DOI QR코드

DOI QR Code

수소 가스 검출용 라만 라이다 측정기의 성능 평가를 위한 기초 연구

A Basic Study for the Performance Evaluation of a Raman LiDAR Detector for Detecting Hydrogen Gas

  • 투고 : 2023.02.07
  • 심사 : 2023.04.05
  • 발행 : 2023.04.28

초록

Hydrogen gas is light and diffuses very quickly. Therefore, when a leakage accident occurs, the damage is great, so a technology that can quickly measure the leakage in the air at a long distance is needed. In order to develop hydrogen gas leaked in the atmosphere in a non-contact manner, an experiment was performed to measure hydrogen gas using a lidar technology using the Raman effect. Hydrogen Raman signals were detected using a UV LED light source, which is a Raman light source, and a spectrometer in the ultraviolet region including an optical filter in the 400-430 nm band. To develop this, a Raman lidar optical structure was designed to measure the hydrogen Raman signal at a certain distance, and the hydrogen Raman spectrum was confirmed using a standard gas to evaluate the performance of this optical structure. The linearity was found to be 0.99 using hydrogen standard gas (10, 50, 100, 500, 1,000 ppm). Accordingly, a Raman lidar capable of measuring hydrogen gas rapidly diffusing in the air in an open state was developed to improve the limitations of existing hydrogen sensors.

키워드

과제정보

본 연구는 소방청 ESS·수소시설 화재안전기술 연구개발사업(과제번호: 20019150)의 연구비 지원으로 수행되었습니다.

참고문헌

  1. A. M. Helmenstine, "Flame temperatures table for different fuels", ThoughtCo., 2019. Retrieved from https://www.thoughtco.com/flame-temperatures-table-607307. 
  2. D. A. Crowl and Y. D. Jo, "The hazards and risks of hydrogen", Journal of Loss Prevention in the Process Industries, Vol. 20, No. 2, 2007, pp. 158-164, doi: https://doi.org/10.1016/j.jlp.2007.02.002. 
  3. B. Park, Y. Kim, S. Paik, and C. Kang, "Numerical and experimental analysis of jet release and jet flame length for qualitative risk analysis at hydrogen refueling station", Process Safety and Environmental Protection, Vol. 155, 2021, pp. 145-154, doi: https://doi.org/10.1016/j.psep.2021.09.016. 
  4. B. Park, Y. Kim, and I. Hwang, "An experimental study on-the explosion hazards in the fuel cell room of residential house", Journal of the Korean Society of Safety, Vol. 36, No. 4, 2021, pp. 71-79, doi: https://doi.org/10.14346/JKOSOS.2021.36.4.71. 
  5. Y. Kim and B. Park, "Experimental and analytical study on hydrogen-air deflagrations in open atmosphere", Journal of the Korean Society of Safety, Vol. 36, No. 1, 2021, pp. 64-71, doi: https://doi.org/10.14346/JKOSOS.2021.36.1.64. 
  6. B. Park, J. Kim, O. K. Lim, and Y. Kim, "A numerical study on jet release from off-site and mobile hydrogen refueling station for separation distance", Fire Science and Engineering, Vol. 35, No. 6, 2021, pp. 75-84, doi: https://doi.org/10.7731/KIFSE.65ac91d8. 
  7. H. K. Kim, Y. M. Choi, S. H. Kim, J. H. Shim, and I. C. Hwang, "The evaluation of hydrogen leakage safety for the high pressure hydrogen system of fuel cell vehicle", Journal of Hydrogen and New Energy, Vol. 23, No. 4, 2012, pp. 316-322, doi: https://doi.org/10.7316/KHNES.2012.23.4.316. 
  8. J. Choi, N. Hur, M. Lee, H. Chang, K. Lee, and G. Yong, "A numerical analysis of hydrogen diffusion for hydrogen leakage from a fuel cell vehicle in a long road tunnel", Journal of Hydrogen and New Energy, Vol. 23, No. 6, 2012, pp. 588-597, doi: https://doi.org/10.7316/KHNES.2012.23.6.588. 
  9. T. H. Nam, D. H. Kim, J. W. Lee, S. K. Lee, and Y. J. Lee, "A study on characteristics of hydrogen leakage in hydrogen town governor room", Journal of Hydrogen and New Energy, Vol. 27, No. 6, 2016, pp. 685-692, doi: https://doi.org/10.7316/KHNES.2016.27.6.685. 
  10. Y. Kim, D. Shin, T. Chung, J. Nam, Y. Kim, and J. Lee, "An experimental study on the sensor response at hydrogen leakage in a residential fuel cell system", Journal of Hydrogen and New Energy, Vol. 20, No. 5, 2009, pp. 378-383. Retrieved from https://koreascience.kr/article/JAKO200908856859391.pdf. 
  11. C. H. Lee and C. O. Park, "The H2 and H2S sensing characteristics of Pd and Pd-Rh gate MOS sensor", Journal of the Korean Hydrogen Energy Society, Vol. 8, No. 4, 1997, pp. 145-154. Retrieved from https://koreascience.kr/article/JAKO199721040976867.pdf.  1040976867.pdf
  12. T. Hubert, L. Boon-Brett, G. Black, and U. Banach, "Hydrogen sensors - A review", Sensors and Actuators B: Chemical, Vol. 157, No. 2, 2011, pp. 329-352, doi: https://doi.org/10.1016/j.snb.2011.04.070. 
  13. E. I. Voronina, V. E. Privalov, and V. G. Shemanin, "Probing hydrogen molecules with a laboratory Raman lidar", Technical Physics Letters, Vol. 30, No. 5, 2004, pp. 178-179, doi: https://doi.org/10.1134/1.1707159. 
  14. A. J. Ball, V. Hohreiter, and D. W. Hahn, "Hydrogen leak detection using laser-induced breakdown spectroscopy", Applied Spectroscopy, Vol. 59, No. 3, 2005, pp. 348-353, doi: https://doi.org/10.1366/0003702053585282. 
  15. I. Asahi, S. Sugimoto, H. Ninomiya, T. Fukuchi, and T. Shiina, "Remote sensing of hydrogen gas concentration distribution by Raman lidar", Lidar Remote Sensing for Environmental Monitoring XIII, Vol. 8526, 2012, pp. 85260X, doi: https://doi.org/10.1117/12.977348. 
  16. S. Y. Choi, K. Y. Han, and B. H. Kim, "Comparison of different multiple linear regression models for real-time flood stage-forecasting", Vol. 32, No. 1B, 2012, pp. 9-20, doi: https://doi.org/10.12652/Ksce.2012.32.1B.009.