Journal of Electrochemical Science and Technology

  • 제12권4호
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  • Pages.387-397
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  • 2021
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  • 2093-8551(pISSN)
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  • 2288-9221(eISSN)
한국전기화학회 (The Korean Electrochemical Society)
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Hygroscopicity of 1:2 Choline Chloride:Ethylene Glycol Deep Eutectic Solvent: A Hindrance to its Electroplating Industry Adoption

  • Brusas, John Raymund (Sustainable Electrochemical Technologies Laboratory, Department of Mining, Metallurgical and Materials Engineering, College of Engineering, University of the Philippines Diliman) ;
  • Dela Pena, Eden May B. (Sustainable Electrochemical Technologies Laboratory, Department of Mining, Metallurgical and Materials Engineering, College of Engineering, University of the Philippines Diliman)
  • 투고 : 2020.10.05
  • 심사 : 2021.03.10
  • 발행 : 2021.11.28
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초록

Deep eutectic solvents have been established as feasible metal electroplating solvent alternatives over traditional toxic aqueous plating baths. However, water, either added intentionally or unintentionally, can significantly influence the solvent's physical properties and performance, thereby hindering its industry application. In this study, the hygroscopicity, or the ability to absorb moisture from the environment, of synthesized ethaline (1:2 choline chloride:ethylene glycol) was investigated. The kinematic viscosity, electrical conductivity, electrochemical window, and water content of ethaline were monitored over a 2-week period. Karl Fischer titration tests showed that ethaline exposed to the atmosphere displayed significant hygroscopicity compared to its unexposed counterpart. 1H NMR spectroscopy revealed that water vapor was readily absorbed at the surface due to the hydrophilic groups present in the ethaline molecule. Water uptake resulted in the decrease in viscosity, increase in electrical conductivity and narrowing of the electrochemical window of ethaline. Solution heating at 100℃ removed the absorbed moisture and allowed the recovery of the solvent's initial properties.

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과제정보

The authors would like to acknowledge the Philippine Council for Industry, Energy, and Emerging Technology Research and Development (PCIEERD) of the Department of Science and Technology (DOST) funded project entitled "Establishing an Environment- electrodeposition from Ionic Liquids 1Friendly Chromium Plating Process using New Generation Ionic liquids" and the Science Education Institute - DOST.

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