자원환경지질 (Economic and Environmental Geology)

  • 제55권4호
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  • Pages.339-352
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  • 2022
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  • 1225-7281(pISSN)
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  • 2288-7962(eISSN)
대한자원환경지질학회 (The Korean Society of Economic and Environmental Geology)
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전국 지화학도 자료를 이용한 지질기원 중금속의 지화학적 발생특성

Geochemical Occurrence Characteristics of Geogenic Heavy Metals in Korea Evaluated Using Geochemical Map Data

  • Ahn, Joo Sung (Korea Institute of Geoscience and Mineral Resources) ;
  • Youm, Seung-Jun (Korea Institute of Geoscience and Mineral Resources) ;
  • Cho, Yong-Chan (Korea Institute of Geoscience and Mineral Resources) ;
  • Yim, Gil-Jae (Korea Institute of Geoscience and Mineral Resources) ;
  • Ji, Sang-Woo (Korea Institute of Geoscience and Mineral Resources) ;
  • Lee, Jung-Hwa (Korea Institute of Geoscience and Mineral Resources) ;
  • Lee, Pyeong-Koo (Korea Institute of Geoscience and Mineral Resources) ;
  • Lee, Jeong-Ho (Korea Institute of Geoscience and Mineral Resources) ;
  • Shin, Seong-Cheon (Korea Institute of Geoscience and Mineral Resources)
  • 투고 : 2022.08.11
  • 심사 : 2022.08.22
  • 발행 : 2022.08.30
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초록

환경 기준 항목이 증가하거나 강화되면서 지질기원에 의한 중금속 오염사례가 증가하고 있으며, 토양이나 지하수의 기준치 초과양상에서 자연적 기원인지 인위적 기원인지 구분해야 할 필요성이 높아지고 있다. 본 연구에서는 전국 지화학도 자료에 대한 통계적 처리와 높은 지질축적지수 분포 지역의 지화학적 특성을 평가하여 중금속 원소들의 지질기원 발생요인을 규명하였다. 지화학도가 작성된 Co, Cr, Cu, Ni, Pb, V, Zn 등을 대상으로 하였으며, 초염기성암 또는 초고철질암에서 기원한 Co, Cr, Ni, V이 요인 1로, 비철금속 황화광물에 기인한 Cu, Pb, Zn가 요인 2로 구분되어졌다. 특히 충청지역의 사문암체 분포지역에서 요인 1에 의한 중금속 지질기원 부화현상이 주로 나타나며 이를 포함한 인근지역에서도 오염 위험이 있다. 요인 2의 경우 태백산 및 경남 광화대 등지의 비철금속 광화지역 뿐만 아니라 국내의 전반적인 금-은 광화대 지역에서도 지질기원 부화현상이 우려된다.

As environmental criteria items are increased or strengthened, cases of heavy metal contamination by geogenic origin are increasing, and the need to distinguish between natural and anthropogenic origins in soil or groundwater exceeding the standard is increasing. In this study, geochemical occurrences of geogenic heavy metals were identified through statistical processing of the national geochemical map data and evaluation of geochemical characteristics of regions with high geoaccumulation indices. Cobalt, Cr, Cu, Ni, Pb, V, and Zn were targeted for which the national geochemical maps were prepared, and Co, Cr, Ni, and V derived from ultrabasic or ultramafic rocks were classified as factor 1. Copper, Pb and Zn of non-ferrous sulfide origin were classified as factor 2. In particular, enrichment of heavy metals by factor 1 occurs mainly in the serpentine distribution areas of the Chungcheong region, and there is a risk of contamination in neighboring areas. In the case of factor 2, geogenic occurrence is concerned not only in non-ferrous metal mineralization areas such as Taebacksan and Gyeongnam mineralization zones, but also in Au-Ag mineralization areas distributed nationwide.

키워드

과제정보

이 연구는 한국지질자원연구원 기본사업(22-3412-2)의 지원을 받아 수행하였습니다.

참고문헌

  1. Ahn, J.S. and Ko, K.S. (2008) Geochemical Distribution of Arsenic in Groundwater of the Geumsan Area. Journal of the Korean Society of Mineral and Energy Resources Engineers, v.45, p.505-515.
  2. Ahn, J.S., Chon, C.M., Kim, K.Y., Ko, K.S. and Park, K.H. (2006) Geochemical Characteristics and Heavy Metal Distribution in Selected Volcanic Ash Soils in Jeju Island. Journal of the Korean Society of Mineral and Energy Resources Engineers, v.43(6), p.602-614.
  3. Ahn, J.S., Ko, K.S. and Chon, C.M. (2007) Arsenic Occurrence in Groundwater of Korea. Journal of Soil and Groundwater Environment, v.12(5), p.64-72.
  4. Ahn, J.,S., Ko, K.S., Lee, J.S. and Kim, J.Y. (2005) Characteristics of Natural Arsenic Contamination in Groundwater and Its Occurrences. Economic and Environmental Geology, v.38(5), p.547-561.
  5. Chae, G.T., Koh, D.C. and Choi, B.Y. (2008) The Origin and Geochemical Behavior of Fluoride in Bedrock Groundwater: A Case Study in Samseung Area (Boeun, Chungbuk). The Journal of Engineering Geology, v.18(4), p.555-566.
  6. Chae, G.T., Yun, S.T., Kim, K. and Mayer, B. (2006) Hydrogeochemistry of sodium-bicarbonate type bedrock groundwater in the Pocheon spa area, South Korea: water-rock interaction and hydrologic mixing, Journal of Hydrology, v.321, p.326-343. doi: 10.1016/j.jhydrol.2005.08.006
  7. Cho, B.W. (2017a) Uranium Concentrations in Groundwater of the Goesan Area, Korea. Economic and Environmental Geology, v.50(5), p.353-361. doi: 10.9719/EEG.2017.50.5.353
  8. Cho. B.W. (2017b) Radon Concentrations in Groundwater of the Goesan Area, Korea. Journal of Soil and Groundwater Environment, v.22(5), p.63-70. doi: 10.7857/JSGE.2017.22.5.063
  9. Cho, B.W., Choo, C.O., Yun, U., Lee, B.D., Hwang, J.H. and Kim, M.S. (2014) Hydrogeochemical Characteristics, Occurrence, and Distribution of Natural Radioactive Materials (Uranium and Radon) in Groundwater of Gyeongnam and Gyeongbuk Provinces. The Journal of Engineering Geology, v.24(4), p.551-574. doi: 10.9720/kseg.2014.4.551
  10. Cho, B.W., Kim, M.S., Kim, D.S. and Hwang, J.H. (2018) Uranium Levels in Groundwater of CGS (Community Groundwater System) of Korea. Economic and Environmental Geology, v.51(6), p.543-551. doi: 10.9719/EEG.2018.51.6.543
  11. Chon, C.M., Ahn, J.S., Kim, K.Y. and Park, K.H. (2008) Evaluation of Soil Redox Capacity using Chromium Oxidation-reduction Reactions in Volcanic Ash Soils in Jeju Island. ournal of the Mineralogical Society of Korea, v.21, p.161-175.
  12. Chon, C.M., Kim, K.Y., Koh, D.C. and Choi, M.J. (2009) Arsenic Distribution and Solubility in Groundwater of Okcheon Area. Journal of the Mineralogical Society of Korea, v.22(4), p.331-342.
  13. Chon, C.M., Moon, H.S., Choi, S.K. and Woo, N.C. (1997a) A Study on Soil Clay Minerals and the Distribution of Heavy Metals in Soils Derived from Black Shale and Black Slate in Dukpyoung Area. Economic and Environmental Geology, v.30(6), p.567-586.
  14. Choo, C.O., Kim, J.T., Chung, I.M., Kim, N.W. and Jeong, G.C. (2008) Geochemical Aspects of Groundwater in Granite Area and the Origin of Fluoride with Emphasis on the Water-Rock Interaction. The Journal of Engineering Geology, v.18(1), p.103-115.
  15. Chon, H.T., Kim,J.D., Kim, O.B., Min, K.W., Park, Y.S. and Yun, J.H. (1997b) Applied geochemistry. Seoul National University Press, 380p.
  16. Darnley, A.G., Bjorklund, A., Bolviken, B., Gustavsson, N., Koval, P.V., Plant, J.A., Steenfelt, A., Tauchid, M., Xuejing, X., Garrett, R.G. and Hall, G.E.M. (1995) A Global Geochemical Database for Environmental and Resource Management. Final Report of IGCP Project 259. Earth Sciences. 19, UNESCO Publishing, Paris, 122p.
  17. Forstner U. and Muller, G. (1981) Concentrations of heavy metals and polycyclic aromatic hydrocarbons in river sediments: geochemical background, man's influence and environmental impact. GeoJournal, v.5(5), p.417-432. doi: 10.1007/bf02484715
  18. Hwang, J. (2001) Fluorine Distribution and Attenuation of Groundwater within Limestone and Granite from Keumsan-Wanju Fluorite Mineralized Zone. Economic and Environmental Geology, v.34, p.105-117.
  19. Hwang, J. (2002) Geochemistry of Groundwater in Limestone and Granite of Hwanggangri Fluorite Mineralized Area. Journal of Korean Earth Science Society, v.23(6), p.486-493.
  20. Jeong, D.H., Kim, M.S., Ju, B.K., Hong, J.K., Kim, D.S., Kim, H.K., Kim, H.J., Park, S.H., Han, J.S. and Kim, T.S. (2013) Environmental Characteristics of Natural Radionuclides in Groundwaters in Volcanic Rock Areas: Korea. Journal of Soil and Groundwater Environment, v.18(1), p.36-45. doi: 10.7857/JSGE.2013.18.1.036
  21. Jeong, G.Y., Kim, K., Kim, J.Y., Park, J.H., Yee, D.Y. and Park, S.G. (2003) High fluorine groundwaters in the Yangsan Fault zone between Pohang-Gyeongju area. Journal of the Geological Society of Korea, v.39(3), p.371-384.
  22. John, Y.W. (1997) Resources and environment of the Earth. Seoul National University Press, 492p.
  23. Ju, B.K., Kim, M.S., Jeong, D.H., Hong, J.K., Kim, D.S., Noh, H.J., Yoon, J.K. and Kim, T.S. (2013) Environmental Characteristics of Naturally Occurring Radioactive Materials (238U, 222Rn) Concentration in Drinking Groundwaters of Metamorphic Rock Areas; Korea. Journal of Soil and Groundwater Environment, v.18(3), p.82-92. doi: 10.7857/jsge.2013.18.3.082
  24. Kang, S.H., Kim, J.J., Kim, Y.H. and Kim, J.W. (2016) Water environment due to detection of arsenic in village water supply facilities in Haman area. Proceedings of the Annual Joint Conference, the Petrological Society of Korea and the Mineralogical Society of Korea, May 26-27, 2016, Busan, Korea, p.131-134.
  25. Kaprara, E., Kazakis, N., Simeonidis, K., Coles, S., Zouboulis, A.I., Samaras, P. and Mitrakas, M. (2015) Occurrence of Cr(VI) in drinking water of Greece and relation to the geological background. Journal of Hazardous Materials, v.281, p.2-11. doi: 10.1016/j.jhazmat.2014.06.084
  26. KEI (2017) A study of policy alternatives for managing heavy-metal contaminated agricultural soils by natural causes, Korea Environment Institute 2017-14, 79p.
  27. KIGAM (1963) Geological map of Taehung sheet, scale 1:50,000. Korea Institute of Geoscience & Mineral Resources, 18p.
  28. KIGAM (2000) National geochemical mapping for natural environment. Korea Institute of Geoscience & Mineral Resources. Report N2-03-01-0A-04, 272p.
  29. KIGAM (2003) National baseline mapping for geochemical hazard assessment. Korea Institute of Geoscience & Mineral Resources. Report 00-J-ND-01-B-17, 223p.
  30. KIGAM (2007) Geochemical Atlas of Korea (1:1,800,000), Series 9. Korea Institute of Geoscience & Mineral Resources, 68p.
  31. KIGAM (2021) Development of real-time landslide early warning technology in urban areas and risk management technique of pollutants in geologic environment. Korea Institute of Geoscience & Mineral Resources. Report GP2020-016-2021, 448p.
  32. Kim, O.J. (1970) Gold-silver metallogenic provinces in South Korea. Journal of the Korean Institute of Mining Geology, v.3(3), p.163-167.
  33. Kim, K. and Jeong, G.Y. (2005) Factors influencing natural occurrence of fluoride-rich groundwaters: a case study in the southeastern part of the Korean Peninsula, Chemosphere, v.58, p.1399-1408. doi: 10.1016/j.chemosphere.2004.10.002
  34. Kim, I., Kim, M., Hamm, S.Y., Kim, H., Kim, D., Jo, S., Lee, H., Hwang, J., Jo, H., Park, S. and Chung, H. (2018) Characteristics of Naturally Occurring Radioactive Materials in Groundwater from Aquifers Composed of Different Geological Settings in Ganghwa Island. Economic and Environmental Geology, v.51(1), p.27-38. doi: 10.9719/EEG.2018.51.1.27
  35. Kim, K.H., Park, J.K., Yang, J.M. and Satake, H. (1993) A study on Serpentinization of Serpentinites from the Ulsan Iron Mine. Economic and Environmental Geology, v.26(3), p.267-278.
  36. Kim, M.H., Song, S.H., Min, E.S. and Jang, I.S. (2000) Heavy Metal Pollutions of the Top Soil, Plants and Stream Water from the Serpentinite Area, Chungnam. Korean Journal of Environment and Ecology, v.14(2), p.119-126.
  37. Kim, J.I., Yoon, J.K., Kim, H., Kim, H.K., Kim, M.S., Park, S., Kim, R.Y., Lee, H., Ko, H., Park, K., Kim, I. and Kim, T.S. (2014) Assessment of fate and transport characteristics for new soil contaminants ('14). National Institute of Environmental Research, NIER-RP2014-388, 40p.
  38. Lee, B. (2018) Hydrogeochemistry and Occurrences of Uranium and Radon in Groundwater of in Chungwon, Korea. Journal of Environmental Science International, v.27(8), p.651-663. doi: 10.5322/jesi.2018.27.8.651
  39. Lee, B., Cho, B.U., Kim, M.S. and Hwang, J.H. (2018b) Hydrogeochemistry and Occurrence of Uranium and Radon in Groundwater of Mungyeong Area. Economic and Environmental Geology, v.51(6), p.553-566. doi: 10.9719/EEG.2018.51.6.553
  40. Lee, J.S., Chon, H.T. and Kim, K.W. (1997) Dispersion and Migration of Potentially Toxic Elements in the Rock-Soil-Plant System from the Boeun Area Underlain by Black Shales, Korea. Economic and Environmental Geology, v.30(6), p.587-601.
  41. Lee, J.H., Jeong, J.O., Kim, K.K., Lee, S.W. and Kim, S.O. (2018a) Origin of Fluorine Contained in Rocks within the Eulwangsan, Yongyudo. Economic and Environmental Geology, v.51(6), p.521-529. doi: 10.9719/EEG.2018.51.6.521
  42. Lee, J.H., Jeong, J.O., Kim, K.K., Lee, S.W. and Kim, S.O. (2019) Geochemical Study on the Naturally Originating Fluorine Distributed in the Area of Yongyudo and Sammokdo, Incheon. Economic and Environmental Geology, v.52(4), p.275-290. doi: 10.9719/EEG.2019.52.4.275
  43. Lee, Y.J., Kim, H.J., Yoo, S., Jeong, H., Kim, D.H., Noh, H.J., Kim, M.S., Yoo, J.Y., Han, J., Jung, D., Jeon, S., Bang, S. and Kim, M.S. (2010) Investigation of Unregulated Contaminants in Groundwater based on the Priority List('10). National Institute of Environmental Research, NIER NO.2010-45-1220. doi: 10.7857/JSGE.2017.22.5.071
  44. Lee, H.G., Noh, H.J., Yoon, J.K., Lim, J.H., Lim, G.H., Kim, H.K. and Kim, J.I. (2018c) Evaluation of the Concentration Distribution and the Contamination Influences for Beryllium, Cobalt, Thallium and Vanadium in Soil Around the Contaminated Sources. Journal of Soil and Groundwater Environment, v.23(4), p.48-59. doi: 10.1007/s10653-021-01159-8
  45. Moon, S.H., Cho, S.Y. and Kim, S. (2018) Rn Occurrences in Groundwater and Its Relation to Geology at Yeongdong Area, Chungbuk, Korea. Economic and Environmental Geology, v.51(5), p.409-428. doi: 10.9719/EEG.2018.51.5.409
  46. Moon, J.T., Kim, K., Kim, S.H., Jeong, C.S. and Hwang, G.S. (2008) Geochemical Investigation on Arsenic Contamination in the Alluvial Groundwater of Mankyeong River Watershed. Economic and Environmental Geology, v.41(6), p.673-683.
  47. Noh, H.J., Jeong, D.H., Yoon, J.K., Kim, M.S., Ju, B.K., Jeon, S.H. and Kim, T.S. (2011) Natural Reduction Characteristics of Radon in Drinking Groundwater. Journal of Soil and Groundwater Environment, v.16(1), p.12-18. doi: 10.7857/JSGE.2011.16.1.012
  48. Park, G., Hwang, J., Oh, J. and Lee, H. (2012) Occurrence and Mineralogy of Serpentinite from Bibong Mine in Chungyang Area, Korea. Journal of the Mineralogical Society of Korea, v.25(1), p.9-21. doi: 10.9727/jmsk.2012.25.1.009
  49. Pyrgaki, K., Argyraki, A., Botsou, F., Kelepertzis, E., Paraskevopoulou, V., Karavoltsos, S., Mitsis, I. and Dassenakis, E. (2021) Hydrogeochemical investigation of Cr in the ultramafic rock-related water bodies of Loutraki basin, Northeast Peloponnese, Greece. Environmental Earth Sciences, v.80(2), p.1-18. doi: 10.1007/s12665-020-09342-3
  50. Ryou, S.H., Kim, J.M., Cha, S.S. and Shim, J.K. (2010) Decomposition of Leaf Litter Containing Heavy Metals in the Andong Serpentine Area, Korea. Korean Journal of Environment and Ecology, v.24(4), p.426-435.
  51. Song, S. (2019) Petrochemistry of the Peridotites within an Andong Ultramafic Complex and Characteristics of Asbestos Occurrences. Journal of the Mineralogical Society of Korea, v.32(1), p.15-39. doi: 10.9727/jmsk.2019.32.1.15
  52. Song, S., Choi, S.G., Oh, C.H., Seo, J.E. and Choi, S. (2004) Petrography and Geochemistry of the Ultramafic Rocks from the HongSeong and Kwangcheon areas, Chungcheongnam-Do. Economic and Environmental Geology, v.37(5), p.477-497.
  53. Song, S. and Kang, J. (2016) Occurrences of Asbestos within Gapyeong Serpentinite Mines and Characteristics of Host Rocks. Journal of Korean Society of Occupational and Environmental Hygiene, v.26(3), p.253-266. doi: 10.15269/JKSOEH.2016.26.3.253
  54. Wedepohl, K.H. (1995) The composition of the continental crust. Geochemica Cosmochimica Acta, v.59, p.1217-1232. doi: 10.1016/0016-7037(95)00038-2
  55. Yun, U., Cho, B.W. and Sung, K.Y. (2004) Occurrence and Species of Arsenic in the Groundwater of Ulsan Area. Economic and Environmental Geology, v.37(6), p.657-667.
  56. Yun, U., Kim, M.S., Jeong, D.H., Hwang, J.H. and Cho, B.W. (2018) Uranium and Radon Concentrations in Groundwater of the Daejeon Granite Area: Comparison with Other Granite Areas. The Journal of Engineering Geology, v.28(4), p.631-643. doi: 10.9720/kseg.2018.4.631