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Effect of Graphitic Nanofibers on Interfacial Adhesion and Fracture Toughness of Carbon Fibers-reinforced Epoxy Composites

  • Received : 2020.11.30
  • Accepted : 2021.03.30
  • Published : 2021.04.30

Abstract

The mechanical properties of carbon fiber-reinforced epoxy composites (CFRPs) are greatly dependent on the interfacial adhesion between the carbon fibers and the epoxy matrix. Introducing nanomaterial reinforcements into the interface is an effective approach to enhance the interfacial adhesion of CFRPs. The main purpose of this work was to introduce graphitic nanofiber (GNFs) between an epoxy matrix and carbon fibers to enhance interfacial properties. The composites were reinforced with various concentrations of GNFs. For all of the fabricated composites, the optimum GNF content was found to be 0.6 wt%, which enhanced the interlaminar shear strength (ILSS) and fracture toughness (KIC) by 101.9% and 33.2%, respectively, compared with those of neat composites. In particular, we observed a direct linear relationship between ILSS and KIC through surface free energy. The related reinforcing mechanisms were also analyzed and the enhancements in mechanical properties are mainly attributed to the interfacial interlocking effect. Such an effort could accelerate the conversion of composites into high performance materials and provide fundamental understanding toward realizing the theoretical limits of interfacial adhesion and mechanical properties.

Keywords

References

  1. Robertson, I.D., Yourdkhani, M., Centellas, P.J., Aw, J.E., Ivanoff, D.G., Goli, E., and Moore, J.S., "Rapid Energy-efficient Manufacturing of Polymers and Composites via Frontal Polymerization", Nature, Vol. 557, 2018, pp. 223-227. https://doi.org/10.1038/s41586-018-0054-x
  2. Taynton, P., Ni, H., Zhu, C., Yu, K., Loob, S., Jin, Y., Qi, H.J., and Zhang, W., "Repairable Woven Carbon Fiber Composites with Full Recyclability Enabled by Malleable Polyimine Networks", Advanced Materials, Vol. 28, 2016, pp. 2904-2909. https://doi.org/10.1002/adma.201505245
  3. Zhang, Y., Heo, Y.J., Son, Y.R., In, I., An, K.H., Kim, B.J., and Park, S.J., "Recent Advanced Thermal Interfacial Materials: A Review of Conducting Mechanisms and Parameters of Carbon Materials", Carbon, Vol. 142, 2019, pp. 445-460. https://doi.org/10.1016/j.carbon.2018.10.077
  4. Kwon, Y.J., Kim, Y., Jeon, H., Cho, S., Lee, W., and Lee, J.U., "Graphene/carbon Nanotube Hybrid as a Multi-functional Interfacial Reinforcement for Carbon Fiber-reinforced Composites", Composites Part B: Engineering, Vol. 122, 2017, pp. 23-30. https://doi.org/10.1016/j.compositesb.2017.04.005
  5. Karger-Kocsis, J., Mahmood, H., and Pegoretti, A., "All-carbon Multi-scale and Hierarchical Fibers and Related Structural Composites: A Review", Composites Science and Technology, Vol. 186, 2020, pp. 107932. https://doi.org/10.1016/j.compscitech.2019.107932
  6. Hong, H., Bae, K.J., and Yu, J., "Effect of Boron Nitride on Mechanical Properties, Thermal and Electrical Conductivities of Carbon Fiber Reinforced Plastics", Composites Research, Vol. 33, No. 3, 2020, pp. 153-160.
  7. Zhang, T., Cheng, Q., Xu, Z., Jiang, B., Wang, C., and Huang, Y., "Improved Interfacial Property of Carbon Fiber Composites with Carbon Nanotube and Graphene Oxide as Multi-scale Synergetic Reinforcements", Composites Part A: Applied Science and Manufacturing, Vol. 125, 2019, pp. 105573. https://doi.org/10.1016/j.compositesa.2019.105573
  8. Jiang, Z., Wang, F., Yin, J., Gong, S., Dai, Z., Pang, Y., Xiong, Y., Zhu, Z., and Li, Z., "Vibration Damping Mechanism of CuAlMn/polymer/carbon Nanomaterials Multi-scale Composites", Composites Part B: Engineering, Vol. 199, 2020, pp. 108266. https://doi.org/10.1016/j.compositesb.2020.108266
  9. Zhou, Y., Jin, P., Zhou, Y., and Zhu, Y., "High-performance Symmetric Supercapacitors Based on Carbon Nanotube/graphite Nanofiber Nanocomposites", Scientific Reports, Vol. 8, 2018, pp. 1-7. https://doi.org/10.1038/s41598-017-18585-3
  10. Jang, J.H., and Han, K.S., "Fabrication of Graphite Nanofibers Reinforced Metal Matrix Composites by Powder Metallurgy and Their Mechanical and Physical Characteristics", Journal of Composite Materials, Vol. 41, 2007, pp. 1431-1443. https://doi.org/10.1177/0021998306068071
  11. Weinstein, R.D., Ferens, A.R., Orange, R.J., and Lemaire, P., "Oxidative Dehydrogenation of Ethanol to Acetaldehyde and Ethyl Acetate by Graphite Nanofibers", Carbon, Vol. 49, 2011, pp. 701-707. https://doi.org/10.1016/j.carbon.2010.10.027
  12. Ferens, A.R., Weinstein, R.D., Giuliano, R., and Hull, J.A., "Selective Decomposition of Isopropanol Using as Prepared and Oxidized Graphite Nanofibers", Carbon, Vol. 50, 2012, pp. 192-200. https://doi.org/10.1016/j.carbon.2011.08.020
  13. Shin, P.S., Kim, J.H., Baek, Y.M., Park, H.S., and Park, J.M., "Epoxy Matrix with Adding Dopamine for Improving Mechanical Property and Interfacial Adhesion with Glass Fiber", Composites Research, Vol. 32, 2019, pp. 96-101.
  14. Kang, M.S., Jeon, M.H., Kim, I.G., and Woo, K.S., "The Study on the Characteristics of Mode I Crack for Cross-ply Carbon/epoxy Composite Laminates Based on Stress Fields", Composites Research, Vol. 32, 2019, pp. 327-334.
  15. Owens, D.K., and Wendt, R.C., "Estimation of the Surface Free Energy of Polymers", Journal of Applied Polymer Science, Vol. 13, 1969, pp. 1741-1747. https://doi.org/10.1002/app.1969.070130815
  16. Fowkes, F.M., "Determination of Interfacial Tensions, Contact Angles, and Dispersion Forces in Surfaces by Assuming Additivity of Intermolecular Interactions in Surfaces", The Journal of Physical Chemistry, Vol. 66, 1962, pp. 382-382. https://doi.org/10.1021/j100808a524
  17. Kaelble, D.H., "Dispersion-polar Surface Tension Properties of Organic Solids", The Journal of Adhesion, Vol. 2, 1970, pp. 66-81. https://doi.org/10.1080/0021846708544582
  18. Ranganathan, N., Oksman, K., Nayak, S.K., and Sain, M., "Structure Property Relation of Hybrid Biocomposites Based on Jute, Viscose and Polypropylene: The Effect of the Fibre Content and the Length on the Fracture Toughness and the Fatigue Properties", Composites Part A: Applied Science and Manufacturing, Vol. 83, 2016, pp. 169-175. https://doi.org/10.1016/j.compositesa.2015.10.037
  19. Lee, S.O., Rhee, K.Y., and Park, S.J., "Influence of Chemical Surface Treatment of Basalt Fibers on Interlaminar Shear Strength and Fracture Toughness of Epoxy-based Composites", Journal of Industrial and Engineering Chemistry, Vol. 32, 2015, pp. 153-156. https://doi.org/10.1016/j.jiec.2015.08.009
  20. Kim, S.H., Park, S.J., Rhee, K.Y., and Park, S.J., "Effects of Ozonized Carbon Black on Fracture and Post-cracking Toughness of Carbon Fiber-reinforced Epoxy Composites", Composites Part B: Engineering, Vol. 177, 2019, pp. 107379. https://doi.org/10.1016/j.compositesb.2019.107379
  21. Kim, B.J., Lee, Y.S., and Park, S.J., "A Study on Pore-opening Behaviors of Graphite Nanofibers by a Chemical Activation Process", Journal of Colloid and Interface Science, Vol. 306, 2007, pp. 454-458. https://doi.org/10.1016/j.jcis.2006.10.038
  22. Rambabu, G., Sasikala, S., and Bhat, S.D., "Nanocomposite Membranes of Sulfonated Poly (phthalalizinone ether ketone)-sulfonated Graphite Nanofibers as Electrolytes for Direct Methanol Fuel Cells", RSC Advances, Vol. 6, 2016, pp. 107507-107518. https://doi.org/10.1039/C6RA23510G
  23. Karakaya, N., Papila, M., and Ozkoc, G., "Overmolded Hybrid Composites of Polyamide-6 on Continuous Carbon and Glass Fiber/epoxy Composites: 'An Assessment of the Interface'", Composites Part A: Applied Science and Manufacturing, Vol. 131, 2020, pp. 105771. https://doi.org/10.1016/j.compositesa.2020.105771
  24. Yang, G., Yang, T., Yuan, W., and Du, Y., "The Influence of Surface Treatment on the Tensile Properties of Carbon Fiber-reinforced Epoxy Composites-bonded Joints", Composites Part B: Engineering, Vol. 160, 2019, pp. 446-456. https://doi.org/10.1016/j.compositesb.2018.12.095
  25. Kim, S.H., Heo, Y.J., Park, M., Min, B.G., Rhee, K.Y., and Park, S.J., "Effect of Hydrophilic Graphite Flake on Thermal Conductivity and Fracture Toughness of Basalt Fibers/epoxy Composites", Composites Part B: Engineering, Vol. 153, 2018, pp. 9-16. https://doi.org/10.1016/j.compositesb.2018.07.022
  26. Park, S.M., Kim, D.W., Jeong, G., Lim, J.H., and Kim, S.W., "Prediction and Calibration of Transverse Mechanical Properties of Unidirectional Composites with Random Fiber Arrangement Considering Interphase Effect", Composites Research, Vol. 32, 2019, pp. 270-278. https://doi.org/10.7234/composres.2019.32.5.270
  27. Han, S.H., Lee, J.W., Kim, J.S., Kim, Y.M., Kim, W.D., and Um, M.K., "A Study on Manufacturing Method of Standard Void Specimens for Non-destructive Testing in RFI Process and Effect of Void on Mechanical Properties", Composites Research, Vol. 32, 2019, pp. 395-402.
  28. Kang, W.S., Rhee, K.Y., and Park, S.J., "Influence of Surface Energetics of Graphene Oxide on Fracture Toughness of Epoxy Nanocomposites", Composites Part B: Engineering, Vol. 114, 2017, pp. 175-183. https://doi.org/10.1016/j.compositesb.2017.01.032
  29. Liu, B., Cao, S., Gao, N., Cheng, L., Liu, Y., Zhang, Y., and Feng, D., "Thermosetting CFRP Interlaminar Toughening with Multi-layers Graphene and MWCNTs under Mode I Fracture", Composites Science and Technology, Vol. 183, 2019, pp. 107829. https://doi.org/10.1016/j.compscitech.2019.107829
  30. Kilic, U., Sherif, M.M., and Ozbulut, O.E., "Tensile Properties of Graphene Nanoplatelets/epoxy Composites Fabricated by Various Dispersion Techniques", Polymer Testing, Vol. 76, 2019, pp. 181-191. https://doi.org/10.1016/j.polymertesting.2019.03.028