In order to recover valuable metals from fine-grained electronic waste, bioleaching of Cu, Zn, Al, Co, Ni, Sn and Pb were carried out using Aspergillus niger as a leaching microorganism in a shaking flask. Aspergillus niger was able to grow in tile presence of electronic scrap. The formation of organic acids(citric and oxalic acid) from Aspergillus niger caused the mobilization of metals from waste electronic scrap. In a preliminary study, in order to obtain the data on the leaching of Cu, Zn, Al, Co and Ni, the metal leaching behaviours were accomplished using Organic acid(Citric acid and Oxalic acid) instead of Aspergillus niger. At the electronic scrap concentration of 50g/L, Aspergillus niger were able to leach more than 95% of the available Cu, Co. But Al, Zn, Pband Sn were able to leach about 15-35%. Ni and Fe were detected in the leachate less than 10%.