Journal of the Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회논문지)

The Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회)
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Controlled Synthesis of Colloidal Cu Nanowires and Nanoplates and Their Tunable Localized Surface Plasmon Resonances

  • Seokhwan Kim (Department of Materials Science and Metallurgical Engineering, Kyungpook National University) ;
  • Jong Wook Roh (School of Nano and Materials Science and Engineering, Kyungpook National University) ;
  • Dong Choon Hyun (Department of Polymer Science and Engineering, Kyungpook National University) ;
  • Seonhwa Park (Regional Leading Research Center for Smart Energy System, Kyungpook National University) ;
  • Yuho Min (Department of Materials Science and Metallurgical Engineering, Kyungpook National University)
  • Received : 2024.06.24
  • Accepted : 2024.07.23
  • Published : 2024.09.01
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Abstract

Precise control over the morphology of nanostructures is critical for tailoring their physical and chemical properties. This study addresses the challenge of developing a simple, integrated method for synthesizing both 1D and 2D colloidal Cu nanostructures in a single system, achieving successful tuning of their localized surface plasmon resonance (LSPR) properties. A facile hydrothermal synthesis utilizing potassium iodide (KI) and hexadecylamine (HDA) is presented for controlling Cu nanostructure morphologies. The key to achieving 1D nanowires (NWs) and 2D nanoplates (NPs) depends on the controlled adsorption of HDA molecules and iodide (I-) ions on specific crystal facets. Depending on the morphologies, the resultant Cu nanostructures exhibit tunable LSPR peaks from 558 nm [nanoplates (NPs)] to 590 nm [nanowires (NWs)]. These results pave the way for the scalable and cost-effective production of plasmonic Cu nanostructures with tunable optical properties, holding promise for applications in sensing, catalysis, and photonic devices.

Keywords

Acknowledgement

This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Ministry of Science and ICT (2021R1A5A8033165 and RS-2023-00241159).

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