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Application and Functionalization of Graphene Oxide on Cotton Fabric Via Aerosol Spray Pyrolysis

그래핀 옥사이드의 에어로졸 분무열분해 공정을 통한 면직물의 전기전도성 및 물성 평가

  • Ohm, Hyunji (Dept. of Clothing & Textiles, Yonsei University) ;
  • Cho, Gilsoo (Dept. of Clothing & Textiles, Yonsei University)
  • 엄현지 (연세대학교 의류환경학과) ;
  • 조길수 (연세대학교 의류환경학과)
  • Received : 2021.11.10
  • Accepted : 2021.12.17
  • Published : 2022.02.28

Abstract

Today, graphene loaded textiles are being considered promising smart clothing due to their high conductivity. In this study, we reported reduced graphene oxide(r-GO) deposited pure cotton fabrics fabricated with a colloidal solution of graphene(GO), using a one-step aerosol spray pyrolysis(ASP) process and their potential application on smart textiles. The ASP process is advantageous in that it is easily implementable and can be applied for continuous processing. Moreover, this process has never been applied to deposit r-GO on pure cotton fabric. The field emission-scanning microscopy (FE-SEM) observation, Fourier transform-infrared(FT-IR) analysis, Raman spectroscopy, X-ray diffraction(XRD) analysis, and ultraviolet transmittance(UVT) were used to evaluate material properties of the r-GO colloids. The resistance was also measured to evaluate the electrical conductivity of the specimens. The results revealed that the r-GO was successfully deposed on specimens, and the specimen with the highest electrical conductivity demonstrated an electrical resistance value of 2.27 kΩ/sq. Taken together, the results revealed that the ASP method demonstrated a high potential for effective deposition of r-GO on cotton fabric specimens and is a prospect for the development of conductive cotton-based smart clothing. Therefore, this study is also meaningful in that the ASP process can be newly applied by depositing r-GO on the pure cotton fabric.

Keywords

Acknowledgement

이 논문은 한국지질자원연구원에서 도움을 받아 수행한 실험 내용을 바탕으로 작성되었음.

References

  1. Ambrosi, A., Chua, C. K., Bonanni, A., & Pumera, M. (2012). Lithium aluminum hydride as reducing agent for chemically reduced graphene oxides. Chemistry of Materials, 24(12), 2292-2298. doi:10.1021/cm300382b
  2. Cai, G., Xu, Z., Yang, M., Tang, B., & Wang, X. (2017). Functionalization of cotton fabrics through thermal reduction of graphene oxide. Applied Surface Science, 393, 441-448. doi:10.1016/j.apsusc.2016.10.046
  3. Ha, T., Kim, S. K., Choi, J. W., Chang, H., & Jang, H. D. (2019). pH controlled synthesis of porous graphene sphere and application to supercapacitors. Advanced Powder Technology, 30(1), 18-22. doi:10.1016/j.apt.2018.10.002
  4. Hummers Jr, W. S., & Offeman, R. E. (1958). Preparation of graphitic oxide. Journal of the American Chemical Society, 80(6), 1339-1339. doi:10.1021/ja01539a017
  5. Jang, E., & Cho, G. (2019). The classification and investigation of smart textile sensors for wearable vital signs monitoring. Fashion & Textile Research Journal, 21(6), 697-707. doi:10.5805/sfti.2019.21.6.697
  6. Jang, H. D., Kim, S. K., Chang, H., Choi, J. W., Luo, J., & Huang, J. (2013). One-step synthesis of Pt-nanoparticles-laden graphene crumples by aerosol spray pyrolysis and evaluation of their electrocatalytic activity. Aerosol Science and Technology, 47(1), 93-98. doi:10.1080/02786826.2012.728302
  7. Karimi, L., Yazdanshenas, M. E., Khajavi, R., Rashidi, A., & Mirjalili, M. (2016). Functional finishing of cotton fabrics using graphene oxide nanosheets decorated with titanium dioxide nanoparticles. The Journal of The Textile Institute, 107(9), 1122-1134. doi:10.1080/00405000.2015.1093311
  8. Kim, D., & Kim, K. (2007). Preparation of nanoparticles by gas phase processes. Korean Chemical Engineering Research, 45(6), 536-546.
  9. Kim, W., Lee, E., Choi, J., & Cho, G. (2020). Improved electrical conductivity of polyurethane nanoweb coated with graphene ink through heat treatment. Fibers and Polymers, 21(6), 1195-1199. doi:10.1007/s12221-020-9912-x
  10. Lee, C., Chang, H., & Jang, H. D. (2017). Preparation of CoFe2O4-graphene composites using aerosol spray pyrolysis for super-capacitors application. Particle and aerosol research, 13(1), 33-40. doi: 10.4209/aaqr.2018.10.0372
  11. Pandiyarasan, V., Archana, J., Pavithra, A., Ashwin, V., Navaneethan, M., Hayakawa, Y., & Ikeda, H. (2017). Hydrothermal growth of reduced graphene oxide on cotton fabric for enhanced ultraviolet protection applications. Materials Letters, 188, 123-126. doi:10.1016/j.matlet.2016.11.047
  12. Samanta, A., & Bordes, R. (2020). Conductive textiles prepared by spray coating of water-based graphene dispersions. RSC Advances, 10(4), 2396-2403. https://doi.org/10.1039/c9ra09164e
  13. Tian, M., Hu, X., Qu, L., Zhu, S., Sun, Y., & Han, G. (2016). Versatile and ductile cotton fabric achieved via layer-by-layer self-assembly by consecutive adsorption of graphene doped PEDOT: PSS and chitosan. Carbon, 96, 1166-1174. doi:10.1016/j.carbon.2015.10.080
  14. Zeng, W., Shu, L., Li, Q., Chen, S., Wang, F., & Tao, X. M. (2014). Fiber-based wearable electronics - A review of materials, fabrication, devices, and applications. Advanced materials, 26(31), 5310-5336 https://doi.org/10.1002/adma.201400633