Journal of Electrochemical Science and Technology

  • 제13권1호
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  • Pages.71-77
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  • 2022
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  • 2093-8551(pISSN)
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  • 2288-9221(eISSN)
한국전기화학회 (The Korean Electrochemical Society)
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Ion Migration in Metal Halide Perovskites

  • Nur'aini, Anafi (Chemical Engineering, Kumoh National Institute of Technology) ;
  • Lee, Seokwon (Departments of Applied Chemistry, Kumoh National Institute of Technology) ;
  • Oh, Ilwhan (Departments of Applied Chemistry, Kumoh National Institute of Technology)
  • 투고 : 2021.01.28
  • 심사 : 2021.06.08
  • 발행 : 2022.02.28
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초록

Metal halide perovskites are promising photovoltaic materials, but they still have some issues that need to be solved. Hysteresis is a phenomenon that strongly is correlated with ion migration; thus, a fast, easy, and low-temperature method for measuring ion migration is required. Through selective blocking, ion migration can be measured separately, apart from electron migration. In this study, ion migration in metal halide perovskites was measured using a vertical device. At different temperatures, ionic activation energies were obtained for a range of perovskite compositions such as MAPbI3, FAPbI3, CsPbI3, and MAPbBr3. By comparing the measured ionic activation energies with the theoretical values, we conclude that among other possibilities, I- is the migrating ion in MAPbI3, FAPbI3, CsPbI3, and Br- is the migrating in MAPbBr3.

키워드

과제정보

This research was supported by the sabbatical of Kumoh National Institute of Technology.

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