의 산화물 반강자성 층을 사용한 스핀밸브의 경우 기본 스핀밸브 구조를 사용하고도 이미 20% 이상의 자기저항비를 달성하였다. 이러한 높은 자기저항비는 절연층인 산화물 반강자성층과 금속 자성층 계면에서 일어나는 전자의 스펙큘라 반사(specular reflection)로부터 기인한다고 보고하고 있다.[2] (중략)

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Direct Electrochemistry and Electrocatalysis of Myoglobin with CoMoO4 Nanorods Modified Carbon Ionic Liquid Electrode

  • Zhao, Zengying;Cao, Lili;Hu, Anhui;Zhang, Weili;Ju, Xiaomei;Zhang, Yuanyuan;Sun, Wei
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.475-481
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    • 2013
  • By using ionic liquid 1-hexylpyridinium hexafluorophosphate ($HPPF_6$) based carbon ionic liquid electrode (CILE) as the substrate electrode, a $CoMoO_4$ nanorods and myoglobin (Mb) composite was casted on the surface of CILE with chitosan (CTS) as the film forming material to obtain the modified electrode (CTS/$CoMoO_4$-Mb/CILE). Spectroscopic results indicated that Mb retained its native structures without any conformational changes after mixed with $CoMoO_4$ nanorods and CTS. Electrochemical behaviors of Mb on the electrode were carefully investigated by cyclic voltammetry with a pair of well-defined redox peaks from the heme Fe(III)/Fe(II) redox center of Mb appeared, which indicated that direct electron transfer between Mb and CILE was realized. Electrochemical parameters such as the electron transfer number (n), charge transfer coefficient (${\alpha}$) and electron transfer rate constant ($k_s$) were estimated by cyclic voltammetry with the results as 1.09, 0.53 and 1.16 $s^{-1}$, respectively. The Mb modified electrode showed good electrocatalytic ability toward the reduction of trichloroacetic acid in the concentration range from 0.1 to 32.0 mmol $L^{-1}$ with the detection limit as 0.036 mmol $L^{-1}$ ($3{\sigma}$), and the reduction of $H_2O_2$ in the concentration range from 0.12 to 397.0 ${\mu}mol\;L^{-1}$ with the detection limit as 0.0426 ${\mu}mol\;L^{-1}$ ($3{\sigma}$).

Growth and Characterization of LaAlO$_3$ Single Crystals by the Traveling Solvent Floating Zone Method (Travelin Solvent Floating Zone법에 의한 LaAlO$_3$ 단결정의 성장 및 특성)

  • 정일형;임창성;오근호
    • Journal of the Korean Ceramic Society
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    • v.35 no.3
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    • pp.280-286
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    • 1998
  • LaAlO3 Single crystals used as a substrate for thin film depositions of a high temperature oxide su-perconductor YB2Cu3O7 and applied to microwave frequencies were grown by the Traveling Solvent Flati-ing Zone (TSFZ) method and characterized. For the growth of LaAlO3 single crystals polycrystalline fe-edrods were prepared from powder mixture of La2O3 and Al2O3 with a mole ratio of 1:1 calcined at 110$0^{\circ}C$ for 3h and sintered at 140$0^{\circ}C$ for 4h The growth LaAlO3 crystals was 4-5mm in diameter 30mm in length and dark brown. The growth rate was 2-3mm/h and the rotation speeds were 10rpm for an upper ro-tation and 40 rpm for a lower rotation The growing crystals and the feedrods were counter-rotated. The orientation of the grown single crystals of LaAlO3 was identified to be [111] direction. Dielectric constants were measured to be 30-33 between 100 kHz and 1 MHz in the 30$0^{\circ}C$ to 45$0^{\circ}C$ temperature range and 102 in a range of 100 kHz at the phase transformation temperature of 522$^{\circ}C$ Dielectric losses were calculated to be 1.8$\times$10-4 at the room temperature and 5.7$\times$10-3 at the phase transformation temperature. Lattice con-stants of the grown crystlals were determined to be aR=5.3806 $\AA$ and $\alpha$=60.043$^{\circ}$ by the least square method.

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A Study on the Borided Stsucture of Cast Iron (주철(鑄鐵)의 침붕조직(浸硼組織)에 관(關)한 연구(硏究))

  • Kim, H.S.;Ra, H.Y.
    • Journal of Korea Foundry Society
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    • v.2 no.3
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    • pp.2-15
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    • 1982
  • In this study, the influenced of graphite shape on the boriding of cast iron and boride structure was investigated. Gray cast iron, ferritic and pearlitic ductile cast iron were borided at 750,850,900 and $950^{\circ}C$ for 1,3 and 5 hours by powder pack method with the mixture of $B_4C_9\;Na_2B_4O_7$, $KBF_4$ and Shc. The boride layer was consisted of FeB(little), $Fe_2B$ (main) and graphite. Some possibility of the existence of unknown Fe-B-C compound in the boride layer was suggested. And precipitates in the diffusion zone was $Fe_3(B,C)$. The concentration of Si and precipitation of $Fe_3(B,C)$ in the ${\alpha}$ layer raised the hardness of this Zone. The depth and hardness of boride layer increased with the increase of treating temperature and tim. But high temperature (over $950^{\circ}C)$ caused pore at graphite position and long treating time (5hrs) sometimes caused formation of graphite layer beneath the boride layer. So, for the practical application of borided cast iron, treating in short time and at low temperature was recommended. And for ductile cast iron, ferritizing or pearlitizing heat treatment was seemmed to be possible at the same time with boriding. The graphite in the boride layer was deeply concerned with the qualitx and characteristics of the boride layer. And it greatly influenced on the shape of the boride phase, structure of the boride layer. Generally speaking, the existance of graphite restrained the growth of the boride phase. But the boundary between the gsaphite and the matrix acted as the shortcut of boron diffusion. So, for gray cast iron, the graphite layed length-wise led the formation of boride layer.

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Characterization of Microstructure, Hardness and Oxidation Behavior of Carbon Steels Hot Dipped in Al and Al-1 at% Si Molten Baths

  • Trung, Trinh Van;Kim, Sun Kyu;Kim, Min Jung;Kim, Seul Ki;Bong, Sung Jun;Lee, Dong Bok
    • Korean Journal of Metals and Materials
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    • v.50 no.8
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    • pp.575-582
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    • 2012
  • Medium carbon steel was aluminized by hot dipping into molten Al or Al-1 at% Si baths. After hot-dipping in these baths, a thin Al-rich topcoat and a thick alloy layer rich in $Al_5Fe_2$ formed on the surface. A small amount of FeAl and $Al_3Fe$ was incorporated in the alloy layer. Silicon from the Al-1 at% Si bath was uniformly distributed throughout the entire coating. The hot dipping increased the microhardness of the steel by about 8 times. Heating at $700-1000^{\circ}C$, however, decreased the microhardness through interdiffusion between the coating and the substrate. The oxidation at $700-1000^{\circ}C$ in air formed a thin protective ${\alpha}-Al_2O_3$ layer, which provided good oxidation resistance. Silicon was oxidized to amorphous silica, exhibiting a glassy oxide surface.

Properties of Oxide Systems for NTC Thermistors (산화물계 NTC 서미스터의 특성)

  • Lee, Sung-Kwan;Lee, Hae-Yon;Lee, Sean-Hag;Her, Jeong-Seob;Kim, Hyun-Sik;Oh, Young-Woo
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1855-1857
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    • 1999
  • $Mn_{1-x}Fe_{2+x}O_4$, $Mg_{1-x}Fe_{2+x}O_4$ (x=0.0, 0.025, 0.1, 0.2) for negative temperature coefficient (NTC) thermistor were prepared by calcining at $800^{\circ}C$ and sintering from 1100 to $1250^{\circ}C$ with $50^{\circ}C$ intervals. The best linear property was obtained in the Mn-based sample sintered at $1200^{\circ}C$ with x=0.0 composition. Temperature coefficient of resistance, $\alpha$, was -3.0 %/$^{\circ}C$ in the Mg-based sample at $25^{\circ}C$. Thermistor parameter, B, was in the range of 2500 [K] $\sim$7400 [K]. The results show the possibility that Mn-Ni-Co based thermistor could be substituted by the composition used in this study.

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$\alpha$-D-Glucosidase Inhibitor from Streptomyces sp. (II) -Cultural Conditions for the Inhibitor Production- (Streptomyces 속 균주가 생성하는 $\alpha$-D-Glucosidase Inhibitor(II)-저해물질의 생산조건 -)

  • 도재호;주현규
    • Microbiology and Biotechnology Letters
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    • v.17 no.3
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    • pp.207-212
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    • 1989
  • Cultural conditions for $\alpha$-D-Glucosidase Inhibitor production from Streptomyces sp. YS-221-B isolated from soil arid identified as Streptomyces flauovirens or a subspecies of it were investigated. When the strain was cultured in a flask containing 2% glucose, 0.3% asparagine, 0.0002% riboflavin, 0.05% $K_2$HPO$_4$, 0.1% MgSO$_4$.7$H_2O$, 0.05% NaCl, pH 8.0 at 3$0^{\circ}C$, maximum production of the inhibitor was obtained after 8-9 days of cultivation. Sugar alcohols such as mannitol, i-inositol, erythritol as carbon sources, asparagine and beef extract as nitrogen sources were favorable for inhibitor production. Among vitamins, riboflavin, p-aminobenzoic acid, pyridoxamine and folic acid promoted the production of inhibitor, but depressed by the addition of hesperidine, and also depressed by cobalt, lithium and ferrous salts.

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Mineralogical Characteristics of the Noro and Miag Series Soils Developed on the Cinder Cones in Jeju Island (제주도(濟州道) 산록(山麓)의 분석구(噴石丘)에서 발달(發達)된 노로통과 미악통 토양(土壤)의 광물학적(鑛物學的) 특성(特性))

  • Zhang, Yong-Seon;Kim, Yoo-Hak;Song, Kwan-Cheol;Kim, Sun-Kwan
    • Korean Journal of Soil Science and Fertilizer
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    • v.35 no.3
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    • pp.145-152
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    • 2002
  • The composition of primary minerals in the rocks and secondary minerals of clay fractions of the soil developed on the cinder cones in the foot of Halla Mt., Jeju Island was investigated. The effects of parent materials on the physico-chemical properties and mineralogical characteristics were evaluated by XRD, DTA with the chemical composition of $H^+$ saturated clays. The main rock-forming minerals of a residual cinder cones were plagioclase with subsidiary minerals of hematite, gibbsite and quartz in the red cinder cone and of augite, quartz, feldspars and olivine in black cinder cone. It is demonstrated that ignition loss and sesquioxides content were higher in the red cinder soil than black cinder, which was resulted in the intermittent eruption of volcanic activity. For the chemical analysis of whole soils, $SiO_2/Al_2O_3$ ratio was increased from 2 to 3, but Ignition loss is decreased and $K_2O$ content are very low with increasing the soil depth in regard to the composition and kinds of clay minerals. No clay formation from micas mineral were in volcanic ashes. Dominant clay minerals of the cinder cone soils as a black and red cinder cone soil were allophane with some quartz and feldspars, while vermiculite, illite, kaolin were coexisted as a subsidiary minerals. But the red cinder cones soils had more hematite and gibbsite of the clay fractions than the black soils with magnetite. The exothermic pick of DTA at about $660^{\circ}C$ for cinder cone soils might be corresponded the oxidation magnetite to hematite reation. With regarding to the compositions of mineral detected by X-ray diffractogram and the properties of minerals by D.T.A thermogram, the dominant clay mineral was allophane of the cinder cone soils with some ferrous compounds, red colour of the cinder cone soils which are originated in hematite.

High-resolution near-IR Spectral Mapping of Multiple Outflows around LkHα 234 in NGC 7129 Star Forming Region

  • Oh, Heeyoung;Pyo, Tae-Soo;Koo, Bon-Chul;Yuk, In-Soo;Park, Byeong-Gon
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.1
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    • pp.38.2-38.2
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    • 2017
  • We present the observational study toward the multiple outflows around $LkH{\alpha}$ 234 star formation region. The high-resolution, near-IR spectral mapping using the Immersion Grating Infrared Spectrograph (IGRINS) allowed us to distinguish at least four separate outflows with the molecular hydrogen ($H_2$) and forbidden iron ([Fe II]) emission lines. The outflow associated with the radio continuum source VLA 3B is detected in both H2 and [Fe II] emission, while the outflows driven by MM 1, VLA 2 sources were only detected in $H_2$, indicating the different physical conditions of outflows. We confirm the axis of VLA 3B jet, the position angle of ${\sim}240^{\circ}$. We firstly identified the redshifted, near-IR H2 outflow associated with VLA 2, which is coincident with the previous detections of $H_2O$ masers. From the $H_2$ line ratios, we interpret the gas properties of the shock excited blue- and redshifted components, and UV excited surrounding photodissociation region. We also discuss the origin of the high-velocity (|VLSR| > $150km\;s^{-1}$) $H_2$ emission.

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Chemical Constituents from the Stems of Lagerstroemia indica and Their Anti-oxidant Effect (배롱나무의 항산화 활성 성분)

  • Woo, Kyeong Wan;Sim, Mi Ok;Park, Eel Jong;Kim, Min Suk;Suh, Won Se;Cho, Hyun Woo;Kwon, Hak Cheol;Park, Jong Cheol;Lee, Kang Ro
    • Korean Journal of Pharmacognosy
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    • v.47 no.3
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    • pp.204-210
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    • 2016
  • Phytochemical investigation of the 80% MeOH extract from the stems of Lagerstroemia indica resulted in the isolation of eighteen compounds; four norsesquiterpenes, fourteen phenolic derivatives. Their chemical structures were characterized by spectroscopic methods to be tachioside (1), isotachioside (2), 2,4,6-trimethoxyphenyl ${\beta}$-D-glucopyranoside (3), gallic acid 4-methyl ether (4), protocatechuic acid (5), gallic acid (6), vanillic acid (7), vanillin (8), 2-methoxy-5-hydroxymethyl-phenyl-1-O-(6"-galloyl)-${\beta}$-D-glucopyranoside (9), 2,4,6-trimethoxyphenol-1-O-${\beta}$-D-(6'-O-galloyl)-glucopyranoside (10), 4-hydroxy-3-methoxyphenyl-1-O-(6'-O-galloyl)-${\beta}$-D-glucopyranoside (11), vomifoliol (12), vomifoliol 9-O-${\beta}$-D-glucopyranoside (13), 6R,9R-3-oxo-${\alpha}$-ionol-9-O-${\beta}$-D-glucopyranoside (14), dihydrophaseic acid 4'-O-${\beta}$-D-glucopyranoside (15), ${\beta}$-hydroxypropiovanillone 3-O-${\beta}$-D-glucopyranoside (16), myrciaphenone A (17), and coumaric acid (18). Compounds 1-5 and 7-18 were isolated for the first time from this plant. Compounds 1-18 were investigated for their antioxidant properties using DPPH and ABTS radical scavenging capacity assay, $Fe^{2+}$ chelating, and FRAP assay. It was found that 4, 6, and 11 possessed the highest antioxidant capacities.