공업화학 (Applied Chemistry for Engineering)

  • 제34권4호
  • /
  • Pages.455-459
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  • 2023
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  • 1225-0112(pISSN)
  • /
  • 2288-4505(eISSN)
한국공업화학회 (The Korean Society of Industrial and Engineering Chemistry)
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Response Optimization for the Preparation of MIL-100(Fe)@COF Materials Using Design of Experiments

  • Min Hyung Lee (Department of Energy & Chemical Engineering, Graduate School of Convergence Science, Seoul National University of Science and Technology) ;
  • Sangmin Lee (Department of Chemical & Biomolecular Engineering, Seoul National University of Science and Technology) ;
  • Kye Sang Yoo (Department of Energy & Chemical Engineering, Graduate School of Convergence Science, Seoul National University of Science and Technology)
  • 투고 : 2023.05.02
  • 심사 : 2023.05.26
  • 발행 : 2023.08.10
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초록

Three different optimization studies were conducted for the synthesis of MIL-100(Fe) and MIL-100(Fe)@COF using design of experiments. In the first study, the optimal concentration of precursors was determined using a mixture design method, and a modified molar ratio of 0.4155:0.2664:0.3182 was found to yield the highest crystallinity. In the second study, a central composite design was used to optimize the main factors of synthesis temperature and time with a synthesis temperature of 161℃ and a synthesis time of 12 hours. In the third study, a screening design method was used to determine the effect of five precursors on the formation of MIL-100(Fe)@COF, and the presence of characteristic peaks at 1552, 1483, and 1354 cm-1 was found to be important for the existence of the COF structure. MIL-100(Fe)@COF synthesized with a modified molar ratio of 0.4831:0.4169:0.1 was predicted to exhibit optimal conditions.

키워드

과제정보

This study was supported by the Research Program funded by the SeoulTech(Seoul National University of Science and Technology)

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