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Eosin Biosorption from Aqueous Solution on Two Types of Activated Sludge

  • Cherifa, Farsi (Laboratoire des Biomatériaux et des Phenomenes de Transferts LBMPT, Universite de Medea) ;
  • Hakima, Cherifi (Laboratoire des Biomatériaux et des Phenomenes de Transferts LBMPT, Universite de Medea) ;
  • Radhia, Yous (Laboratoire des Biomatériaux et des Phenomenes de Transferts LBMPT, Universite de Medea) ;
  • Salah, Hanini (Laboratoire des Biomatériaux et des Phenomenes de Transferts LBMPT, Universite de Medea) ;
  • Razika, Khalladi (Laboratoire des Materiaux et Environnement LME, Universite de Medea)
  • Received : 2021.07.18
  • Accepted : 2021.10.01
  • Published : 2022.02.01

Abstract

In wastewater treatment processes huge quantities of sludge are produced continuously each year. This work investigated the reuse of two types of sludge as biosorbents of a toxic dye. The potential of granular and filamentous fungus dried sludge for the elimination of eosin from aqueous solution was studied in batch system. The effect of initial concentration and temperature was examined. Maximum uptake was observed at 100 mg l-1 and 30 ℃. The maximum removal rate was 92% for the granular sludge and 90% for the filamentous one. Equilibrium was attained after 30 min for the studied dye concentrations. The equilibrium uptake increased with the initial eosin concentration. The Freundlich and Langmuir adsorption models were also investigated. The reuse of disposed sludge as adsorbent could be a solution for the valorization of such dangerous waste to resolve two environmental problems at the same time.

Keywords

References

  1. Chatterjee, S., Chatterjee, Sa., Chatterjee, B. P., Das, A.R. and Guha, A. K., "Adsorption of a Model Anionic Dye, Eosin Y, from Aqueous Solution by Chitosan Hydrobeads," J. Colloid. Interface Sci., 288(1), 30-35(2005). https://doi.org/10.1016/j.jcis.2005.02.055
  2. Arafah, M., Zakir, M. and Raya, I., "Kinetics and Thermodynamics Study of Eosin Adsorption on Rice Husk Based Activated Carbon under Sonication," Indonesia Chimica Acta, 7(1), (2014).
  3. Ansari, R. and Mosayebzadeh, Z., "Removal of Eosin Y, an Anionic Dye, from Aqueous Solutions using Conducting Electroactive Polymers," Iran Polym. J., 19(7), 541-551(2010).
  4. Kant, R., "Adsorption of Dye Eosin from an Aqueous Solution on Two Different Samples of Activated Carbon by Static Batch Method," J. Water Res. Prot., 4, 93-98(2012). https://doi.org/10.4236/jwarp.2012.42011
  5. Huanga, X.-Y., Binb, J.-P., Buc, H.-T., Jianga, G.-B. and Zengd, M.-H., "Removal of Anionic Dye Eosin Y from Aqueous Solution Using Ethylenediamine Modified Chitosan," Carbohydr. Polym., 84, 1350-1356(2011). https://doi.org/10.1016/j.carbpol.2011.01.033
  6. Abdus-Salam, N., AbiolaIkudayisi-Ugbe, V. and Ugbe, F. A., "Adsorption Studies of Acid Dye - Eosin Yellow on Date Palm Seeds, Goethite and Their Composite," Chem. Data Collect., 31, 100626(2021). https://doi.org/10.1016/j.cdc.2020.100626
  7. Mittal, A., Jhare, D. and Mittal, J., "Adsorption of Hazardous Dye Eosin Yellow from Aqueous Solution onto Waste Material De-Oiled Soya: Isotherm, Kinetics and Bulk Removal," J. Mol. Liq., 179, 133-140(2013). https://doi.org/10.1016/j.molliq.2012.11.032
  8. Selmani, F., Cherifi, H., Hanini, S. and Khalladi, R., "Competitive Adsorption of Dyes on Activated Carbon Prepared from Vegetable Fibers," Fresenius Environ. Bullet., 28(6), 4598(2019).
  9. Fukahori, S., Fujiwara, T., Ito, R. and Funamizu, N., "pH-Dependent Adsorption of Sulfa Drugs on High Silica Zeolite: Modeling and Kinetic Study," Desalination, 275, 237-242(2011). https://doi.org/10.1016/j.desal.2011.03.006
  10. Mittal, A., Krishnan, L. and Gupta, V. K., "Use of Waste Materials-Bottom Ash and De-Oiled Soya, as Potential Adsorbents for the Removal of Amaranth from Aqueous Solutions," J. Hazard. Mater., 117, 171-178(2005). https://doi.org/10.1016/j.jhazmat.2004.09.016
  11. https://www.aps.dz/regions/70454-region-ouest-des-campagnesd-information-sur-l-utilisation-des-boues-issues-des-step-dans-lagriculture, Region ouest: des campagnes d'information sur l'utilisation des boues issues des STEP dans l'agriculture, February 27/2018.
  12. Cherifi, H., Djezar, S., Korichi, A., Nekkache, K. and Messahel, H., "Biosorption of Methylene Blue by Activated Sludge," Desalin. Water Treat., 57, 10-14(2016).
  13. Yous, R., Mohellebi, F., Cherifi, H. and Amrane, A., "Competitive Biosorption of Heavy Metals from Aqueous Solutions Onto Streptomyces Rimosus", Korean J. Chem. Eng., 35(4), 890-899(2018). https://doi.org/10.1007/s11814-018-0004-1
  14. Ahluwalia, S. S. and Goyal, D., "Microbial and Plant Derived Biomass for Removal of Heavy Metals from Wastewater," Biores. Technol., 98, 2243-2257(2007). https://doi.org/10.1016/j.biortech.2005.12.006
  15. Langergren, S. and Svenska Zur, B. K., "Theorie Der Sogenannten Adsorption Geloesterstoffe," Veternskapsakad Handlingar, 24, 1-39(1898).
  16. Ho, Y. S. and Mac Kay, G., "Pseudo-second Order Model for Sorption Process," Proc. Biochem., 34, 451-465(1999). https://doi.org/10.1016/S0032-9592(98)00112-5
  17. Aksu, Z., "Equilibrium and Kinetics Modelling of Cadmium (II) Biosorption by C. vulgaris in Batch System: Effect of Temperature," Sep. Purif. Technol., 21, 285-294(2001). https://doi.org/10.1016/S1383-5866(00)00212-4
  18. Yous, R., Cherifi, H. and Khalladi, R., "Comparative Mass Transfer Study of Basic and Acid Magenta Adsorption onto Natural Clay," Indones. J. Chem., 19(4), 1031-1042(2019). https://doi.org/10.22146/ijc.41820
  19. Jiang, L., Wen, Y., Zhu, Z., Liu, X. and Shao, W., "A Double Cross-linked Strategy to Construct Graphene Aerogels with Highly Efficient Methylene Blue Adsorption Performance," Chemosphere, 265, 129-169(2021).
  20. Langmuir, I., "The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinum," J. Am. Chem. Soc., 40, 1361-1368(1918). https://doi.org/10.1021/ja02242a004
  21. Freundlich, H., Adsorption in Solution, J. Phys. Chem., 40, 1361-1368(1906).
  22. Smith, J. M., Chemical Engineering Kinetics, 3rd ed., McGrawHill, Singapore (1981).
  23. Darwish, A. A. A., Rashad, M., AL-Aoh, H. A., "Methyl Orange Adsorption Comparison on Nanoparticles: Isotherm, Kinetics, and Thermodynamic Studies," Dyes Pigm., 160, 563-571(2019). https://doi.org/10.1016/j.dyepig.2018.08.045
  24. Kilic, M. and Janabi, A. S. K., "Investigation of Dyes Adsorption with Activated Carbon Obtained from Cordia myxa", Bilge Int. J. Sci. Technol. Res., 1(2), 87-104(2017).
  25. Wang, Y., Yang, M., Quan-Bao, Z. and Han-Qing, Y., "Isotherms, Kinetics and Thermodynamics of Dye Biosorption by Anaerobic Sludge," Sep. Purif. Technol., 50, 1-7(2006). https://doi.org/10.1016/j.seppur.2005.10.012