Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
권호 표지
DOI QR코드

DOI QR Code

A Study on the Quantitative Analysis of Allergenic Dispersed Dyes in Polyester Dyeing Fabric Using by HPTLC

HPTLC를 이용한 폴리에스터 염색 원단의 알러지성 분산염료 정량분석에 관한 연구

  • Kang, Mi-Young (Korea Dyeing and Finishing Technology Institute (DYETEC)) ;
  • Song, Sun-Hye (Korea Dyeing and Finishing Technology Institute (DYETEC))
  • Received : 2022.05.07
  • Accepted : 2022.06.09
  • Published : 2022.06.30
⟨ Previous Next ⟩

Abstract

In this study, allergenic dispersed dyes Red1, Blue3, and Orange3 were dyeing at 0.05%, 0.1%, and 0.5% o.w.f. concentrations on polyester fabrics, and the dyeing fabrics were extracted with Pyridine and analyzed quantitatively using HPTLC(high performance thin layer chromatography). The developing solvent of the HPTLC stationary phase(plate) was mixed and development in a ratio of toluene: acetone (20:1 v/v), the concentration of the calibration curve of each allergenic dispersed dyes was 0.1 to 10 g/l, and the correlation coefficient (r2 ) was 0.999 or more. The quantitative limit was about 0.012 to 0.033 g/l and the detection limit was 0.039 to 0.105 g/l, and as a result of the precision test, the dispersion coefficient (C.V.) was less than 0.9%. In addition, through comparative analysis of HPTLC and HPLC, it was confirmed that the quality and quantity of each mixed dye allergenic dispersed dyes can be measured by HPTLC analysis.

Keywords

Acknowledgement

본 연구는 산업통상자원부 상용표준물질개발 보급사업(20016336)의 지원에 의해 수행된 연구 결과입니다.

References

  1. R. M. Christie, "Colour Chemisttry", Royal Society of Chemistry, Cambridge, 2001.
  2. An Dooms-Goossens, "Textile Dye Dermatitis", Contact Dermatitis, 1992, 27, 321-323. https://doi.org/10.1111/j.1600-0536.1992.tb03289.x
  3. S. Seidenari, B. M. Manzini, and P. Danese, "Contact Sensitization to Textile Dyes: Description of 100 Subjects", Contact Dermatitis, 1991, 24, 253-258. https://doi.org/10.1111/j.1600-0536.1991.tb01718.x
  4. W. L. Weaton and A. Bruckner, "Allergic Contact Dermatitis", Pediatr. Clin. N. Am., 2000, 47, 897-907. https://doi.org/10.1016/s0031-3955(05)70247-9
  5. K. L. Hatch, H. Moyschi, and H. I. Maibach, "Textile-dye and Colored-textile Allergic Contact Dermatitis", Exog. Dermatol., 2003, 2, 206-209. https://doi.org/10.1159/000076803
  6. K. Ryberg, A. Goossens, M. Isaksson, B. Gruvberger, E. Zimerson, F. Nilsson, J. Bjork, M. Hindsen, and M. Bruze, "Is Contact Allergy to Disperse Dyes and Related Substances Associated with Textile Dermatitis?", Br. J. Dermatol., 2009, 160, 107-115. https://doi.org/10.1111/j.1365-2133.2008.08953.x
  7. Y.-S. Shim, "Food Analysis Technique Using by HPTLC/MS", Bull. Food Technol., 2011, 24, 236-244.
  8. J. Novakovie, "High-performance Thin-layer Chromatography for the Determination of Ranitidine Hydrochloride and Famotidine in Pharmaceuticals", J. Chromatography A, 1999, 846, 193-198. https://doi.org/10.1016/S0021-9673(99)00510-5
  9. L. G. LaLA, "HPTLC Determination of Diclofenac Sodium from Serum", J. Pharmaceutical and Biomedical Analysis, 2002, 29, 539-544. https://doi.org/10.1016/S0731-7085(02)00131-0
  10. A. Shailesh, "Development of a Sensitive High-performance Thin-layer Chromatography Method for Estimation of Ranitidine in Urine and Its Application for Bioequivalence Decision for Ranitidine Tablet Formulations", J. Chromatography B, 2002, 767, 83-91. https://doi.org/10.1016/S0378-4347(01)00544-8
  11. B. Vandana, "HPTLC Determination of Nimesulide from Pharmaceutical Dosage Forms", J. Pharmaceutical and Biomedical Analysis, 2001, 25, 685-688. https://doi.org/10.1016/S0731-7085(00)00597-5
  12. S. N. Makhija, "Stability Indicating HPTLC Method for the Simultaneous Determination of Pseudoephedrine and Cetirizine in Pharmaceutical Formulations", J. Phamaceutical and Biomedical Analysis, 2001, 25, 663-667. https://doi.org/10.1016/S0731-7085(00)00586-0